Article
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS  (1996)

Reactions of dichloromethane with thioanions. 3. Preparation and aminolysis of bis(alkoxythiocarbonylthio)methanes

Benavente, C; Díaz P; Vega J.C.

Abstract

Bis(alkoxythiocarbonylthio)methanes are prepared by reaction of sodium O-alkyldithiocarbonates in water with dichloromethane catalyzed by polyethylenglycol 1,500. The aminolysis of these products with monoalkylamines, in 1 : 7 molar proportion, in the presence of CH2Cl2 and the polymer above, affords 5-alkyl-1,3,5-dithiazinane, and dialkylcarbamothioate, in 1 : 2 molar proportion.

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Título de la Revista: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volumen: 116
Editorial: TAYLOR & FRANCIS LTD
Fecha de publicación: 1996
Página de inicio: 49
Página final: 56
URL: http://www.scopus.com/inward/record.url?eid=2-s2.0-0042785335&partnerID=q2rCbXpz