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Carlos Manual Diaz Valenzuela

Profesor Titular

Universidad de Chile

Santiago, Chile

Using the macromolecular metal complexes Chitosan?MXn and PS-co-4-PVP?MXn (PS-co-4-PVP = Poly(styrene-co-4-vinylpyridine), we have prepared a series of nanostructured M°, MxOy materials by their solid state pyrolysis under air and at 800°C.

Chemistry, UNIVERSIDAD DE CHILE. Chile, 1987
Chemistry, UNIVERSIDAD DE CHILE. Chile, 1987

Profesor Titular Full Time

UNIVERSIDAD DE CHILE

Ciencias

Santiago, Chile

1974 - A la fecha

Profesor Full Time

Universidad de Chile

Santiago , Chile

1987 - A la fecha

TESIS DIRIGIDAS Universidad de Chile:

Pregrado
María Luisa Valenzuela
Alejandra Pesce
Katherine Soto
Daniel Carrillo
Gonzalo Barrera
Soledad Platoni
Octavio Cadet
José Riquelme
Daniela Bobadilla
Elizabeth Franco
Gonzalo Vargas
Renato Diaz
Nancy cabezas
Rodrigo Baez (UNAB)

MAGISTER
DanielBravo
Daniel Carrillo
Gonzalo Barrera
Sandra Caceres

DOCTORADO
Alejandra Arancibia
María Luisa Valenzuela
Alejandra Pesce
Miguel Barbosa
Patricio Allende ( en tesis)
Daniel Carrillo (en etapa inicial
Cristobal Garcia (en tesis)

Posdoctorado

Svetlana Ushua


Solventless Preparation of Thoria and Its Inclusion into SiO2 and TiO2: A Luminescence and Photocatalysis Study Diaz, Carlos; Valenzuela, M. L.; Laguna-Bercero, Miguel A.; Carrillo, Daniel; Segovia, Marjorie; Mendoza, Karina; Cartes, Patricio Article ISI ACS OMEGA (2021)
Iridium nanostructured metal oxide, its inclusion in Silica matrix and their activity toward Photodegradation of Methylene Blue Díaz, Carlos, Valenzuela, Maria L. , Cifuentes-Vaca, Olga, Segovia,Marjorie, Laguna, Miguel Article MATERIALS CHEMISTRY AND PHYSICS (2020)
Incorporation of Nanostructured ReO3 in Silica Matrix and Their Activity Toward Photodegradation of Blue Methylene Diaz C.; Valenzuela M.L.; Cifuentes-Vaca O.; Segovia M.; Laguna-Bercero M.A. Article ISI SCOPUS JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2020)
Incorporation of NiO into SiO2, TiO2, Al2O3, and Na4.2Ca2.8(Si6O18) Matrices: Medium Effect on the Optical Properties and Catalytic Degradation of Methylene Blue Diaz, Carlos; Valenzuela, Maria L.; Cifuentes-Vaca, Olga; Segovia, Marjorie; Laguna-Bercero, Miguel A. Article ISI NANOMATERIALS (2020)
Iridium nanostructured metal oxide, its inclusion in silica matrix and their activity toward photodegradation of methylene blue Diaz, C.; Valenzuela, M. L.; Cifuentes-Vaca, O.; Segovia, M.; Laguna-Bercero, M. A. Article ISI MATERIALS CHEMISTRY AND PHYSICS (2020)
Polymer Precursors Effect in the Macromolecular Metal-Polymer on the Rh/RhO2/Rh(2)O(3)Phase Using Solvent-Less Synthesis and Its Photocatalytic Activity Diaz, C.; Valenzuela, M. L.; Cifuentes-Vaca, O.; Segovia, M. Article ISI JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2020)
TiO2/SiO2 Composite for Efficient Protection of UVA and UVB Rays Through of a Solvent-Less Synthesis Allende, Patricio Barrientos, Lorena Orera, Alodia Laguna, Miguel Salazar,Natalia Valenzuela, Maria Diaz Carlos a Orera, Alodia Laguina, Miguel Salazar, Article JOURNAL OF CLUSTER SCIENCE (2019)
Cylindrical Micelles by the Self-Assembly of Crystalline-b-Coil Polyphosphazene-b-P2VP Block Copolymers. Stabilization of Gold Nanoparticles Cortes, Maria de los Angeles; de la Campa, Raquel; Valenzuela, Maria Luisa; Díaz, Carlos; Carriedo, Gabino A.; Presa Soto, Alejandro Article ISI SCOPUS MOLECULES (2019)
TiO2/SiO2 Composite for Efficient Protection of UVA and UVB Rays Through of a Solvent-Less Synthesis Allende,Patricio, Barrientos, Lorena, Laguna, Miguel, Salazar, Natalia,Valenzuela, Maria M.L. , Diaz C. Article JOURNAL OF CLUSTER SCIENCE (2019)
TiO2/SiO2 Composite for Efficient Protection of UVA and UVB Rays Through of a Solvent-Less Synthesis Allende, P.; Barrientos, L.; Orera, A.; Laguna-Bercero, M. A.; Salazar, N.; Valenzuela, M. L.; Diaz, C. Article ISI SCOPUS JOURNAL OF CLUSTER SCIENCE (2019)
Solid State tuning Morphology, Crystal Phase and Size through Metal Macromolecular Complexes and Its Significance in the Photocatalytic Response Allende, Patricio, Laguna, Miguel, Barrientos, Lorena, Valenzuela, Maria L, Diaz,Carlos Article ACS APPLIED ENERGY MATERIALS (2018)
Solid State Tuning of TiO2 Morphology, Crystal Phase, and Size through Metal Macromolecular Complexes and Its Significance in the Photocatalytic Response Allende-Gonzalez, P; Laguna-Bercero, MA; Barrientos, L; Valenzuela, ML; Diaz, C Article ISI ACS APPLIED ENERGY MATERIALS (2018)
Solid-State synthesis of LnOCl/Ln2O3 (Ln = Eu,Nd) by using chitosan and PS-co-P4VP as polymeric supports. Diaz,Carlos, De la Campa, Raquel, Presa, Alejandro, Valenzuela, Maria L. Article JOURNAL OF RARE EARTHS (2018)
Solid-State synthesis of LnOCl/Ln2O3 (Ln =Eu, Nd) by using chitosan and PS-co-P4VP as polymer supports Diaz, Carlos; Carrillo, Daniel ; De la Campa, Raquel; Soto A.P., Valenzuela Article JOURNAL OF RARE EARTHS (2018)
Solution , Solid-State Two Step Synthesis and Optica Properties of ZnO and ZnO2 Nanoparticles and Their Nanocomposites with SiO2 Diaz,Carlos .; Valenzuela, Maria Luisa..Luisa.; Segovia, Marjorie.; De la Campa, Raquel Article JOURNAL OF CLUSTER SCIENCE (2018)
Solution, Solid-State Two Step Synthesis and Optical Properties of ZnO and SnO Nanoparticles and Their Nanocomposites with SiO2. Diaz, C. and Valenzuela, M.L., Segovia, Marjorie, De la Campa, Raquel, Presa, Alejandro Article JOURNAL OF CLUSTER SCIENCE (2018)
Bimetallic Au//Ag Alloys Inside SiO2 Diaz, Carlos; , Valenzuela; Bobadilla,Daniela Article JOURNAL OF CLUSTER SCIENCE (2017)
Solid-state synthesis of pure and doped lanthanides oxide nanomaterials by using polymer templates. Study of their luminescent properties Diaz. C.; Valenzuela, M.L.,Garcia, Cristobal, Dela Campa, Raquel, Presa Alejandro Article MATERIALS LETTERS (2017)
Solid-State synthesis of pure and doped lanthanides oxide nanomaterials by using polymer templates.Study of their lumiscent properties Diaz,Carlos; Valenzuela, Maria Luisa; Garcia,Cristobal; de la Campa,Raquel; Soto,A Article MATERIALS LETTERS (2017)
Synthesis and Magnetic Properties of Nanostructured metallic Co, Mn and Ni oxide materials obtained from solid-state macromolecular complex precursors Carlos Díaz, María Luisa Valenzuela, Laguna,Miguel ,Orera, Alodia ,Bobadilla,Daniela, Abarca, Sebastian , Peña, Octavio Article RSC ADVANCES (2017)
Synthesis and Magnetic Properties of Nanostructured metallic Co, Mn and Ni oxide materials obtained from solid-state macromolecular complex precursors. Diaz,Carlos, Valenzuela, Maria L. Laguna,Miguel Orera, Alodia Bobadilla,Daniela Abarca, Sebastian Peña, O Article RSC ADVANCES (2017)
Synthesis and magnetic properties of nanostructured metallic Co, Mn and Ni oxide materials obtained from solid-state metal-macromolecular complex precursors Díaz, C.; Valenzuela, M. L.; Laguna-Bercero, M. A.; Orera, A.; Bobadilla, D.; Abarca, S.; Peña, O. Article ISI SCOPUS RSC ADVANCES (2017)
Solvent-less method for efficient photocatalytic Fe2O3 nanoparticles for using macromolecular polymeric precursors Diaz, C. Barrera,G. Segovia, M.Valenzuela, M.L. Osiak,M. O´Dwyer,C.O. Article NEW JOURNAL OF CHEMISTRY (2016)
Solvent-less method for efficient photocatalytic Fe2O3 nanoparticles for using macromolecular polymeric precursors Diaz,Carlos, Barrientos,Lorena, Carrillo, Daniel, Valdebenito, Javier, Valenzuela, Maria, L. Allende, Patricio, Geaney, Hugh, O'Dwyer, Colm . Article NEW JOURNAL OF CHEMISTRY (2016)
Solvent-less method for efficient photocatalytic alfa-Fe2O3 nanoparticle using macromolecular polymeric precursors Díaz, Carlos; Barrientos, Lorena; Carrillo, Daniel; Valdebenito, Javier; Valenzuela, María Luisa; Allende, Patricio; Geaney, Hugh; O ´Dwyer,Colm Article NEW JOURNAL OF CHEMISTRY (2016)
Solvent-less method for efficient photocatalytic alpha-Fe2O3 nanoparticles using macromolecular polymeric precursors Diaz, C; Barrientos, L; Carrillo, D; Valdebenito, J; Valenzuela, ML; Allende, P; Geaney, H; O'Dwyer, C Article ISI SCOPUS NEW JOURNAL OF CHEMISTRY (2016)
Solvent-less method for efficient photocatalytic -Fe2O3 nanoparticles for using macromolecular polymeric precursors Carlos Díaz, G. Barrera, M. Segovia, María Luisa Valenzuela, M. Osiak and C. O’Dowyer. Article NEW JOURNAL OF CHEMISTRY (2016)
Crystallizing Vanadium Pentoxide Nanostructures in Solid-State using Modified Block co-Polymer and ChitosanComplexes Diaz,Carlos; Barrera,Gonzalo; Segovia,Marjorie; Valenzuela,Maria Luisa; Osiak,M Article JOURNAL OF NANOMATERIALS (2015)
Crystallizing Vanadium Pentoxide Nanostructures in the Solid State using Modified Block co-Polymer and Chitosan Complexes Diaz, Carlos, Barrera, Gonzalo , Marjorie, Segovia ,Valenzuela, Maria L., Osiak, M., O´Dwyer Article JOURNAL OF NANOMATERIALS (2015)
BIMETALLIC AU/AG METAL SUPERSTRUCTURES FROM MACROMOLECULAR METAL COMPLEXES IN SOLID-STATE Díaz, Carlos; Valenzuela, Maria Luisa; BOBADILLA, DANIELA Article ISI SCIELO SCOPUS Journal of the Chilean Chemical Society (2013)
Layered Graphitic Carbon Host Formation during Liquid-free Solid State Growth of Metal Pyrophosphates Díaz, C.; Valenzuela, M. L.; Lavayen V.; O'Dwyer C. Article ISI SCOPUS Inorganic Chemistry (2012)
POLYMER/TRIMER/METAL COMPLEX MIXTURES AS PRECURSORS OF GOLD NANOPARTICLES: TUNING THE MORPHOLOGY IN THE SOLID-STATE Díaz, Carlos; Carriedo, Gabino; Valenzuela, Maria; Zuniga, Luis; Odwyer, Colm Article JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS (2012)
SOL-GEL INCORPORATION OF ORGANOMETALLIC COMPOUNDS INTO SILICA: USEFUL PRECURSORS TO METALLIC NANOSTRUCTURED MATERIALS Díaz, C.; Valenzuela, M. L.; Garrido, D.; Aguirre P. Article ISI SCOPUS Journal of the Chilean Chemical Society (2012)
The Inclusion of Organometallic Derivatives of Cyclotriphosphazenes Inside SiO2 Matrix and Their Conversion to Nanostructured Metal-Oxides and Phosphates Díaz, C.; Carrillo, D.; Riquelme, J.; Díaz R; Valenzuela, M. L. Article ISI SCOPUS Journal of Inorganic and Organometallic Polymers and Materials (2012)
Nanostructured copper oxides and phosphates from a new solid-state route Díaz, C.; Valenzuela, ML; Lavayen V.; Mendoza K.; Pena, DO; O'Dwyer C. Article ISI SCOPUS Inorganica Chimica Acta (2011)
Nanostructured VOx/VO(PO 4) n Using Solid-State Vanadium Containing Phosphazene Precursors: A Useful Potential Bi-Catalyst System Díaz, C.; Yutronic, N; Villalobos, V.; Barrera, G; Valenzuela, M. L. Article JOURNAL OF CLUSTER SCIENCE (2011)
Nanostructured VOx/VO(PO4)(n) Using Solid-State Vanadium Containing Phosphazene Precursors: A Useful Potential Bi-Catalyst System Díaz, C.; Valenzuela, ML; Yutronic, N; Villalobos, V.; Barrera, G Article ISI SCOPUS Journal of Cluster Science (2011)
Solid-state synthesis of embedded single-crystal metal oxide and phosphate nanoparticles and in situ crystallization Díaz, C.; Valenzuela, ML; Bravo D.; Dickinson, C.; O'Dwyer C. Article ISI SCOPUS Journal of Colloid and Interface Science (2011)
Copper (II) Ions into Polyphosphazenes: Solid-Like Solution Behavior Valenzuela, ML; Díaz, C. Article ISI SCOPUS Journal of Inorganic and Organometallic Polymers and Materials (2010)
Gelation of N 3P 3[NH(CH 2) 3Si(OEt) 3] 6-n[X] n X = NH(CH 2) 3Si(OEt) 3, NCH 3(CH 2) 3CN and OC 6H 4(CH 2)CN, n = 0 or 3 at the liquid/air/ interface Díaz, C.; Yutronic, N; Valenzuela, M. L.; Aguirre P. Article Journal of the Chilean Chemical Society (2010)
Metallophosphazene Precursor Routes to the Solid-State Deposition of Metallic and Dielectric Microstructures and Nanostructures on Si and SiO2 Díaz, C.; Valenzuela, ML; Laguna, A.; Lavayen V.; Jimenez, J; Power, LA; O'Dwyer C. Article ISI SCOPUS Langmuir (2010)
Single-crystal micro/nanostructures and thin films of lamellar molybdenum oxide by solid-state pyrolysis of organometallic derivatives of a cyclotriphosphazene Díaz, C.; Lavayen V.; O'Dwyer C. Article ISI SCOPUS Journal of Solid State Chemistry (2010)
Metallocyclo- and Polyphosphazenes Containing Gold or Silver: Thermolytic Transformation into Nanostructured Materials Jimenez, J; Laguna, A.; Benouazzane, M; Sanz, JA; Díaz, C.; Valenzuela, ML; Jones, PG Article ISI SCOPUS CHEMISTRY-A EUROPEAN JOURNAL (2009)
Nanostructured Silicon Containing Materials Derived from Solid State Pyrolysis of Sililated Polyphosphazene Derivatives Díaz, C.; Valenzuela, ML; Ushak, S.; Lavayen V.; O'Dwyer C. Article ISI SCOPUS Journal of Nanoscience and Nanotechnology (2009)
Organometallic Derivatives of Cyclotriphosphazene as Precursors of Nanostructured Metallic Materials: A New Solid State Method Díaz, C.; Valenzuela, ML; Zuniga, L.; O'Dwyer C. Article ISI SCOPUS JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2009)
Polymer and oligomer phosphazene cymantrene derivatives as solid state precursors of nanostructured manganese pyrophosphate Díaz, C.; Carriedo, GA; Valenzuela, ML Article ISI SCOPUS POLYMER BULLETIN (2009)
Synthesis and Characterization of Cyclotriphosphazenes Containing Silicon as Single Solid-State Precursors for the Formation of Silicon/Phosphorus Nanostructured Materials Díaz, C.; Valenzuela, ML; Bravo D.; Lavayen V.; O'Dwyer C. Article ISI SCOPUS INORGANIC CHEMISTRY (2008)
Synthesis and Characterization of N(3)P(3)(O(2)C(12)H(8))(2)(OC(6)H(4)Si(CH(3))(3))(OC(6)H(4)Br) and Its Conversion to Nanostructured Si Material Díaz, C.; Valenzuela, ML; Ushak, S. Article ISI SCOPUS JOURNAL OF CLUSTER SCIENCE (2008)
SYNTHESIS AND CHARACTERIZATION OF N3P3(O2C12H8)(2)(OC6H4SI(CH3)(3))(OC6H4BR) AND ITS CONVERSION TO NANOSTRUCTURED SI MATERIAL Díaz, Carlos; Valenzuela, Maria; Ushak, Svetlana Article JOURNAL OF CLUSTER SCIENCE (2008)
A cyclic and polymeric phosphazene as solid state template for the formation of RuO 2 nanoparticles Díaz, C.; Valenzuela, M. L.; Spodine, E.; Moreno Y.; Peña O. Article JOURNAL OF CLUSTER SCIENCE (2007)
A cyclic and polymeric phosphazene as solid state template for the formation of RuO2 nanoparticles Díaz, C.; Valenzuela, ML; Spodine, E.; Moreno Y.; Peña O. Article ISI SCOPUS JOURNAL OF CLUSTER SCIENCE (2007)
Erratum: Photoluminiscent manganese nanoparticles from solid state polyphosphazenes organometallic derivatives (Journal of Inorganic and Organometallic Polymers and Materials DOI: 10.1007/s10904-006-9035-x) Díaz, C.; Valenzuela, M. L. Article JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2007)
Polyphosphazenes as solid templates for the formation of monometallic and bimetallic nanostructures Díaz, C.; Valenzuela, ML; Yutronic, N Article ISI SCOPUS JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2007)
Microsize and nanosize BPO 4 from pyrolysis of a carborane-substituted polyphosphazene Díaz, C.; Valenzuela, M. L.; Abizanda, D; Jimenez, J; Laguna, A. Article JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2006)
Microsize and nanosize BPO4 from pyrolysis of a carborane-substituted polyphosphazene Díaz, C.; Abizanda, D; Jimenez, J; Laguna, A.; Valenzuela, ML Article ISI SCOPUS JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2006)
Neutral AuCl complexes supported in linear high molecular weight, poly-spirophosphazene-phosphine copolymers and its conversion to nanostructured gold materials Díaz, C.; Valenzuela, ML; Carriedo, GGA; Garcia-Alonso, FJ; Presa, A Article ISI SCOPUS POLYMER BULLETIN (2006)
Organometallic derivatives of polyphosphazenes as precursors for metallic nanostructured materials Díaz, C.; Valenzuela, ML Article ISI SCOPUS JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2006)
Photoluminiscent manganese nanoparticles from solid state polyphosphazenes organometallic derivatives Díaz, C.; Valenzuela, ML Article ISI SCOPUS JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2006)
Small molecule and high polymeric phosphazenes containing oxypyridine side groups and their organometallic derivatives: Useful precursors for metal nanostructured materials Díaz, C.; Valenzuela, ML Article ISI MACROMOLECULES (2006)
Synthesis and characterization of organocyclophosphazene-silica composites: new materials able to retain metal complexes Barbosa, M.; Díaz, C.; Toral, MI; Retuert, J; Martinez, Y Article ISI SCOPUS JOURNAL OF MATERIALS CHEMISTRY (2005)
Synthesis of nanostructured materials by a new solid state pyrolysis organometallic polymer method Díaz, C.; Valenzuela, ML Article ISI SCIELO Journal of the Chilean Chemical Society (2005)
Thermolytic transformation of organometallic polymers containing the Cr(CO)(5) precursor into nanostructured chromium oxide Díaz, C.; Castillo P.; Valenzuela,M. Article ISI SCOPUS JOURNAL OF CLUSTER SCIENCE (2005)
A facile organometallic-induced cross-linking of copolymers of phosphazene Díaz, C.; Valenzuela, ML; Barbosa, M. Article ISI SCOPUS MATERIALS RESEARCH BULLETIN (2004)
A one step functionalization, coordination of N 3P 3Cl 6 using [CpFe(dppe)SC 6H 4OH] Díaz, C.; Carrasco, E; Spodine, E.; Moreno Y. Article Journal of the Chilean Chemical Society (2004)
A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3CL6 USING [CPFE(DPPE)SC6H4OH](+) Díaz, Carlos; Spodine, Evgenia; Moreno, Yanko; Carrasco, Elena Article Journal of the Chilean Chemical Society (2004)
A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+ Díaz, C.; Spodine, E.; Moreno Y.; Carrasco, E Article ISI SCIELO Journal of the Chilean Chemical Society (2004)
Monobranched and hyperbranched dendrimers based on cyclophosphazene containing nitrile and phosphine donors and their Fe and Ru organometallic derivatives Díaz, C.; Barbosa, M.; godoy Z Article ISI SCOPUS POLYHEDRON (2004)
Synthesis and characterization of soluble polyphosphazenes having pendent Cp Fe(dppe) groups Díaz, C.; Castillo P. Article ISI SCOPUS POLYMER BULLETIN (2003)
SYNTHESIS, SPECTROSCOPIC AND ELECTROCHEMICAL STUDY OF CATIONIC CICLOPENTADIENYLIRON(DIPHOSPHINE) COMPLEXES SUPPORTED ON A HIGH MOLECULAR WEIGHT PHOSPHAZENE POLYMER THROUGH NITRILE LIGANDS Carriedo, Gabino; García, Francisco; Gomez, Paloma; Díaz, Carlos Article Journal of the Chilean Chemical Society (2003)
THE REACTION OF THE BIS-SPIROCYCLIC PHOSPHAZENE [N3P3(O2C12H8)(2)CL-2](O2C12H8=2,2 -DIOXYBIPHENYL) WITH THIOPHENOLS, IN THE PRESENCE OF ALKALI CARBONATES Carriedo, Gabino; García, Francisco; López S.; Díaz, Carlos; Yutronic, Nicolas Article PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS (2003)
Cymantrene derivatives of oligomers and polyphosphazenes containing benzylcyanide spacer Díaz, C.; Castillo P.; Carriedo, GA; Gomez-Elipe, P; Alonso, FJG Article ISI SCOPUS MACROMOLECULAR CHEMISTRY AND PHYSICS (2002)
Iron-iron interaction through an ethanedithiolate ligand: a magnetic and theoretical study Costuas, K; Valenzuela, ML; Vega A.; Moreno Y.; Peña O.; Spodine, E.; Saillard, JY; Díaz, C. Article ISI SCOPUS INORGANICA CHIMICA ACTA (2002)
NEW ENTRY TO PIANO -STOOL ELECTRON RICH (PENTAMETHYL CYCLOPENTADIENYL) IRON COMPLEXES Díaz, C.; Cabezas, N; Mendizabal, F Article ISI SCIELO SCOPUS BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA (2002)
Transition metal containing dendrimers based on cyclophosphazene units Díaz, C.; Valenzuela, ML Article ISI SCOPUS POLYHEDRON (2002)
EXPONENTIAL DECAY OF A CHARGE TRANSFER INDUCED BY COORDINATION IN ORGANOMETALLIC COMPLEXES Díaz, C.; Mendizabal, F Article ISI SCIELO SCOPUS BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA (2001)
EXPONENTIAL DECAY OF A CHARGE TRANSFER INDUCED BY CORRDINATION IN ORGANOMETTALIC COMPLEXES Díaz, Carlos; Mendizabal, Fernando Article BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA (2001)
Incorporation of chromium-carbonyl fragments to bis-spirocyclophosphazene and spiro polyphosphazene containing a benzylcyanide spacer Díaz, C.; Castillo P. Article ISI SCOPUS JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS (2001)
New ruthenium(II) complexes containing organodisulfide ligands Díaz, C.; Gomez A. Article ISI JOURNAL OF COORDINATION CHEMISTRY (2001)
Dendrimers based on cyclophosphazene unit and containing iron (III) Díaz, C.; Valenzuela, ML Article ISI SCIELO SCOPUS BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA (2000)
FE (II) - FE (III) ELECTRONIC AND MAGNETIC INTERACTION THROUGH A THIOPYRIDINE BRIDGE Díaz, C.; Spodine, E.; Moreno Y.; Arancibia A. Article ISI SCIELO SCOPUS BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA (2000)
Intervalence electron transfer through a thiolate bridge ligand: a Fe-III-S-R-Fe-II mixed valence complex Díaz, C.; Arancibia A. Article ISI POLYHEDRON (2000)
Intervalence electron transfer through a thiolate bridge ligand: A FeIIIS-R-FeII mixed valence complex Díaz, C.; Arancibia A. Article SCOPUS POLYHEDRON (2000)
Metal-metal interaction through CH2-CN bridge: synthesis and characterization of [CpM(L-2) NCCH(2)Fc]PF6 complexes (Fc = ferrocenyl; L=1/2 dppe, PPh3; M = Fe,Ru) Díaz, C.; Izquierdo, I; Valenzuela, ML; Yutronic, N Article ISI SCOPUS INORGANIC CHEMISTRY COMMUNICATIONS (2000)
S-H bond cleavage in molecules of biological interest with CpFe(dppe)I Díaz, C.; Pesce, A Article ISI APPLIED ORGANOMETALLIC CHEMISTRY (2000)
TCNE and TCNQ ligands as efficient bridges in mixed-valence complexes containing iron-cyclopentadienyl and other organometallic systems Díaz, C.; Arancibia A. Article ISI SCOPUS POLYHEDRON (2000)
Iron and ruthenium organometallic derivatives of spiro-substituted cyclotriphosphazenes bearing nitrile spacer: Synthesis and electronic structure Díaz, C.; Izquierdo, I; Mendizabal, F; Yutronic, N Article INORGANICA CHIMICA ACTA (1999)
OBSERVATION OF STABLE 17 e IRON(III) CYCLOPENTADIENYL RADICAL COMPLEXES Díaz, C. Article SCIELO BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA (1999)
THE CRYSTAL STRUCTURE OF A NOVEL SULFENAMIDE: (N,N-DIBENZYL)BENCENESULFENAMIDE Brito, I; Díaz, C.; Gonzalez G. ; Manriquez, V.; Rodriguez M.L. Article SCIELO BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA (1999)
An evidence of mixed-valence electron transfer in the inverted Marcus region Díaz, C.; Arancibia A. Article BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA (1998)
Molecular encapsulation of half-sandwich complexes of iron with cyclodextrins: New laminar materials Díaz, C.; Arancibia A. Article JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY (1998)
Monodentate and bridging behavior of dinitriles ligands toward the fragment Cp(dppe)Fe+ Díaz, C.; Arancibia A. Article BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA (1998)
Redox properties of 17-electron thiolate complexes of cyclopentadienyl iron (III) Díaz, C.; Araya, E.; Santa Ana M.A. Article POLYHEDRON (1998)
The cyanide ligand as an efficient bridge in mixed-valence complexes Díaz, C.; Arancibia A. Article INORGANICA CHIMICA ACTA (1998)
Donor-acceptor properties of the methyl cyanide and methyl isocyanide ligands towards the fragment CpFe(dppe) Díaz, C.; Yutronic, N Article Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry (1997)
Monodentated, bridged and chelated behaviour of diphosphines towards the fragment CpFe (dppe)+ Díaz, C.; Araya, E. Article POLYHEDRON (1997)
Solvent effect on the oxidative addition of HS-C6H4Br to CpFe(dppe)+; a reaction involving an Fe-S intramolecular electron transfer Díaz, C.; Montecinos R. Article BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA (1997)
Sulfur-hydrogen bond activation of thiols by the fragment CpFe(dppe)+: Cyclopentadienyl iron(III) thiolate complexes Díaz, C. Article POLYHEDRON (1997)
Coordinating properties of some solvents towards the fragment CpFe(dppe)+ Díaz, C.; Yutronic, N Article POLYHEDRON (1996)
Inclusion compounds of half-sandwich complexes of iron with cyclodextrins: Unprecedented laminar structures Díaz, C.; Arancibia A. Article BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA (1996)
Oxidative addition of disulfides to the fragment CpFe(dppe) +: Steric and dielectric medium control on the reaction Díaz, C.; Leal C.; Yutronic, N Article JOURNAL OF ORGANOMETALLIC CHEMISTRY (1996)
S-S cleavage in disulphides by the fragment CpFe(dppe)+ Díaz, C.; Leal C.; Yutronic, N Article BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA (1996)
Thermal behaviour of benzenesulfenamides and of their chromium carbonyl complexes Manriquez, V.; Díaz, C.; Gonzalez G. ; Brito, I Article Journal of Thermal Analysis (1996)
A characteristic redox reaction for N,N' thiobisamines and some other S(II) compounds” Díaz, C. Article POLYHEDRON
A Reversible Oxidative Addition of HSCH2CH2SH to The Fragment CpFe(dppe); Medium Control of the Reaction Díaz, C. Article Bol. Soc. Chil. Quim
Alkoxythioamines Díaz, C. et all. Article Phosphorus and Sulfur
Bimetallic Au//Ag Alloys Inside SiO2 Using a Solid-State Method Diaz, Carlos, Valenzuela,Maria L., Bobadilla, Daniela, Laguna Miguel A. Article JOURNAL OF CLUSTER SCIENCE
C5H5-diphenylphosphinoethane iron (II) derivatives from (n-C5H5)Fe(CO)2I.Synthesis and Mössbauer spectra Díaz, C. and Latorre, R. Article Bol. Soc. Chi. Quim.
Cis-trans isomeric influence on the reactivity of BrMn(CO)2dppmP(OPh)3 towards dialkylthioethers Diaz, C. and Leal, C. Article POLYHEDRON
Cis-Trans Isomerism in the complex BrMn(CO)2dppm P(OPh)3. An Electronic spectroscopy study Díaz, C.; Yutronic, N. Article SPECTROSCOPY LETTERS
Comparison of the oxidation of dinuclear cyclopentadienyl iron diphosphine complexes with the bridging ligands-CN and-C=C (CH2)2CN Carriedo, A.; Arancibia, A.; Díaz-Valenzuela, C.; Yutronic, N.; Pérez Carreño, E.; García-Granda, S. Article Journal Organometallic Chemistry
Coordination of (N,-N'-Dibenzyl)-benzene sulfenamide, via sulfur atom. Crystal and Molecular Structure of (C6H5CH2)2NS(C6H5)Cr(CO)5 Díaz, C. et all. Article Journal Organometallic Chemistry
Coordination properties of some solvents in Cr(CO)5L complexes Díaz, C. and Yutronic, N Article POLYHEDRON
Crystal structure of Methylsulfenamide Pentacarbonyl Chromium (0). A complex with a short Cr-S Bond Díaz, C.; Manriquez, V; et all Article Bol. Soc. Chi. Quim.
Dioxybiphenyl and chiral dioxybinaphthyl Polyphosphazene random copolymers carrying carboxylic acids and their reactions with ε- caprolactam to form nylon-6-branched phosphazene materials Carriedo, G.; Diaz, C.; Valenzuela, M.L. and Garcia-Alonso, F.J. Article MACROMOLECULES
Donor-acceptor molecular complexes of the thiobisphaltalimide with diphenylamine and potassium thiocyanate Díaz, C.; Copaja, S. and Gonzales, G. Article Acta Sudamericana de Quimica
Electrochemical oxidation of monosubstituted chromium carbonyl complexes. Ligand and solvent effect Díaz, C. et all. Article J. Chem. Soc., Dalton Trans
ESCA studies of N,N'-thiobisamines and of their chromium, carbonyl complexes Díaz, C. et all. Article Zeitschrift für Natuforschung
Espectros Infrarrojos de la N,N'-tiobisdimetilamina y sus derivados Díaz, C. Article Acta Sudamericana de Química
Generation of thionitroso compounds from N,N'-thiodiamines. A molecular orbital study Diaz, C. and Weiss, B. Article Phosphorus, Sulfur, and Silicon
Identification of lowest excited state in the complex Cr(CO)5PBu3 Díaz, C. and Yutronic, N Article POLYHEDRON
Identification of Lowest excited States in the Organometallic iron-Nitrile Complexes”. Díaz, C. Article Bol. Soc. Chil. Quim
Infrared and Raman study of thiobisamines Díaz, C.; Clavijo, E. and Gonzales, G. Article Spectrochim. Acta
Interation of thiourea with sulfur divalent compounds: Desulfurization of thiourea by N,N'-Thiobismorpholine Díaz, C.; Bustos, O. and Yutronic, N. Article Phosphorus, Sulfur and Silicon
Ionization of the Fe-X bond in polar solvents: a spectroscopic study of CpFe(dppe)X complexes Díaz, C.; Yutronic, N. and Weiss, B. Article POLYHEDRON
IR and 'H-NMR characterization of Sulfenamides Díaz, C.; Cuevas, G. and González, G. Article Sulfur Letter
Iron (II) and manganese (I) complexes containing diphosphine ligands. An infrared study of BrMn(CO)2 (dpmm)P(OPh)3 and CpFe(dppe)R(R=I, CN) Campos, M.; Díaz, C.; Figueroa, K.; Padilla. L. and Lara, N. Article VIBRATIONAL SPECTROSCOPY
Iron and Ruthenium Derivatives of Cyclophosphazenes Coordinated Through Nitrile Spacer Ligands Diaz, C. and Izquierdo, I. Article POLYHEDRON
Luminescent Gold and Silver Complexes with the Monophosphane 1‐(PPh2)‐2-Me‐C2B10H10 and Their Conversion to Gold Micro- and Superstructured Materials. Inorganic Chemistry crespo, O.; Diaz, C.; O’Dwyer, O.; Gimeno, M. C.; Laguna, A.; Ospino, I. and Valenzuela, M.L. Article Inorganic Chemistry
N,N-Thiodianilines. Detection of thionitrosobenzene derivatives Díaz, C.; Benavente, E. and González, G. Article Phosphorus, Sulfur, and Silicon
New Complexes [CpFe(dppe)thiophenes]PF6 Diaz, C. and Leal, C. Article POLYHEDRON
NEW ENTRY TO PIANO - STOOL ELECTRON RICH (PENTAMETHYL CYCLOPENTADIENYL) IRON COMPLEXES Díaz, Carlos; Cabezas, Nancy; Mendizabal, Fernando Article BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA
Novel Solid-State Route to nanostructured Tin, Zinc and Cerium Oxides as Potencial Materials for Sensors Diaz, C.; Valenzuela, M.L.; Platoni, S.; Molina, A.; Geaney, H. and O'Dwyer, C Article JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
Preparation of new cationic complexes [(n5-C5H5)Fe(dppe)L]PF6 with sulphur and other donor ligands Díaz, C. and Arancibia, A. Article POLYHEDRON
Properties of dioxybiphenyl- and chiral dioxybinaphthyl phosphazene copolymers with propyl-carboxylate-phenoxy units and the randomization of the substitution reactions of poly(dichlorophosphazene) Carriedo, G.; Diaz, C.; Valenzuela, M.L.; Fidalgo, I.; Garcia-Alonso, F.J.; and Presa, S. Article MACROMOLECULES
Reactivity of Sulfur(II) compounds. Chemical properties and frontier molecular orbital analysis Díaz, C. et all. Article Phosphorus and Sulfur
Reaktionen von Diaminosulfanen mit Kupfer (II) - Salzen Díaz, C.; Copaja, S. and Gonzales, G. Article MONATSHEFTE FUR CHEMIE
Redox and coordinated properties of N,N'-Dithiobisamines: Oxidative Desulphuration by Cu (II) ions and Cr(CO)5 S2(NR2) 2 complexes Díaz, C.; Yutronic, N. and Weiss, B. Article POLYHEDRON
Role of the linking of metallic centers to macromolecular and oligomeric systems in the pyrolytic products Diaz, C.; Valenzuela, M.L.; and Zuñiga, L. Article Journal of the Chilean Chemical Society
Solid State Pathways to Complex Shape Evolution and Tunable Porosity During Metallic Crystal Growth. Diaz, C.; Valenzuela, M.L.; Carriedo, G.; Zuñiga, L. and O'Dwyer, C Article SCIENTIFIC REPORTS
Solid state synthesis of micro and nanostructured metal oxides using organometallic-polymers precursors Diaz, C. and M.L.Valenzuela Article Journal Chilean Chemical Society
Solution and surfactant-free growth of supported high index facet SERS active nano particles of rhenium by phase demixing Diaz, C.; Valenzuela, M.L.; Caceres, S.; O'Dwyer, C Article JOURNAL OF MATERIALS CHEMISTRY A
Solution and surfactant-free growth of supported high index facet SERS actu Diaz, C.; Valenzuela, M.L.; Caceres, S.; O'Dwyer, C Article Journal Chilean Chemical Society
Solvent and stabilizer free growth of Ag and Pd nanoparticles using Metallic salts/cyclotriphosphazenes mixtures Diaz, C.; Valenzuela, M.L.; Caceres, S.; R. Diaz, R. and O'Dwyer, C Article Material Chem. Phis.
Solvent effect on the infrared and 1H-NMR spectra of N,N'- thodianilines Díaz, C. et all. Article Phosphorus, Sulfur and Silicon
Spectroscopic properties of N,N'-dithiobisamines and their cyclic analogues N,N'- dialkylcyclotetrasulfur-1,4-diimides Díaz, C. and Arancibia, A. Article Phosphorus and Sulphur
Structure of (N,N'-dicyclohexyl) benzenesulfenamide and its pentacarbonyl chromium (O) complex via sulfur atom Díaz, C. et all. Article Journal Organometallic Chemistry
Structure of Pentacarbonyl-(morpholin) Chromium (O) Díaz, C. et all. Article Acta Crist. C
Sulfenamides as ligands in transition metal chemistry. Pentacarbonyl (Sulfenamide) Chromium (0) complexes Díaz, C. et all. Article Z. Anorg. Allg. Chem.
Sulphur (II) - metal coordination compounds. Group VI metal carbonyl complexes with N,N' - thiobisamine ligands Díaz, C. and Gonzales, G. Article Inorganic Chem. Acta
Sulphur(II) compounds as ligands. Chromium pentacarbonyl complexes with alkoxythioamines as ligands Díaz, C. Article Sulfur Letters
Sulphurating and coordinating properties of N,N'-Thiobismorpholine towards iron Carbonyls Díaz, C. Article POLYHEDRON
Synthesis and oxidation of cationic heterobinuclear Cyanide-Bridged Complexes of Manganese and iron Díaz, C. et all. Article Inorganic Chemisty
Synthesis and Pyrolysis of Silicon and Tin containing Poly-2,2’-dioxy-1,1’ biphenoxyphosphazene Carriedo, G.; Diaz, C.; Valenzuela, M.L.; and Ushak, S. Article EUROPEAN POLYMER JOURNAL
Synthesis and thermal decarbonylation of W(CO)5 complexes supported by nitrile, pyridine and phosphine ligands to polyspirophosphazene random copolymers carryng OC6H4CO2Pr group Carriedo, G.; Diaz, C.; Valenzuela, M.L. and Garcia-Alonso, F.J. Article POLYHEDRON
Synthesis of disubstituted ammonium trichlorodicuprate (I) from the reaction of CuCl2.2H2O with N,N'thiobisamines Díaz, C. Article POLYHEDRON
Synthesis of new carbonyl complexes of manganese (I) containing monodentate Ph2PCH2PPh2(dppm) Díaz, C. et all. Article Journal Organometallic Chemistry
The 1A1 → 1E transition as a measure of the π-acceptor ability in M(CO)5L complexes" Díaz, C. and Yutronic, N Article POLYHEDRON
The crystal structure of the Hydrogen Bonded Molecular adduct Thiobisphtalimide. Diphenylamine Díaz, C. et all. Article Phosphorus, Sulfur and Silicon
the first spectroscopic evidence for the existence of substituted thionitrosobenzene, X-C6H4N=S, as an intermediate in the thermal decomposition of N,N-thiodianilines Díaz, C.; Benavente, E. and González, G. Article bol. Soc. Chi. Quim.
The mass spectral fragmentation of N,N'-Dithiobisamines and their Cyclic Analogues 3,6-Dialkyl-1,2,4,5,3,6-Tetrathiadiazines Díaz, C. Article Phosphorus and Su
The S-S Bond in N,N'-Dithiobisamines. A Raman study Díaz, C. and Yutronic, N Article Phosphorus, Sulfur and Silicon
Unexpected reaction of sulphur dichloride with Cr(CO)5THF: A Cr(III)product without carbon monoxide as ligand Díaz, C. Article POLYHEDRON


A General Solid-State approach to metallic, metal oxides and Phosphates Nanoparticles Diaz, C. and Valenzuela, M.L.; Taylor, J.C BookSection
Coordination of Organometallic Fragments to Polyphospahzenes Containing Side Groups with Donor Atoms Diaz, C. and Valenzuela, M.L.; Bregg, R.K BookSection
Metallic Nanostructures using Oligo and Polyphosphazenes as Template /stabilizer in solid state Diaz, C. and Valenzuela, M.L.; Nalwa, H.S. BookSection
Nanostructured Materials from Solid-State Pyrolysis of Organometallic Derivatives of Phospahzenes Diaz, C. and Valenzuela, M.L.; Donahue, W.S and Brandt, J.C. BookSection
Organometallic-Metallic-Cyclotriphosphazene Mixtures : Solid-State Method for Metallic Nanoparticle Growth Diaz, C. and Valenzuela, M.L.; Chow, P.E. BookSection
Solution and Solid State Methods to prepare Au Nanoparticles : A comparison Diaz, C. and Valenzuela, M.L.; P.E. Chow BookSection
Synthesis and Characterization of Organometallic Polyphospazenes and their Applications in Nanoscience Diaz, C. and Valenzuela, M.L.; Adrianov, A. BookSection


Chemical Study of Metal Nanodecoration onto Select Guests partially Included in Cyclodextrins FONDECYT (1160114) Proyecto 2016-2019 Coinvestigador(a)
Metal and metal oxides nanostructured materials inside solid matrix by a new method=> Matrix effect on nanostructured metal and metal oxides FONDECYT (1160241) Proyecto 2016-2019 Inv. Responsable
NEW MATERIALS BASED IN POLYSPIROPHOSPHAZENE FUNCTIONALIZED FONDECYT (1130416) Proyecto 2013-2017 Coinvestigador(a)
FABRICATION OF METALLIC AND METAL OXIDES NANOPARTICLES BY A NEW SOLID-STATE METHOD USING MACROMOLECULAR METAL COMPLEXES FONDECYT (1120179) Proyecto 2012-2016 Inv. Responsable
“Preparation of metallic nanostructured materials from organometallic derivatives of cyclotriphosphazenes and its inclusion inside solid matrix” Díaz, C.; Valenzuela, M. L. Proyecto (2008)