Different topologies in three manganese-mu-azido 1D compounds: magnetic behavior and DFT-quantum Monte Carlo calculations

Mautner, Franz A.; Berger, Christian; Scherzer, Michael; Fischer, Roland C.; Maxwell, Lindley; Ruiz, Eliseo; Vicente, Ramon

Abstract

The syntheses and structural characterization of three new monodimensional azido-bridged manganese(II) complexes with empirical formulae [Mn(N-3)(2)(aminopyz)(2)](n) (1), [Mn(N-3)(2)(4-azpy)(2)](n) (2) and [Mn(N-3)(2)(4-Bzpy)(2)](n) (3) (pyz = pyrazine (1,4-diazine)), 4-azpy = 4-azidopyridine and 4-Bzpy = 4-benzoylpyridine) are reported. 1 is a monodimensional compound with double EO azido bridges, 2 is an alternating monodimensional compound with double end-on and double end-to-end azido bridges in the sequence di-EO-di-EE and 3 is a monodimensional compound with double end-on and double end-to-end azido bridges in the sequence di-EO-di-EO-diEO-di-EO-di-EE. The magnetic properties of 1-3 are reported. Periodic DFT calculations were performed to estimate the J values and quantum Monte Carlo simulations were carried out using the calculated J values to check their accuracy in comparison with the experimental magnetic measurements. From this theoretical analysis, two appealing features of the di-EO Mn(II) compounds can be extracted: first, the exchange coupling becomes more ferromagnetic when the Mn-N-Mn bridging angle becomes larger and the spin density of the bridging nitrogen atoms has an opposite sign to that of the Mn(II) centers.

Más información

Título según WOS: ID WOS:000363580800038 Not found in local WOS DB
Título de la Revista: J. Inorg. Biochem
Volumen: 44
Número: 42
Editorial: Elsevier
Fecha de publicación: 2015
Página de inicio: 18632
Página final: 18642
DOI:

10.1039/c5dt03034j

Notas: ISI