Metal carbonyl complexes containing heterocyclic nitrogen ligands - Part IX. MnBr(CO)(3)(3,3 '-R-2,2 '-biquinoline) compounds

Moya, SA; Guerrero, J; Pastene, R.; Azocar-Guzman, I; Pardey, AJ

Abstract

The fac-MnBr(CO)3(3,3?-R-2,2?-biquinoline) (R = CH3 and CH3; H and H;-CH2-CH2- or -CH2-CH2-CH2-) compounds were synthesized and characterized. The fac-conformation for the carbonyl complexes was established by IR spectroscopy. Conformational effects were investigated by means of 1H NMR and UV-Vis spectroscopical and electrochemical properties and these properties were compared with related rhenium compounds. © 2002 Published by Elsevier Science Ltd.

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Título según WOS: Metal carbonyl complexes containing heterocyclic nitrogen ligands - Part IX. MnBr(CO)(3)(3,3 '-R-2,2 '-biquinoline) compounds
Título según SCOPUS: Metal carbonyl complexes containing heterocyclic nitrogen ligands Part IX. MnBr(CO)3(3,3?-R-2,2?-biquinoline) compounds
Título de la Revista: POLYHEDRON
Volumen: 21
Número: 4
Editorial: PERGAMON-ELSEVIER SCIENCE LTD
Fecha de publicación: 2002
Página de inicio: 439
Página final: 444
Idioma: English
DOI:

10.1016/S0277-5387(01)01009-9

Notas: ISI, SCOPUS