A new approach to the mechanism for the acetalization of benzaldehyde over MOF catalysts
Abstract
The benzaldehyde acetalization reaction catalyzed by UiO-66, and its fluorinated analog UiO-66F, was carried out in a batch-type reactor at room temperature and atmospheric pressure, and the full kinetic study was performed using the Langmuir-Hinshelwood and Eley-Rideal models. It was established that the Eley-Rideal model is the one that best fits the experimental data. The catalytic results indicated that both MOFs enable carrying out the acetalization reaction. However, UiO-66F has the highest activity, which could be attributed to its high acidity. Both structures were characterized by N(2)physisorption, thermogravimetry, powder X-ray diffraction, potentiometric titrations, and infrared spectroscopy. The highest acidity displayed by UiO-66F was explained by DFT studies and experimental studies.
Más información
Título según WOS: | A new approach to the mechanism for the acetalization of benzaldehyde over MOF catalysts |
Título de la Revista: | NEW JOURNAL OF CHEMISTRY |
Volumen: | 44 |
Número: | 35 |
Editorial: | ROYAL SOC CHEMISTRY |
Fecha de publicación: | 2020 |
Página de inicio: | 14865 |
Página final: | 14871 |
DOI: |
10.1039/D0NJ02416C |
Notas: | ISI |