Man

Daniel Alejandro Aravena Ponce

Assistant Professor

Universidad de Santiago de Chile

Santiago, Chile

Líneas de Investigación


ab initio calculations, molecular magnetism, molecular spintronics, Optical properties of inorganic systems

Educación

  •  Licenciado en Química, Universidad de Chile. Chile, 2009
  •  Químico, Universidad de Chile. Chile, 2009
  •  Máster en Química, Universidad de Barcelona. España, 2011
  •  Doctor en Química, Universidad de Barcelona. España, 2013

Experiencia Académica

  •   Postdoctoral Fellow Full Time

    Max Planck Institute For Chemical Energy Conversion

    Muelheim an der Ruhr, Alemania

    2014 - 2015

Experiencia Profesional

  •   Associate Professor Full Time

    Universidad de Santiago de Chile

    Santiago, Chile

    2015 - At present

Formación de Capital Humano


Director 2 Tesis de pregrado Licenciatura en Química USACH (terminadas)
Co-Director 1 Tesis de postgrado Doctorado en Química U de Chile (terminada)
Director 1 Tesis de postgrado Doctorado en Química USACH (en curso)


Premios y Distinciones

  •   Premio Extraordinario del Máster en Química

    UNIVERSIDAD DE BARCELONA

    España, 2013

    Prize awarded to master students obtaining a final average grade over 9 (out of 10). The prize can be awarded to a maximum of 1 out of 15 students.


 

Article (52)

Nuclearity Control for Efficient Thermally Activated Delayed Fluorescence in a CuI Complex and its Halogen-Bridged Dimer

sun, chen; Llanos, Leonel; Arce, Pablo; Oliver, Allen; Wannemacher, Reinhold; Cabanillas-Gonzalez, Juan; Lemus, luis; Aravena, Daniel

Article ISI DOI: https://doi.org/10.1021/acs.chemmater.1c01531
CHEMISTRY OF MATERIALS  (2021)

Structure and excited-state dynamics of dimeric copper(i) photosensitizers investigated by time-resolved X-ray and optical transient absorption spectroscopy

Velasco, Lucia; Llanos, Leonel; Levin, Pedro; Vega, Andres; Yu, Jin; Zhang, Xiaoyi; Lemus, luis; Aravena, Daniel; Moonshiram, Dooshaye

Article ISI
PHYSICAL CHEMISTRY CHEMICAL PHYSICS  (2021)

Tuning Single-Molecule Conductance by Controlled Electric Field-Induced trans-to-cis Isomerisation

Quintans, C. S.; Andrienko, Denis; Domke, Katrin F.; Aravena, Daniel; Koo, Sangho; Diez-Perez, Ismael; Aragones, Albert C.

Article ISI
APPLIED SCIENCES-BASEL  (2021)

Control of magnetic anisotropy by macrocyclic ligand distortion in a family of Dy-III and Er-III single molecule magnets

Gil, Yolimar; Fuentealba, Pablo; Vega, Andres; Spodine, Evgenia; Aravena, Daniel

Article ISI
DALTON TRANSACTIONS  (2020)

Effect of Second-Sphere Interactions on the Magnetic Anisotropy of Lanthanide Single-Molecule Magnets: Electrostatic Interactions and Supramolecular Contacts

Gil Y.; LLanos, L; Cancino P.; Fuentealba P.; Vega A.; Spodine E.; Aravena D.

Article ISI SCOPUS
JOURNAL OF PHYSICAL CHEMISTRY C  (2020)

High performance single-molecule magnets, Orbach or Raman relaxation suppression?

Castro-Alvarez, Alejandro; Gil, Yolimar; Llanos, Leonel; Aravena, Daniel

Article ISI
INORGANIC CHEMISTRY FRONTIERS  (2020)

Reactivity of (CuN4)-N-I Flattened Complexes: Interplay between Coordination Geometry and Ligand Flexibility

Llanos, Leonel; Vera, Cristian; Vega, Andres; Aravena, Daniel; Lemus, luis

Article ISI
INORGANIC CHEMISTRY  (2020)

Single-Molecule Transport of Fullerene-Based Curcuminoids

Duli? D.; Rates A.; Castro E.; Labra-Muñoz J.; Aravena D.; Etcheverry-Berrios A.; Riba-López D.; Ruiz E.; Aliaga-Alcalde N.; Soler M.; Echegoyen L.; Van Der Zant H.S.J.

Article ISI SCOPUS
JOURNAL OF PHYSICAL CHEMISTRY C  (2020)

Spin dynamics in single-molecule magnets and molecular qubits

Aravena, Daniel; Ruiz, Eliseo

Article ISI
DALTON TRANSACTIONS  (2020)

Tuning Single-Molecule Conductance in Metalloporphyrin-Based Wires via Supramolecular Interactions

Aragones, Albert C.; Martin-Rodriguez, Alejandro; Aravena, Daniel; Puigmarti-Luis, Josep; Amabilino, David B.; Aliaga-Alcalde, Nuria; Gonzalez-Campo, Arantzazu; Ruiz, Eliseo; Diez-Perez, Ismael

Article ISI
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION  (2020)

[UF6](2-): A Molecular Hexafluorido Actinide(IV) Complex with Compensating Spin and Orbital Magnetic Moments

Pedersen K.S.; Meihaus K.R.; Rogalev A.; Wilhelm F.; Aravena D.; Amoza M.; Ruiz E.; Long J.R.; Bendix J.; Clérac R.

Article ISI SCOPUS
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION  (2019)

Influence of the channel size of isostructural 3d-4f MOFs on the catalytic aerobic oxidation of cycloalkenes

Cancino P.; Santibañez L.; Stevens C.; Fuentealba P.; Audebrand N.; Aravena D.; Torres J.; Martinez S.; Kremer C.; Spodine E.

Article ISI SCOPUS
NEW JOURNAL OF CHEMISTRY  (2019)

Relaxation time enhancement by magnetic dilution in single-molecule magnets: An ab initio study

LLanos, L; Aravena D.

Article ISI SCOPUS
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS  (2019)

Ab Initio Prediction of Tunneling Relaxation Times and Effective Demagnetization Barriers in Kramers Lanthanide Single-Molecule Magnets

Aravena, Daniel

Article ISI SCOPUS
JOURNAL OF PHYSICAL CHEMISTRY LETTERS  (2018)

Designing a Dy-2 Single-Molecule Magnet with Two Well Differentiated Relaxation Processes by Using a Nonsymmetric Bisbidentate Bipyrimidine-N-Oxide Ligand: A Comparison with Mononuclear Counterparts

Diaz-Ortega, IF; Herrera JM; Aravena, D; Ruiz, E; Gupta T.; Rajaraman, G; Nojiri, H; Colacio, E

Article ISI SCOPUS
INORGANIC CHEMISTRY  (2018)

Effect of Heteroatoms on Field-Induced Slow Magnetic Relaxation of Mononuclear Fe-III (S=5/2) Ions within Polyoxometalates

Minato, Takuo; Aravena, Daniel; Ruiz, Eliseo; Yamaguchi, Kazuya; Mizuno, Noritaka; Suzuki, Kosuke

Article ISI SCOPUS
INORGANIC CHEMISTRY  (2018)

Effect of Low Spin Excited States for Magnetic Anisotropy of Transition Metal Mononuclear Single Molecule Magnets



Article WOS-ESCI SCOPUS
INORGANICS  (2018)

Influence of the substituent on the phosphine ligand in novel rhenium(i) aldehydes. Synthesis, computational studies and first insights into the antiproliferative activity

Muñoz, Michelle; Siegmund, Daniel; Gomez, Alejandra; Godoy, Fernando; Fierro, Angelica; Llanos, Leonel; Aravena, Daniel; Metzler-Nolte, Nils

Article ISI SCOPUS
DALTON TRANSACTIONS  (2018)

Solid state photoluminescence studies of [(EuLH2)-H-n(NO3)(3)](H2O)(x) macrocyclic complexes with Schiff base ligands

de Santana, Ricardo C.; Fuentealba, Pablo A.; Maia, Lauro J.Q.; Paredes-García, Verónica; Aravena, Daniel; Venegas-Yazigi, Diego; Manzur, Jorge; Spodine, Evgenia

Article ISI SCOPUS
JOURNAL OF LUMINESCENCE  (2018)

Steric and Electronic Factors Affecting the Conformation of Bimetallic Cu-I Complexes: Effect of the Aliphatic Spacer of Tetracoordinating Schiff-Base Ligands

Lemus, luis; Díaz, Daniel E.; Llanos, Leonel; Arce, Pablo; Lorca, Romina; Guerrero, Juan; Costamagna, Juan; Aravena, Daniel; Ferraudi, Guillermo; Oliver, Allen; Lappin, Alexander Graham

Article ISI SCOPUS
CHEMISTRY-A EUROPEAN JOURNAL  (2018)

Charge Transport through a Single Molecule of trans-1-bis-Diazofluorene [60]fullerene

Stefani, Davide; Gutiérrez-Cerón, Cristian A.; Aravena, Daniel; Labra-Muñoz, Jacqueline; Suarez, Catalina; Liu, Shuming; Soler, Monica; Echegoyen, Luis; van der Zant, Herre S.J.; Dulic, Diana

Article ISI SCOPUS
CHEMISTRY OF MATERIALS  (2017)

Effect of the substituent of the cation of N-octylpyridinium hexafluorophosphate in the electrical and electrochemical response of carbon paste electrodes modified with these ionic liquids

Fuenzalida, F; Aravena, D; Garcia, C; Garcia, M; Arce, R; Ramirez, G; Diaz, C; Isaacs, M; Arevalo, MD; Aguirre, MJ

Article ISI SCOPUS
Electrochimica Acta  (2017)

Influence of the Lanthanide (III) ion in {[Cu3Ln2(oda)6(H2O)6]·nH2O}n (LnIII=> La,Gd,Yb) Catalysts on the Heterogeneous Oxidation of Olefins

Cancino, Patricio; Paredes-Garcia, Veronica; Aliaga, Carolina; Aguirre, Pedro; Aravena, Daniel; Spodine, Evgenia

Article
Catalysis Science & Technology  (2017)

Metal-Controlled Magnetoresistance at Room Temperature in Single-Molecule Devices

Aragones, Albert; Aravena, Daniel; Valverde-Muñoz, Francisco; Real, Jose Antonio; Sanz, Fausto; Díez-Pérez, Ismael; Ruiz, Eliseo

Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY  (2017)

Models to Predict the Magnetic Properties of Single- and Multiple-Bridged Phosphate CuII Systems=> A Theoretical DFT Insight

Muñoz-Becerra, Karina; Aravena, Daniel; Ruiz, Eliseo; Spodine, Evgenia; Soto-Donoso, Nicolas; Paredes-Garcia, Veronica; Venegas-Yazigi, Diego

Article
Inorganic Chemistry Frontiers  (2017)

A Low Spin Manganese(IV) Nitride Single Molecule Magnet

Ding, M; Cutsail III, GE; Aravena, D; Amoza, M; Rouzières, M; Dechambenoit, P; Losovyj, Y; Pink, M; Ruiz, E; Clérac, R; Smith, JM

Article
Chemical Science  (2016)

DFT Approaches to Transport Calculations in Magnetic Single-Molecule Devices

Martín-Rodríguez, A; Aravena, D; Ruiz, E

Article
THEORETICAL CHEMISTRY ACCOUNTS  (2016)

Exchange Interactions on the Highest-Spin Reported Molecule: the Mixed-Valence Fe-42 Complex

Aravena, D; Venegas-Yazigi, D.; Ruiz, E

Article ISI SCOPUS
SCIENTIFIC REPORTS  (2016)

Improved Segmented All-Electron Relativistically Contracted Basis Sets for the Lanthanides

Aravena, D; Neese F.; Pantazis D.A.

Article ISI SCOPUS
JOURNAL OF CHEMICAL THEORY AND COMPUTATION  (2016)

Lanthanide Tetrazolate Complexes Combining Single-Molecule Magnet and Luminescence Properties: The Effect of the Replacement of Tetrazolate N-3 by -Diketonate Ligands on the Anisotropy Energy Barrier

Jimenez, JR; Diaz-Ortega, IF; Ruiz, E; Aravena, D; Pope, SJA; Colacio, E; Herrera, JM

Article ISI SCOPUS
CHEMISTRY-A EUROPEAN JOURNAL  (2016)

Large Conductance Switching in a Single-Molecule Device through Room Temperature Spin-Dependent Transport

Aragones, AC; Aravena, D; Cerda, JI; Acis-Castillo, Z; Li, HP; Real, JA; Sanz, F; Hihath, J; Ruiz, E; Diez-Perez, I

Article ISI SCOPUS
NANO LETTERS  (2016)

Periodic Trends in Lanthanide Compounds through the Eyes of Multireference ab Initio Theory

Aravena, D; Atanasov M.; Neese F.

Article ISI SCOPUS
INORGANIC CHEMISTRY  (2016)

Single Molecule Magnet Properties of Transition Metal Ions encapsulated in Lacunary Polyoxometalates: a Theoretical Study

Aravena, D; Venegas-Yazigi, D; Ruiz, E

Article
INORGANIC CHEMISTRY  (2016)

First principles approach to the electronic structure, magnetic anisotropy and spin relaxation in mononuclear 3d-transition metal single molecule magnets

Atanasov, Mihail; Aravena, Daniel; Suturina, Elizaveta; Bill, Eckhard; Maganas, Dimitrios; Neese, Frank

Article ISI
COORDINATION CHEMISTRY REVIEWS  (2015)

Increasing the effective energy barrier promoted by the change of a counteranion in a Zn-Dy-Zn SMM: slow relaxation via the second excited state

Oyarzabal, I; Ruiz, J.; Ruiz, E; Aravena, D; Seco, JM; Colacio, E

Article ISI SCOPUS
Chemical Communications  (2015)

Large magnetic anisotropy in mononuclear metal complexes

Gomez-Coca, Silvia; Aravena, Daniel; Morales, Roser; Ruiz, Eliseo

Article ISI
COORDINATION CHEMISTRY REVIEWS  (2015)

Neodymium 1D systems: targeting new sources for field-induced slow magnetization relaxation

Jassal, AK; Aliaga-Alcalde, N; Corbella, M; Aravena, D; Ruiz, E; Hundal, G

Article ISI SCOPUS
DALTON TRANSACTIONS  (2015)

Effect of metal complexation on the conductance of single molecular wires measured at room temperature

Ponce, Julia; Arroyo, Carlos R.; Tatay, Sergio; Frisenda, Riccardo; Gaviña, Pablo; Aravena, Daniel; Ruiz, Eliseo; van?der?Zant, Herre S. J.; Coronado, Eugenio

Article SCOPUS
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY  (2014)

Rational electrostatic design of easy-axis magnetic anisotropy in a ZnII-DyIII-ZnII single-molecule magnet with a high energy barrier

Oyarzabal, I; Ruiz, J.; Seco J.M.; Evangelisti M.; Camon A.; Ruiz, E; Aravena, D; Colacio, E

Article SCOPUS
CHEMISTRY-A EUROPEAN JOURNAL  (2014)

Spin-crossover behavior in two new supramolecular isomers

Yan, Z; Ni Z.-P.; Guo F.-S.; Li J.Y.; Chen Y.C.; Liu J.L.; Lin W.-Q.; Aravena, D; Ruiz, E; Tong M.-L.

Article SCOPUS
INORGANIC CHEMISTRY  (2014)

Two C3-Symmetric Dy3III Complexes with Triple Di-μ-methoxo-μ-phenoxo Bridges, Magnetic Ground State, and Single-Molecule Magnetic Behavior

Hänninen, Mikko M.; Mota, Antonio J.; Aravena, Daniel; Ruiz, Eliseo; Sillanpää, Reijo; Camón, Agustín; Evangelisti, Marco; Colacio, Enrique

Article SCOPUS
CHEMISTRY-A EUROPEAN JOURNAL  (2014)

CuII-GdIII Cryogenic Magnetic Refrigerants and Cu8Dy9 Single-Molecule Magnet Generated by In Situ Reactions of Picolinaldehyde and Acetylpyridine: Experimental and Theoretical Study

Lin, Wei-Quan; Chen, Yan-Cong; Gómez-Coca, Silvia; Aravena, Daniel; Ruiz, Eliseo; Leng, Ji-Dong; Tong, Ming-Liang

Article SCOPUS
CHEMISTRY-A EUROPEAN JOURNAL  (2013)

Reversible Chemisorption of Sulfur Dioxide in a Spin Crossover Porous Coordination Polymer

Arcís-Castillo, Zulema; Muñoz-Lara, Francisco J.; Muñoz, M. Carmen; Aravena, Daniel; Gaspar, Ana B.; Sánchez-Royo, Juan F.; Ruiz, Eliseo; Ohba, Masaaki; Matsuda, Ryotaro; Kitagawa, Susumu; Real, José A.

Article SCOPUS
INORGANIC CHEMISTRY  (2013)

Shedding Light on the Single-Molecule Magnet Behavior of Mononuclear DyIII Complexes

Aravena, Daniel; Ruiz, Eliseo

Article SCOPUS
INORGANIC CHEMISTRY  (2013)

Spins on a curved surface: An FeIII 14 ferracalixarene

Ako A.M.; Lan Y.; Mereacre V.; Ruiz, E; Aravena, D; Anson C.E.; Powell A.K.

Article SCOPUS
DALTON TRANSACTIONS  (2013)

Two 3d-4f nanomagnets formed via a two-step in situ reaction of picolinaldehyde

Liu J.L.; Chen Y.C.; Li Q.-W.; Gomez-Coca S.; Aravena, D; Ruiz, E; Lin W.-Q.; Leng J.-D.; Tong M.-L.

Article SCOPUS
CHEMICAL COMMUNICATIONS  (2013)

Unprecedented ferromagnetic dipolar interaction in a dinuclear holmium(III) complex: a combined experimental and theoretical study

Leng, Ji-Dong; Liu, Jun-Liang; Lin, Wei-Quan; Gómez-Coca, Silvia; Aravena, Daniel; Ruiz, Eliseo; Tong, Ming-Liang

Article SCOPUS
CHEMICAL COMMUNICATIONS  (2013)

Coherent transport through spin-crossover single molecules

Aravena, D; Ruiz, E

Article SCOPUS
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY  (2012)

Enhanced bistability by guest inclusion in Fe(II) spin crossover porous coordination polymers

Muñoz-Lara, Francisco J.; Gaspar, Ana B.; Aravena, Daniel; Ruiz, Eliseo; Muñoz, M. Carmen; Ohba, Masaaki; Ohtani, Ryo; Kitagawa, Susumu; Real, José A.

Article SCOPUS
CHEMICAL COMMUNICATIONS  (2012)

Hexanuclear copper(II) cages built on a central {μ 3- O⋯H⋯μ 3-O} moiety, 1,3-bis(dimethylamino)-2- propanolato and capping R-phosphonates: Crystal structures, magnetic behavior, and DFT studies

Speed S.; Vicente R.; Aravena, D; Ruiz, E; Roubeau O.; Teat S.J.; El Fallah M.S.

Article SCOPUS
INORGANIC CHEMISTRY  (2012)

Theoretical Study of Exchange Coupling in 3d-Gd Complexes: Large Magnetocaloric Effect Systems

Cremades, Eduard; Gómez-Coca, Silvia; Aravena, Daniel; Alvarez, Santiago; Ruiz, Eliseo

Article SCOPUS
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY  (2012)

The Dilemma of CrIIINiII Exchange Interactions: Ferromagnetism versus Antiferromagnetism

Aravena, Daniel; Ruiz, Eliseo

Article SCOPUS
CHEMISTRY-A EUROPEAN JOURNAL  (2011)

Proyecto (4)

Spin and Chirality: New strategies for spin-dependent functionality in inorganic materials

Aravena, Daniel; Lemus, luis; Spodine, Evgenia; Fuentealba, Pablo

Proyecto
 (2021)

RATIONAL DESIGN OF FUNCTIONAL MAGNETIC MATERIALS BASED ON INORGANIC MOLECULAR SYSTEMS

FONDECYT (1170524)

Proyecto
2017-2021
Inv. Responsable

Estructura electrónica y propiedades de materiales inorgánicos funcionales

PAI (82140014)

Proyecto
2015-2017
Inv. Responsable

Materiales Inorgánicos Funcionales en Base a Metales Chilenos Estratégicos - IPMaG

PIA (ACT1404)

Proyecto
2015-2018
Investigador(a)

Review (1)

Structural and electronic effects on the exchange interactions in dinuclear bis(phenoxo)-bridged copper(II) complexes

Venegas-Yazigi, D; Aravena, D; Spodine, E.; Ruiz, E; Álvarez, S.

Review ISI SCOPUS
Coordination Chemistry Reviews  (2010)

48
Daniel Aravena

Assistant Professor

Quimica de los Materiales

Universidad de Santiago de Chile

Santiago, Chile

4
Andres Vega

Director

Departamento de Química

UNIVERSIDAD ANDRES BELLO

Santiago, Chile

3
Pablo Fuentealba

Profesor Asistente

Departamento Química Inorgánica y Analítica

Universidad de Chile

Santiago, Chile

3
Luis Lemus

PROFESOR ASOCIADO

FACULTAD DE QUIMICA Y BIOLOGIA

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

2
Verónica Paredes

Academic

Ciencias Químicas

UNIVERSIDAD ANDRES BELLO

Santiago, Chile

2
Diana Dulic

Associated Professor

Physics

Universidad de Chile

Santiago, Chile

2
Patricio Cancino

Docente

Departamento de Ciencias Químicas y Farmacéuticas

Universidad de Chile

Santiago , Chile

2
Diego Venegas

Full Professor

Quimica de los Materiales

UNIVERSIDAD DE SANTIAGO DE CHILE, FACULTAD DE QUÍMICA Y BIOLOGÍA, DEPARTAMENTO DE QUÍMICA DE LOS MATERIALES

Santiago, Chile

2
Evgenia Spodine

Full Professor

Química Inorgánica y Analítica

UNIVERSIDAD DE CHILE

Santiago, Chile

2
Monica Soler

Associate Professor

Chemical Engineering, Biotechnology and Materials

University of Chile

Santiago, Chile

1
Mauricio Isaacs

Full Professor

Química Inorganica

Pontificia Universidad Católica de Chile

Santiago, Chile

1
Pablo Arce

estuadiante

Química de los materiales

Universidad de Santiago de Chile

Santiago, Chile

1
Carlos Díaz

Investigador Responsable Proyecto Postdoctorado ANID/Docente

Ingeniería Geoespacial y Ambiental

Universidad de Santiago de Chile

Santiago, Chile

1
Alejandra Gómez

Asistente

Química de los Materiales

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

1
Angelica Fierro

Associate

Chemistry

PONTIFICIA UNIVERSIDAD CATÓLICA DE CHILE

Santiago, Chile

1
Alvaro Etcheverry

Postdoctoral Research Associate

School of Chemistry

University of Edinburgh

Edinburgh, Reino Unido

1
Galo Ramírez

Profesor Asociado

Química Inorgánica

Pontificia Universidad Catolica de Chile

Santiago, Chile

1
fernando godoy

Full Professor

Quimica de los Materiales

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

1
Juan Guerrero

ACADEMICO

QUÍMICA DE LOS MATERIALES

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

1
Michelle Muñoz

Profesor por hora

Química de los Materiales

Universidad de Santiago de Chile

Santiago, Chile

1
Alejandro Castro

Académico

Ciencias Preclínicas

Universidad de La Frontera

Temuco, Chile

1
Pedro Levín

Investigador postdoctoral

Química de los materiales

Universidad de Santiago de Chile

Santiago, Chile

1
Macarena García

1
Cristian Gutiérrez

Investigador de Postdoctorado

Departemento Química de los Materiales

Universidad de Santiago de Chile

Santiago, Chile

1
ROXANA ARCE

Académica

Departamento de Ciencias Químicas

Universidad Andrés Bello

Santiago, Chile

1
Luis Santibáñez

Químico Investigación y desarrollo

Photio spa.

Santiago, Chile

1
Francesca Fuenzalida

académico asociado

Universidad de Las Américas

santiago, Chile