Abstract

A linear sweep anodic stripping voltammetric method using a carbon nanotube-gold nanoparticle-modified vibrating screen printed electrode for the determination of arsenic(III) is reported. The experiments were conducted with a 0.1 mol L-1 solution of H2SO4 in order to estimate the electrode area related to gold oxide formation. The results showed a clear reduction peak at approximately +0.85 V corresponding to the reduction of the gold surface oxide with a superficial area of 0.089 cm(2). A vibrating motor was attached to the screen printed electrode to create a portable and autonomous system with enhanced mass transfer. The repeatability of the measurements was 2.4 % (n = 10) at the level of 0.5 mg L-1 of arsenic(III) under the best instrumental operating conditions. The peak current was linearly dependent on the arsenic(III) concentration, thus allowing the construction of a linear analytical curve in the range from 10 to 550 mu g L-1 with the equation: -I-p (mu A) = 0.05 + 134.59 [As(III) (mu g L-1)], R-2 = 0.99. The obtained detection and quantification limits were 0.5 (3 SD) and 1.5 (10 SD) mu g L-1, respectively, using 120 s as the deposition time. It was shown that Cu(II) does not interfere in the detection of As(III) using the proposed method.