Synthesis, characterization and 2,5-pyridinedicarboxylic acid interaction of Zinc(II) complexes with N-(4-Xphenyl)pyridine-2-yl -methanimine ligands (X= -Cl and -N(CH3)2

Dinamarca, Nicole; Levín, Pedro; Muñoz, Hugo; Caruso, Franceso; Rossi, Miriam; Guerrero, Juan; Azócar, Manuel Ignacio


Two new Zn(II) N-(4-X-phenyl)pyridine-2-yl-methanimine complexes, [Zn(NN´-Cl)Cl2](1) and [Zn(NN´-N(CH3)2)Cl2](2), have been synthesized and characterized by elemental analysis, FT-IR and NMR-1H spectra. The crystal structure of complex 1 was determined by X-ray single crystal diffraction. Experiments performed by Benesi-Hilderbrand method indicate that zinc complexes interact with 2,5-pyridinedicarboxyc acid.

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Título de la Revista: Communication in inorganic synthesis
Volumen: 5
Fecha de publicación: 2017
Página de inicio: 11
Página final: 14
Idioma: Inglés