Studies on the liquid-liquid extraction of nickel(II), zinc(II), cadmium(II), mercury(II) and lead(II) with 1-phenyl-3hydroxy-4-dodecyldithiocarboxylate-5-pyrazolone
Abstract
The extraction behaviour of Ni(II), Zn(II), Cd(II), Hg(II) and Pb(II) from aqueous solution, as function of pH, has been investigated with chloroform solutions of 1-phenyl-3-hydroxy-4-dodecyldithiocarboxylate-5-pyrazolone (HDTC-12) as extractant. In each case, the extracted species was found to be M(DTC-12)2 and the extraction constants were deduced by non-linear regression analysis. The results demonstrate that this ligand extracts selectively Hg(II) from Cd(II) as well as from Pb(II).
Más información
| Título según WOS: | Studies on the liquid-liquid extraction of nickel(II), zinc(II), cadmium(II), mercury(II) and lead(II) with 1-phenyl-3hydroxy-4-dodecyldithiocarboxylate-5-pyrazolone |
| Título según SCOPUS: | Studies on the liquid-liquid extraction of nickel(II), zinc(II), cadmium(II), mercury(II) and lead(II) with 1-phenyl-3-hydroxy-4-dodecyldithiocarboxylate-5-pyrazolone |
| Título de la Revista: | MICROCHIMICA ACTA |
| Volumen: | 140 |
| Número: | 03-abr |
| Editorial: | SPRINGER WIEN |
| Fecha de publicación: | 2002 |
| Página de inicio: | 201 |
| Página final: | 203 |
| Idioma: | English |
| URL: | http://link.springer.com/10.1007/s00604-002-0905-9 |
| DOI: |
10.1007/s00604-002-0905-9 |
| Notas: | ISI, SCOPUS |