A new approach to the mechanism for the acetalization of benzaldehyde over MOF catalysts

Camu, Esteban; Pazo, Cesar; Becerra, Daniel; Hidalgo-Rosa, Yoan; Paez-Hernandez, Dayan; Zarate, Ximena; Schott, Eduardo; Escalona, Nestor

Abstract

The benzaldehyde acetalization reaction catalyzed by UiO-66, and its fluorinated analog UiO-66F, was carried out in a batch-type reactor at room temperature and atmospheric pressure, and the full kinetic study was performed using the Langmuir-Hinshelwood and Eley-Rideal models. It was established that the Eley-Rideal model is the one that best fits the experimental data. The catalytic results indicated that both MOFs enable carrying out the acetalization reaction. However, UiO-66F has the highest activity, which could be attributed to its high acidity. Both structures were characterized by N(2)physisorption, thermogravimetry, powder X-ray diffraction, potentiometric titrations, and infrared spectroscopy. The highest acidity displayed by UiO-66F was explained by DFT studies and experimental studies.

Más información

Título según WOS: A new approach to the mechanism for the acetalization of benzaldehyde over MOF catalysts
Título de la Revista: NEW JOURNAL OF CHEMISTRY
Volumen: 44
Número: 35
Editorial: ROYAL SOC CHEMISTRY
Fecha de publicación: 2020
Página de inicio: 14865
Página final: 14871
DOI:

10.1039/D0NJ02416C

Notas: ISI