Effect of the Incorporation of Ni in the Adsorption Capacity of Paracetamol (N-Acetyl-P-Aminophenol) on MIL-101(Cr)

Baeza, patricio; Astudillo, Camila; Diaz, Manuel; Matus, Camila; Ramirez M.; Aguila, Gonzalo; ojeda, juan


The effect of nickel in the adsorption of N- acetyl-p-aminophenol (paracetamol) on a metal-organic frameworks (MOFs) type MIL-101(Cr) was studied. The incorporation of Ni to MOFs adsorbent was carried out by impregnation and adjusted to give a 4.00 wt.% Ni. The adsorbents were characterized by specific sur- face area (SSA), surface acidity techniques, electropho- retic migration (EM), thermogravimetric analysis (TGA), and scanning electron microscope (SEM) and were tested by the adsorption of paracetamol solutions. The results showed that the Ni particles were well dispersed throughout the MIL-101(Cr) crystal increas- ing the acid strength and the density of acid site values in the MOFs surface. The increase in adsorption capacity of MIL-101(Cr) when Ni was incorporated can be at- tributed to the availability of metal atoms as adsorption centers that can adsorb the paracetamol by electronic retro-donation through π-type complexing

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Título de la Revista: Water, Air, & Soil Pollution
Volumen: 231
Fecha de publicación: 2020


Notas: wos