Article ISI SCOPUS
POLYMER BULLETIN  (2002)

Study of the polymerization of 1-octadecene with different metallocene catalysts

Quijada R.; Guevara, JL; Yazdani-Pedram, M.; Galland G.B.; Ribeiro, D.

Abstract

1-Octadecene (C18) was polymerized by using different metallocene catalysts. The rac-Et(Ind)2ZrCl2/MAO (I) and rac-Me2Si(Ind)2ZrCl2/MAO (III) presented the highest activity as compared with rac-Et(2-Me-Ind)2ZrCl2/MAO (II) and Ph2C(Flu)(Cp)ZrCl2/MAO (IV) catalysts. Catalyst IV produced polymers with highest molecular weights. The microstructure of the polymers was determined by 13C-NMR spectroscopy. Catalyst systems I, II and III produced isotactic polymers while catalyst IV produced polymers with mainly syndiotactic structures but with large amount of stereoregular error.

Más información

Título según WOS: Study of the polymerization of 1-octadecene with different metallocene catalysts
Título según SCOPUS: Study of the polymerization of 1-octadecene with different metallocene catalysts
Título de la Revista: POLYMER BULLETIN
Volumen: 49
Número: 4
Editorial: Springer
Fecha de publicación: 2002
Página de inicio: 273
Página final: 280
Idioma: English
URL: http://link.springer.com/10.1007/s00289-002-0103-2
DOI:

10.1007/s00289-002-0103-2
Notas: ISI, SCOPUS