Structure and Properties of (CH3NH3)(3)Tl2Cl9: A Thallium-Based Hybrid Perovskite-Like Compound

Castillo, Rodrigo; Cisterna, Jonathan; Brito, Ivan; Conejeros, Sergio; Llanos, Jaime

Abstract

The new compound (CH3NH3)(3)Tl2Cl9 was synthesized and fully characterized. X-ray photoelectron spectroscopy and Raman spectroscopy are consistent with the crystal structure solved by single-crystal X-ray diffraction. This compound is a semiconductor with a measured band gap of E-g = 2.91 eV. It is the first thallium-based hybrid perovskite and shows remarkably high stability to ambient conditions.

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Título según WOS: Structure and Properties of (CH3NH3)(3)Tl2Cl9: A Thallium-Based Hybrid Perovskite-Like Compound
Título de la Revista: INORGANIC CHEMISTRY
Volumen: 59
Número: 14
Editorial: AMER CHEMICAL SOC
Fecha de publicación: 2020
Página de inicio: 9471
Página final: 9475
DOI:

10.1021/ACS.INORGCHEM.0C01321

Notas: ISI