A trinuclear Cu-II complex with functionalized s-heptazine N-ligands: molecular chemistry from a g-C3N4 fragment

Maxwell, Lindley; Gomez-Coca, Silvia; Weyhermueller, Thomas; Panyella, David; Ruiz, Eliseo

Abstract

A new kind of N-ligand based on heptazine derivatives is presented. A trinuclear Cu-II complex, [(L)(2)(Cu3Cl3)-Cl-II](ClO4)(3)center dot 3CH(2)Cl(2) (L = 2,4,6-tris(di-2-pyridylamino)heptazine), utilizing a pyridine derivative of heptazine has been synthesized and characterized avoiding the inherent solubility problems of heptazine compounds. Thus, this work opens the application of such ligands either in supramolecular chemistry as a larger ligand of the widely used s-triazine derivatives or to provide molecular systems for photocatalysis as heptazine is the fundamental unit of the very promising g-C3N4 2D compound.

Más información

Título según WOS: ID WOS:000360471000003 Not found in local WOS DB
Título de la Revista: J. Inorg. Biochem
Volumen: 44
Número: 36
Editorial: Elsevier
Fecha de publicación: 2015
Página de inicio: 15761
Página final: 15763
DOI:

10.1039/c5dt02485d

Notas: ISI