Man

Adalberto Hugo Klahn Oliva

Full Professor

PUCV

Valparaiso, Chile

Líneas de Investigación


Quimica Inorganica; Quimica Organometalica; Quimica Bioorganometalica; Catalysis.

Educación

  •  Chemistry, SIMON FRASER UNIVERSITY. Canada, 1987

Experiencia Académica

  •   Full Professor Full Time

    PONTIFICIA UNIVERSIDAD CATOLICA DE VALPARAISO

    Science

    Valparaiso, Chile

    1978 - At present

Experiencia Profesional

  •   Full Professor Full Time

    Pontificia Universidad Catolica de Valparaiso

    Chile

    1978 - At present

Formación de Capital Humano


Tesis Doctorales dirigidas:
1. Coordinación y Activación de Enlaces C-F y C-H en Bencenos Fluorados por Complejos Organometálicos de Renio.
Alumna: Beatriz Oelckers P.
Universidad Católica de Valparaíso, 1999.

2. Reacciones del Ligando Tetrametilfulveno Coordinado a Complejos de Renio. Alumno: Fernando Godoy G.
Universidad Católica de Valparaíso, 2003.

3. Compuestos organometálicos de cyretreno y ferroceno con potencial actividad antiparasitaria.
Alumno: Rodrigo Arancibia G.
Universidad Católica de Valparaíso, 2011.

4. Complejos Heterobinucleares derivados de ligandos ciretrenos.
Alumno: Diego Sierra.
Universidad Católica de Valparaíso, 2011.

5. Ligandos Organometálicos Piridínicos y Polipiridínicos Cyretrénicos y sus Complejos de
Coordinación.
Alumno: Teresa Cautivo S.
Universidad Católica de Valparaíso, 2012.

6.- Tesis de Pregrado: 25 tesis dirigidas de alumnos de Licenciatura en Química y Química
Industrial de las cuales 4 han sido ejecutadas durante 2004-2014.



 

Article (41)

Synthesis and characterization of thin molybdenum oxide films prepared from molybdenum dioxo tropolonate precursors by photochemical metal-organic deposition (PMOD) and its evaluation as ammonia gas sensors
Synthesis, characterization and in vitro anti-Trypanosoma cruzi and anti-Mycobacterium tuberculosis evaluations of cyrhetrenyl and ferrocenyl thiosemicarbazones
METHOXYCARBONYLATION OF STYRENE BY PALLADIUM(II) COMPLEX CONTAINING THE DIPHENYLPHOSPHINOCYRHETRENE LIGAND
Pt/WO3 thin films prepared by photochemical metal-organic deposition (PMOD) and its evaluation as carbon monoxide sensor
? 2-coordination of chlorobenzenes to rhenium fragment Cp*Re(CO) 2: Chemical and photochemical syntheses of Cp*Re(CO) 2(? 2-C 6H 6-nCl n)
Suzuki cross-coupling of aryl bromides catalyzed by cyrhetrenylphosphine complexes of palladium (II)
Synthesis and evaluation of bis-?-diketonate dioxotungsten(VI) complexes as precursors for the photodeposition of WO 3 films
Synthesis and evaluation of bis-beta-diketonate dioxotungsten(VI) complexes as precursors for the photodeposition of WO3 films
Synthesis, characterization and anti-Trypanosoma cruzi evaluation of ferrocenyl and cyrhetrenyl imines derived from 5-nitrofurane
(Z)-3-(4-Bromoanilino)-1-ferrocenylbut-2-en-1-one
Growth and characterization of molybdenum oxide thin films prepared by photochemical metal-organic deposition (PMOD)
Heterobimetallic Re=Pd complexes bridged by eta(1):eta(5)-Ph2PC5H4 ligand. Synthesis, electronic and crystal structure of (CO)(2)(PR3)(eta(5)-C5H4(PPh2)Re-P)over bardCl(2), R = Me and OMe
Synthesis and antimalarial activities of rhenium bioorganometallics based on the 4-aminoquinoline structure
Synthesis and reactivity of eta(5)-tetramethylcyclopentadienyl-propenyl rhenium complexes: Molecular structure of [(eta(5):eta(2)-C(5)Me(4)CH(2)CH=CH(2))Re(CO)(2)]
Heterobimetallic Re-Pd, Re-Au and Re-Cu complexes derived from diphenylphosphino cyrhetrene: Synthesis and X-ray structure
Reactions of cationic complex [(?5-C5Me5)Re(CO)3I]+ with primary amines leading to cyclic carbamoyl complexes
Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta(5):eta(1)-C5Me4CH2PPh2)Re(CO)(2)
Cyrhetrenylimines and cyrhetrenylamines: Synthesis, characterization and X-ray crystal structure
?-Diketones derived from cyclopentadienyl rhenium tricarbonyl
SOLID STATE PHOTOCHEMISTRY OF Cu(II) ALKYLTROPOLONATE COMPLEXES IN THIN FILMS: THE PHOTOCHEMICAL FORMATION OF HIGH QUALITY FILMS OF COPPER(I) OXIDE
Characterization of pure ZnO thin films prepared by a direct photochemical method
Reductive elimination reaction of rhenium complexes trans-(?5-C5Me5)Re(CO)2(chloroaryl)Cl
Selectivity in C-Cl bond activation of dichloroarenes by photogenerated Cp*Re(CO)(2): combined experimental and DFT studies
NICKEL TROPOLONATE COMPLEXES AS PRECURSORS FOR THE DIRECT PHOTODEPOSITION OF NiO THIN FILMS
Reaction of tetramethylfulvene rhenium complexes (?6-C 5Me4CH2Re(CO)2R (R = I, C6F5) with alkyl phosphines and trimethylphosphite. X-ray structure of [(?5-C5Me4CH2-(PMe3))Re(CO)2(PMe3)]+I-
Cis-trans isomerisation of CpRe(CO)2(H)(ArF) (ArF = C6FnH5-n; n = 0-5) is the rate determining step in C-H activation of fluoroarenes: A DFT study
Photochemical C-Cl bond activation of trichloroarenes by the rhenium complex (eta(5)-C5Me5)Re(CO)(3). X-ray structure of trans-(eta(5)-C5Me5)Re(CO)(2)(2-methoxy-4,5-dichlorophenyl)chloride
Syntheses and reactivity of functionalized (eta(5)-tetramethylcyclopentadienyl) rhenium complexes: Molecular structures of (eta(5):eta(2)-C5Me4CH2CH2CH=CH2)Re(CO)(2) and (eta(5)-C5Me4CH2-2-C4H3S)Re(CO)(2)(PMe3)
Syntheses and reactions of the complexes (?5-C5Me5)Re(CO)2 (C6Cl5-nHn)Cl (n = 2,3): Compounds derived from initial C-Cl activation
SYNTHESES AND REACTIONS OF THE COMPLEXES (N5-C5ME5)RE(CO)2(C6CL5-NHN)CL(N=2,3): COMPOUNDS DERIVED FROM INITIAL C-CL ACTIVATION
Photochemical reactions of [Re(?5-C5R5)(CO)3] (R = H or Me) with partially fluorinated benzenes: C-H and C-F activation
Synthesis and X-ray structure of the rhenium methyl complex trans-Cp*Re(CO)2(Me)I and a study of the products of photolysis of the rhenium alkyl methyl and dimethyl complexes Cp*Re(CO)2(Me)R (R = Ph, p-Tolyl, Me) under CO
SYNTHESIS AND CHARACTERIZATION OF BIS(ALKYLTROPOLONATE) URANYL COMPLEXES: NEW PRECURSORS FOR THE PHOTODEPOSITION OF THIN FILMS OF UO3
Synthesis and reactions of the rhenium fulvene complexes [Re(?6-C5Me4CH2)(CO) 2(C6F4R)] (R = F or CF3): Products derived from initial C-F activation
Direct and high yield syntheses of Re2(CO)10 and Re(CO)5 Cl by sodium reduction of K2ReCl6 under CO
Sensitized photolysis of dihydrobis(1-pyrazolyl)borate copper(II); general reaction pattern
Stepwise substitution reactions of the (?5-C5Me5) Re(CO) 2I2 complex: Aryl-iodo and aryl-methyl derivatives trans-(?5-C5Me5) Re(CO) 2(Ar) X, X = I and Me. X-ray structure of trans-(?5-C5Me5) Re(CO) 2(Ph) I
Structure and dynamics of the ?2-hexafluorobenzene complexes [Re(?5-C5H4R)(CO)2(? 2-C6F6)] (R = H or Me) and [Rh(?5-C5Me5)(PMe3)(? 2-C6F6)]
Benzophenone sensitized photochemistry of a copper(ii) polypyrazolylborate complex
The mechanism of the photoreaction of cis-(?5-C5Me5)Re(CO)2I 2 with P(OMe)3
SYNTHESES AND REACTIONS OF THE COMPLEXES (ETA(5)-C5ME5)RE(CO)(2)(C6CL5-NHN)CL (N=2,3): COMPOUNDS DERIVED FROM INITIAL C-CL ACTIVATION
42
Adalberto Klahn

Full Professor

Instituto de Quimica

PUCV

Valparaiso, Chile

14
fernando godoy

Full Professor

Quimica de los Materiales

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

6
Diego Sierra

Profesor Auxiliar

Instituto de Química y Bioquímica

Universidad de Valparaíso

Valparaíso, Chile

6
Gerardo Cabello

Académico

Ciencias Básicas

UNIVERSIDAD DEL BIO-BIO

Chillán, Chile

6
Gerardo Cabello

Academico

Departamento de Ciencias Básicas

Universidad del Bio-Bio, Chile

Chillán, Chile

5
Mauricio Fuentealba

Profesor Adjunto

Pontificia Universidad Católica de Valparaíso

Valparaíso, Chile

4
Rodrigo Arancibia

PUCV

Valparaiso, Chile

4
Eduardo Muñoz

PROFESOR TITULAR

INSTITUTO DE QUÍMICA

Pontificia Universidad Católica de Valparaíso

Valparaiso, Chile

4
Juan Maya

Full Professor

Biomedical Sciences Institute

UNIVERSIDAD DE CHILE

Santiago, Chile

3
Agustin Ibañez

DIRECTOR

INCYT

CABA, Argentina

3
Cecilia Manzur

profesora

Química Inorgánica

P. Universidad Católica de Valparaíso

Valparaíso, Chile

2
César Zúñiga

Profesor Investigador

Instituto de Ciencias Naturales

Universidad de Las Américas

Santiago, Chile

1
Alvaro Muñoz

Profesor Titular

Universidad San Sebastián

Santiago, Chile

1
Andres Vega

Director

Departamento de Química

UNIVERSIDAD ANDRES BELLO

Santiago, Chile

1
claudio olea

Full Professor

Inorganica y Analitica

UNIVERSIDAD DE CHILE

Santiago, Chile

1
Ricardo Schrebler

PROFESOR TITULAR

INSTITUTO DE QUÏMICA

Pontificia Universidad Católica de Valparaíso

VALPARAÏSO, Chile

1
Rodrigo Ramírez

Director

Direccion de Investigacion y Postgrado

Universidad de Aconcagua

Santiago, Chile

1
Michel Lapier

Académico

Química y Farmacia

Universidad de Valparaíso

Valparaíso, Chile

1
Ramiro Arratia

DIRECTOR DOCTORADO

CIENCIAS QUIMICAS

UNIVERSIDAD ANDRES BELLO

Santiago, Chile

1
Juan Oyarzo

Investigador Postdoctoral

Facultad de Ciencias

Pontificia Universidad Católica de Valparaíso

Valparaíso, Chile

1
Rodrigo del Rio

associate professor

inorganic chemistry

PONTIFICIA UNIVERSIDAD CATOLICA DE CHILE, FACULTAD DE QUIMICA, DPTO QUIMICA INORGANICA

santiago, Chile

1
Alejandra Gómez

Asistente

Química de los Materiales

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile