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Emilio Enrique Bunel Torrealba

Associate Professor

Pontificia Universidad Católica de Chile

Santiago, Chile

Chemistry, CALIFORNIA INSTITUTE OF TECHNOLOGY. Estados Unidos, 1988
Chemistry, UNIVERSIDAD DE CHILE. Chile, 1980
Chemical Engineering, UNIVERSIDAD DE CHILE. Chile, 1980

Associate Professor Full Time

PONTIFICIA UNIVERSIDAD CATOLICA DE CHILE

Química y Farmacia

Santiago, Chile

2019 - At present


Study of the Molecular Properties of Mono- and Binuclear Metal s-Indacenyl Complexes with Ir, Rh, and Re: A Theoretical Approach Zarate, Ximena; Schott, Eduardo; Bunel, Emilio; Manríquez, Juan M.; Chávez, Ivonne Article ISI SCOPUS JOURNAL OF CHEMISTRY (2017)
Supported Single-Site Ti(IV) on a Metal-Organic Framework for the Hydroboration of Carbonyl Compounds Huang, Zhiyuan; Liu, Dong; Camacho-Bunquin, Jeffrey; Zhang, Guanghui; Yang, Dali; Lopez-Encarnacion, Juan M.; Xu, Yunjie; Ferrandon, Magali S.; Niklas, Jens; Poluektov, Oleg G.; Jellinek, Julius; Lei, Aiwen; Bunel, Emilio E.; Delferro, Massimiliano Article ISI ORGANOMETALLICS (2017)
Aromatic C-H bond cleavage by using a Cu(I) ate-complex Zhang, Guanghui; Yi, Hong; Xin, Jie; Deng, Yi; Bai, Ruopeng; Huang, Zhiliang; Miller, Jeffrey T.; Kropf, A. Jeremy; Bunel, Emilio E.; Qi, Xiaotian; Lan, Yu; Lei, Aiwen Article ISI ORGANIC CHEMISTRY FRONTIERS (2016)
Homolytic cleavage of the O-Cu(II) bond: XAFS and EPR spectroscopy evidence for one electron reduction of Cu(II) to Cu(I) Yi, Hong; Zhang, Guanghui; Xin, Jie; Deng, Yi; Miller, Jeffrey T.; Kropf, Arthur J.; Bunel, Emilio E.; Qi, Xiaotian; Lan, Yu; Lee, Jyh-Fu; Lei, Aiwen Article ISI CHEMICAL COMMUNICATIONS (2016)
Bimetallic zinc complex - active species in coupling of terminal alkynes with aldehydes via nucleophilic addition/Oppenauer oxidation Yuan, Jiwen; Wang, Jing; Zhang, Guanghui; Liu, Chao; Qi, Xiaotian; Lan, Yu; Miller, Jeffrey T.; Kropf, A. Jeremy; Bunel, Emilio E.; Lei, Aiwen Article ISI CHEMICAL COMMUNICATIONS (2015)
Carboxylic acid derivatives via catalytic carboxylation of unsaturated hydrocarbons: whether the nature of a reductant may determine the mechanism of CO2 incorporation? Kirillov, E.; Carpentier, J. -F.; Bunel, E. Article ISI DALTON TRANSACTIONS (2015)
Copper-catalyzed aerobic oxidative coupling: From ketone and diamine to pyrazine Wu, Kun; Huang, Zhiliang; Qi, Xiaotian; Li, Yingzi; Zhang, Guanghui; Liu, Chao; Yi, Hong; Meng, Lingkui; Bunel, Emilio E.; Miller, Jeffrey T.; Pao, Chih-Wen; Lee, Jyh-Fu; Lan, Yu; Lei, Aiwen Article ISI SCIENCE ADVANCES (2015)
Evidence of Cu-I/Cu-II Redox Process by X-ray Absorption and EPR Spectroscopy: Direct Synthesis of Dihydrofurans from beta-Ketocarbonyl Derivatives and Olefins Yi, Hong; Liao, Zhixiong; Zhang, Guanghui; Zhang, Guoting; Fan, Chao; Zhang, Xu; Bunel, Emilio E.; Pao, Chih-Wen; Lee, Jyh-Fu; Lei, Aiwen Article ISI CHEMISTRY-A EUROPEAN JOURNAL (2015)
Heterogeneous nucleation and shape transformation of multicomponent metallic nanostructures Kwon, Soon Gu; Krylova, Galyna; Phillips, Patrick J.; Klie, Robert F.; Chattopadhyay, Soma; Shibata, Tomohiro; Bunel, Emilio E.; Liu, Yuzi; Prakapenka, Vitali B.; Lee, Byeongdu; Shevchenko, Elena V. Article ISI NATURE MATERIALS (2015)
Iron-Catalyzed Oxidative C-H/C-H Cross-Coupling between Electron-Rich Arenes and Alkenes Ma, Yiyang; Zhang, Dongchao; Yan, Zhiyuan; Wang, Mengfan; Bian, Changliang; Gao, Xinlong; Bunel, Emilio E.; Lei, Aiwen Article ISI ORGANIC LETTERS (2015)
Revealing the halide effect on the kinetics of the aerobic oxidation of Cu(I) to Cu(II) Deng, Yi; Zhang, Guanghui; Qi, Xiaotian; Liu, Chao; Miller, Jeffrey T.; Kropf, A. Jeremy; Bunel, Emilio E.; Lan, Yu; Lei, Aiwen Article ISI CHEMICAL COMMUNICATIONS (2015)
Cu(II)-Cu(I) Synergistic Cooperation to Lead the Alkyne C-H Activation Bai, Ruopeng; Zhang, Guanghui; Yi, Hong; Huang, Zhiliang; Qi, Xiaotian; Liu, Chao; Miller, Jeffrey T.; Kropf, A. Jeremy; Bunel, Emilio E.; Lan, Yu; Lei, Aiwen Article ISI JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Direct Observation of Reduction of Cu(II) to Cu(I) by Terminal Alkynes Zhang, Guanghui; Yi, Hong; Zhang, Guoting; Deng, Yi; Bai, Ruopeng; Zhang, Heng; Miller, Jeffrey T.; Kropf, Arthur J.; Bunel, Emilio E.; Lei, Aiwen Article ISI JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Discovery of Highly Selective Alkyne Semihydrogenation Catalysts Based on First-Row Transition-Metallated Porous Organic Polymers Tanabe, Kristine K.; Ferrandon, Magali S.; Siladke, Nathan A.; Kraft, Steven J.; Zhang, Guanghui; Niklas, Jens; Poluektov, Oleg G.; Lopykinski, Susan J.; Bunel, Emilio E.; Krause, Theodore R.; Miller, Jeffrey T.; Hock, Adam S.; Nguyen, SonBinh T. Article ISI ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)
Structure-kinetic relationship study of organozinc reagents Zhang, Guanghui; Li, Jing; Deng, Yi; Miller, Jeffrey T.; Kropf, A. Jeremy; Bunel, Emilio E.; Lei, Aiwen Article ISI CHEMICAL COMMUNICATIONS (2014)
Highly selective rhodium-catalyzed conjugate addition reactions of 4-oxobutenamides Zigterman, Jamie L.; Woo, Jacqueline C. S.; Walker, Shawn D.; Tedrow, Jason S.; Borths, Christopher J.; Bunel, Emilio E.; Faul, Margaret M. Article ISI Journal of Organic Chemistry (2007)
New catalysts for Suzuki-Miyaura coupling reactions of heteroatom-substituted heteroaryl chlorides Guram, Anil S.; Wang, Xiang; Bunel, Emilio E.; Faul, Margaret M.; Larsen, Robert D.; Martinelli, Michael J. Article ISI Journal of Organic Chemistry (2007)
Palladium-catalyzed alpha-vinylation of carbonyl compounds Huang, Jinkun; Bunel, Emilio; Faul, Margaret M. Article ISI ORGANIC LETTERS (2007)
Stereoselective synthesis of a MCHr1 antagonist Andersen, Denise; Storz, Thomas; Liu, Pingli; wang, xin; Li, Leping; Fan, Pingchen; Chen, Xiaoqi; Allgeier, Alan; Burgos, Alain; Tedrow, Jason; Baum, Jean; Chen, Ying; Crockett, Rich; Huang, Liang; Syed, Rashid; Larsen, Robert D.; Martinelli, Mike Article ISI Journal of Organic Chemistry (2007)
New air-stable catalysts for general and efficient Suzuki-Miyaura cross-coupling reactions of heteroaryl chlorides Guram, AS; King, AO; Allen, JG; Wang, XH; Schenkel, LB; Chan, J; Bunel, EE; Faul, MM; Larsen, RD; Martinelli, MJ; Reider, PJ Article ISI ORGANIC LETTERS (2006)
Ruthenium carbonyl complexes in catalytic epoxidation of olefins co-catalyzed by isobutyl-aldehyde Aguirre P.; ZOLEZZI, S; Parada, J; Bunel, E.; Moya, SA; Sariego R. Article ISI SCOPUS APPLIED ORGANOMETALLIC CHEMISTRY (2006)
Pd-II complexes possessing a seven-membered N-heterocyclic carbene ligand Scarborough, CC; Grady, MJW; Guzei, IA; Gandhi, BA; Bunel, EE; Stahl, SS Article ISI ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)
Synthesis, characterization, and reactivity of [((Pr-i)(2)P(CH2)(3)P(Pr-i)(2))(PCy3)PdH][OR] Perez, PJ; Calabrese, JC; Bunel, EE Article ISI ORGANOMETALLICS (2001)


1. Surface modification of catalysts by organic molecules and metal cations for selective catalysis Bunel, Emilio; Shevchenko, Elena; Kwon, Soongu Patent (2014)
Catalyzed process of making C-5-substituted heterocyclic inhibitors of 11beta-hydroxy steroid dehydrogenase type 1 Bunel, Emilio; Guram, Anil; Liu, Qingyian Patent (2007)
Preparation of non-steroidal vitamin D receptor modulators Bunel, Emilio; Dahnke, Karl Robert; Gajewski, Robert Peter; Jones, Charles David; Nagpal, Sunil; Lu, Jianliang Patent (2005)
Preparation of phenylalkyl thiophene-type vitamin D receptor modulators for treating bone disease, psoriasis and other disorders Bunel, Emilio; Dahnke, Karl Robert; Gajewski, Robert Peter; Jones, Charles David; Linebarger, Jared Harris Patent (2005)