First-principles screening of metal-organic frameworks for entangled photon pair generation
Abstract
The transmission of strong laser light in nonlinear optical materials can generate output photons sources that carry quantum entanglement in multiple degrees of freedom, making this process a fundamentally important tool in optical quantum technology. However, the availability of efficient optical crystals for entangled light generation is severely limited in terms of diversity, thus reducing the prospects for the implementation of next-generation protocols in quantum sensing, communication and computing. To overcome this, we developed and implemented a multi-scale first-principles modeling technique for the computational discovery of novel nonlinear optical devices based on metal-organic framework (MOF) materials that can efficiently generate entangled light via spontaneous parametric down-conversion (SPDC). Using collinear degenerate type-I SPDC as a case study, we computationally screen a database of 114 373 synthesized MOF materials to establish correlations between the structure and chemical composition of MOFs with the brightness and coherence properties of entangled photon pairs. We identify a subset of 49 non-centrosymmetric mono-ligand MOF crystals with high chemical and optical stability that produce entangled photon pairs with intrinsic G(2) correlation times tau c similar to 10-30 fs and pair generation rates in the range 104-1010s-1mW-1mm-1 at 1064 nm. Conditions for optimal type-I phase matching are given for each MOF and relationships between pair brightness, crystal band gap and optical birefringence are discussed. Correlations between the optical properties of crystals and their constituent molecular ligands are also given. Our work paves the way for the computational design of MOF-based devices for optical quantum technology.
Más información
Título según WOS: | ID WOS:001183673200001 Not found in local WOS DB |
Título de la Revista: | MATERIALS FOR QUANTUM TECHNOLOGY |
Volumen: | 4 |
Número: | 1 |
Editorial: | IOP PUBLISHING LTD |
Fecha de publicación: | 2024 |
DOI: |
10.1088/2633-4356/ad2c96 |
Notas: | ISI |