Radiative decay channel assessment to understand the sensing mechanism of a fluorescent turn-on Al3+ chemosensor

Treto-Suárez M.A.; Hidalgo-Rosa Y.; Schott E.; Zarate X.; Páez-Hernández D.

Abstract

The turn-on luminescent chemosensor [2-Hydroxy-1-naphthaldehyde-(2-pyridyl) hydrazone] (L), selective to Al3+ ions, was studied by means of density functional theory (DFT) and time-dependent-DFT quantum mechanics calculations. The UV-Vis absorption and the radiative channel from the adiabatic S-1 excited state were assessed in order to elucidate the selective sensing mechanism of L to Al3+ ions. We found that twisted intramolecular charge transfer (TICT) and photoelectron transfer (PET), which alter the emissive state, are responsible for the luminescence quenching in L. After coordination with Al3+, the TICT is blocked, and PET is no longer possible. So, the emission of the coordination complex is activated, and a fluorescence effect enhanced by chelation is observed. For compounds with Zn2+ and Cd2+, the luminescence quenching is caused by PET, while for Ni2+, ligand to metal charge transfer is the prominent mechanism. To go into more detail, the metal-ligand interaction was analyzed via the Morokuma-Ziegler energy decomposition scheme and the natural orbital of chemical valence.

Más información

Título según WOS: Radiative decay channel assessment to understand the sensing mechanism of a fluorescent turn-on Al3+ chemosensor
Título según SCOPUS: Radiative decay channel assessment to understand the sensing mechanism of a fluorescent turn-on Al3+ chemosensor
Volumen: 120
Número: 3
Fecha de publicación: 2020
Idioma: English
DOI:

10.1002/qua.26083

Notas: ISI, SCOPUS