Photo-induced single electron transfer addition of triphenylgermane to conjugated carbonyl compounds: competitive radical addition

Feddouli, A; El Kadib, A; Riviere, P; Delpech, F; Riviere-Baudet, M; Castel A; Manriquez, MJ; Chavez, I; Itto, MYA; Ahbala, M

Abstract

Conjugated ketones are poorly reactive towards triphenylgermane under radical conditions, but in their excited state they can undergo single electron transfer (SET) reactions. The SET reaction, through the formation of a germanium-centred radical, initiates a competitive and divergent radical addition. In the case of carvone, the SET adduct was isolated pure from the reaction of triphenylgermyllithium with the same ketone. Copyright © 2004 John Wiley & Sons, Ltd.

Más información

Título según WOS: Photo-induced single electron transfer addition of triphenylgermane to conjugated carbonyl compounds: competitive radical addition
Título según SCOPUS: Photo-induced single electron transfer addition of triphenylgermane to conjugated carbonyl compounds: Competitive radical addition
Título de la Revista: APPLIED ORGANOMETALLIC CHEMISTRY
Volumen: 18
Número: 5
Editorial: Wiley
Fecha de publicación: 2004
Página de inicio: 233
Página final: 240
Idioma: English
DOI:

10.1002/aoc.614

Notas: ISI, SCOPUS