Reactivity of 2,6-diethyl-4,8-dimethyl-1,5-dioxo-s-hydrindacene towards radical, anionic and cationic germylation

El Kadib, A; Castel A; Delpech, F; Riviere, P; Riviere-Baudet, M; Gornitzka, H; Aguirre P.; Manriquez, JM; Chavez, I; Abril, D.

Abstract

The synthesis and diastereoisomeric resolution of 2,6-diethyl-4,8-dimethyl- 1,5-dioxo-s-hydrindacene allowed the determination of the structure of the meso compound by X-ray diffractometry. The diastereoisomers were inactive towards radical germylation but reacted with acidic hydrogermanes or germylithium yielding ?-germylated alcohols. By contrast, they were poorly reactive towards germylamines or SET reactions. This diketone acts as an efficient spin trap in radical hydrogermylation of alkenes. © 2003 Elsevier B.V. All rights reserved.

Más información

Título según WOS: Reactivity of 2,6-diethyl-4,8-dimethyl-1,5-dioxo-s-hydrindacene towards radical, anionic and cationic germylation
Título según SCOPUS: Reactivity of 2,6-diethyl-4,8-dimethyl-1,5-dioxo-s-hydrindacene towards radical, anionic and cationic germylation
Título de la Revista: INORGANICA CHIMICA ACTA
Volumen: 357
Número: 4
Editorial: ELSEVIER SCIENCE SA
Fecha de publicación: 2004
Página de inicio: 1256
Página final: 1264
Idioma: English
DOI:

10.1016/j.ica.2003.10.017

Notas: ISI, SCOPUS