Regio- and stereo-selectivity in the silylation of 2,6-diethyl-3,4,7,8-tetramethyl-1,5-dihydro-s-indacene

Dahrouch M.; Burgos F.; Castel A; Chavez, I; Gornitzka, H; Manriquez, JM; Riviere, P; Riviere-Baudet, M; Alvarez J.; Onyszchuk, M

Abstract

Disilylation of 2,6-diethyl-3,4,7,8-tetramethyl-1,5-dihydro-s-indacene is regioselective and stereoselective. The stereoselectivity was modified by changing the experimental conditions, allowing an understanding of the reaction mechanism. The structure of the 'meso' diastereoisomer was established by X-ray diffraction. Copyright © 2006 John Wiley & Sons, Ltd.

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Título según WOS: Regio- and stereo-selectivity in the silylation of 2,6-diethyl-3,4,7,8-tetramethyl-1,5-dihydro-s-indacene
Título según SCOPUS: Regio- and stereo-selectivity in the silylation of 2,6-diethyl-3,4,7,8- tetramethyl-1,5-dihydro-s-indacene
Título de la Revista: APPLIED ORGANOMETALLIC CHEMISTRY
Volumen: 21
Número: 1
Editorial: Wiley
Fecha de publicación: 2007
Página de inicio: 31
Página final: 38
Idioma: English
URL: http://doi.wiley.com/10.1002/aoc.1154
DOI:

10.1002/aoc.1154

Notas: ISI, SCOPUS