Synthesis and characterization of N-maleylglycine and its homopolymer

Pizarro G.D.C.; Rivas B.L; Geckeler K.E.

Abstract

The synthesis of the heterocyclic monomer N-maleylglycine starting from maleic anhydride and glycine and subsequent refluxing of the maleamic acid formed in the presence of triethylamine in toluene is described. In addition, the homopolymer of N-maleylglycine was synthesized by radical polymerization in solution. Both compounds were characterized by elemental analysis, FT-IR, 1H-NMR and 13C-NMR spectroscopy. The polymer has a molecular mass of 11500 g/mol and showed a considerably higher stability than the N-maleylglycine monomer.

Más información

Título de la Revista: BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA
Volumen: 41
Número: 2
Editorial: Sociedad Chilena de Química
Fecha de publicación: 1996
Página de inicio: 181
Página final: 188
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-0038417270&partnerID=q2rCbXpz