Man

Carlos Manual Diaz Valenzuela

Profesor Titular

Universidad de Chile

Santiago, Chile

Líneas de Investigación


Using the macromolecular metal complexes Chitosan?MXn and PS-co-4-PVP?MXn (PS-co-4-PVP = Poly(styrene-co-4-vinylpyridine), we have prepared a series of nanostructured M°, MxOy materials by their solid state pyrolysis under air and at 800°C.

Educación

  •  Chemistry, UNIVERSIDAD DE CHILE. Chile, 1987
  •  Chemistry, UNIVERSIDAD DE CHILE. Chile, 1987

Experiencia Académica

  •   Profesor Titular Full Time

    UNIVERSIDAD DE CHILE

    Ciencias

    Santiago, Chile

    1974 - A la fecha

Experiencia Profesional

  •   Profesor Full Time

    Universidad de Chile

    Santiago , Chile

    1987 - A la fecha

Formación de Capital Humano


TESIS DIRIGIDAS Universidad de Chile:

Pregrado
María Luisa Valenzuela
Alejandra Pesce
Katherine Soto
Daniel Carrillo
Gonzalo Barrera
Soledad Platoni
Octavio Cadet
José Riquelme
Daniela Bobadilla
Elizabeth Franco
Gonzalo Vargas
Renato Diaz
Nancy cabezas
Rodrigo Baez (UNAB)

MAGISTER
DanielBravo
Daniel Carrillo
Gonzalo Barrera
Sandra Caceres

DOCTORADO
Alejandra Arancibia
María Luisa Valenzuela
Alejandra Pesce
Miguel Barbosa
Patricio Allende ( en tesis)
Daniel Carrillo (en etapa inicial
Cristobal Garcia (en tesis)

Posdoctorado

Svetlana Ushua



 

Article (162)

Solventless Preparation of Thoria and Its Inclusion into SiO2 and TiO2: A Luminescence and Photocatalysis Study
Iridium nanostructured metal oxide, its inclusion in Silica matrix and their activity toward Photodegradation of Methylene Blue
Incorporation of Nanostructured ReO3 in Silica Matrix and Their Activity Toward Photodegradation of Blue Methylene
Incorporation of NiO into SiO2, TiO2, Al2O3, and Na4.2Ca2.8(Si6O18) Matrices: Medium Effect on the Optical Properties and Catalytic Degradation of Methylene Blue
Iridium nanostructured metal oxide, its inclusion in silica matrix and their activity toward photodegradation of methylene blue
Polymer Precursors Effect in the Macromolecular Metal-Polymer on the Rh/RhO2/Rh(2)O(3)Phase Using Solvent-Less Synthesis and Its Photocatalytic Activity
TiO2/SiO2 Composite for Efficient Protection of UVA and UVB Rays Through of a Solvent-Less Synthesis
Cylindrical Micelles by the Self-Assembly of Crystalline-b-Coil Polyphosphazene-b-P2VP Block Copolymers. Stabilization of Gold Nanoparticles
TiO2/SiO2 Composite for Efficient Protection of UVA and UVB Rays Through of a Solvent-Less Synthesis
TiO2/SiO2 Composite for Efficient Protection of UVA and UVB Rays Through of a Solvent-Less Synthesis
Solid State tuning Morphology, Crystal Phase and Size through Metal Macromolecular Complexes and Its Significance in the Photocatalytic Response
Solid State Tuning of TiO2 Morphology, Crystal Phase, and Size through Metal Macromolecular Complexes and Its Significance in the Photocatalytic Response
Solid-State synthesis of LnOCl/Ln2O3 (Ln = Eu,Nd) by using chitosan and PS-co-P4VP as polymeric supports.
Solid-State synthesis of LnOCl/Ln2O3 (Ln =Eu, Nd) by using chitosan and PS-co-P4VP as polymer supports
Solution , Solid-State Two Step Synthesis and Optica Properties of ZnO and ZnO2 Nanoparticles and Their Nanocomposites with SiO2
Solution, Solid-State Two Step Synthesis and Optical Properties of ZnO and SnO Nanoparticles and Their Nanocomposites with SiO2.
Bimetallic Au//Ag Alloys Inside SiO2
Solid-state synthesis of pure and doped lanthanides oxide nanomaterials by using polymer templates. Study of their luminescent properties
Solid-State synthesis of pure and doped lanthanides oxide nanomaterials by using polymer templates.Study of their lumiscent properties
Synthesis and Magnetic Properties of Nanostructured metallic Co, Mn and Ni oxide materials obtained from solid-state macromolecular complex precursors
Synthesis and Magnetic Properties of Nanostructured metallic Co, Mn and Ni oxide materials obtained from solid-state macromolecular complex precursors.
Synthesis and magnetic properties of nanostructured metallic Co, Mn and Ni oxide materials obtained from solid-state metal-macromolecular complex precursors
Solvent-less method for efficient photocatalytic Fe2O3 nanoparticles for using macromolecular polymeric precursors
Solvent-less method for efficient photocatalytic Fe2O3 nanoparticles for using macromolecular polymeric precursors
Solvent-less method for efficient photocatalytic alfa-Fe2O3 nanoparticle using macromolecular polymeric precursors
Solvent-less method for efficient photocatalytic alpha-Fe2O3 nanoparticles using macromolecular polymeric precursors
Solvent-less method for efficient photocatalytic -Fe2O3 nanoparticles for using macromolecular polymeric precursors
Crystallizing Vanadium Pentoxide Nanostructures in Solid-State using Modified Block co-Polymer and ChitosanComplexes
Crystallizing Vanadium Pentoxide Nanostructures in the Solid State using Modified Block co-Polymer and Chitosan Complexes
BIMETALLIC AU/AG METAL SUPERSTRUCTURES FROM MACROMOLECULAR METAL COMPLEXES IN SOLID-STATE
Layered Graphitic Carbon Host Formation during Liquid-free Solid State Growth of Metal Pyrophosphates
POLYMER/TRIMER/METAL COMPLEX MIXTURES AS PRECURSORS OF GOLD NANOPARTICLES: TUNING THE MORPHOLOGY IN THE SOLID-STATE
SOL-GEL INCORPORATION OF ORGANOMETALLIC COMPOUNDS INTO SILICA: USEFUL PRECURSORS TO METALLIC NANOSTRUCTURED MATERIALS
The Inclusion of Organometallic Derivatives of Cyclotriphosphazenes Inside SiO2 Matrix and Their Conversion to Nanostructured Metal-Oxides and Phosphates
Nanostructured copper oxides and phosphates from a new solid-state route
Nanostructured VOx/VO(PO 4) n Using Solid-State Vanadium Containing Phosphazene Precursors: A Useful Potential Bi-Catalyst System
Nanostructured VOx/VO(PO4)(n) Using Solid-State Vanadium Containing Phosphazene Precursors: A Useful Potential Bi-Catalyst System
Solid-state synthesis of embedded single-crystal metal oxide and phosphate nanoparticles and in situ crystallization
Copper (II) Ions into Polyphosphazenes: Solid-Like Solution Behavior
Gelation of N 3P 3[NH(CH 2) 3Si(OEt) 3] 6-n[X] n X = NH(CH 2) 3Si(OEt) 3, NCH 3(CH 2) 3CN and OC 6H 4(CH 2)CN, n = 0 or 3 at the liquid/air/ interface
Metallophosphazene Precursor Routes to the Solid-State Deposition of Metallic and Dielectric Microstructures and Nanostructures on Si and SiO2
Single-crystal micro/nanostructures and thin films of lamellar molybdenum oxide by solid-state pyrolysis of organometallic derivatives of a cyclotriphosphazene
Metallocyclo- and Polyphosphazenes Containing Gold or Silver: Thermolytic Transformation into Nanostructured Materials
Nanostructured Silicon Containing Materials Derived from Solid State Pyrolysis of Sililated Polyphosphazene Derivatives
Organometallic Derivatives of Cyclotriphosphazene as Precursors of Nanostructured Metallic Materials: A New Solid State Method
Polymer and oligomer phosphazene cymantrene derivatives as solid state precursors of nanostructured manganese pyrophosphate
Synthesis and Characterization of Cyclotriphosphazenes Containing Silicon as Single Solid-State Precursors for the Formation of Silicon/Phosphorus Nanostructured Materials
Synthesis and Characterization of N(3)P(3)(O(2)C(12)H(8))(2)(OC(6)H(4)Si(CH(3))(3))(OC(6)H(4)Br) and Its Conversion to Nanostructured Si Material
SYNTHESIS AND CHARACTERIZATION OF N3P3(O2C12H8)(2)(OC6H4SI(CH3)(3))(OC6H4BR) AND ITS CONVERSION TO NANOSTRUCTURED SI MATERIAL
A cyclic and polymeric phosphazene as solid state template for the formation of RuO 2 nanoparticles
A cyclic and polymeric phosphazene as solid state template for the formation of RuO2 nanoparticles
Erratum: Photoluminiscent manganese nanoparticles from solid state polyphosphazenes organometallic derivatives (Journal of Inorganic and Organometallic Polymers and Materials DOI: 10.1007/s10904-006-9035-x)
Polyphosphazenes as solid templates for the formation of monometallic and bimetallic nanostructures
Microsize and nanosize BPO 4 from pyrolysis of a carborane-substituted polyphosphazene
Microsize and nanosize BPO4 from pyrolysis of a carborane-substituted polyphosphazene
Neutral AuCl complexes supported in linear high molecular weight, poly-spirophosphazene-phosphine copolymers and its conversion to nanostructured gold materials
Organometallic derivatives of polyphosphazenes as precursors for metallic nanostructured materials
Photoluminiscent manganese nanoparticles from solid state polyphosphazenes organometallic derivatives
Small molecule and high polymeric phosphazenes containing oxypyridine side groups and their organometallic derivatives: Useful precursors for metal nanostructured materials
Synthesis and characterization of organocyclophosphazene-silica composites: new materials able to retain metal complexes
Synthesis of nanostructured materials by a new solid state pyrolysis organometallic polymer method
Thermolytic transformation of organometallic polymers containing the Cr(CO)(5) precursor into nanostructured chromium oxide
A facile organometallic-induced cross-linking of copolymers of phosphazene
A one step functionalization, coordination of N 3P 3Cl 6 using [CpFe(dppe)SC 6H 4OH]
A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3CL6 USING [CPFE(DPPE)SC6H4OH](+)
A ONE STEP FUNCTIONALIZATION, COORDINATION OF N3P3Cl6 USING [CpFe(dppe)SC6H4OH]+
Monobranched and hyperbranched dendrimers based on cyclophosphazene containing nitrile and phosphine donors and their Fe and Ru organometallic derivatives
Synthesis and characterization of soluble polyphosphazenes having pendent Cp Fe(dppe) groups
SYNTHESIS, SPECTROSCOPIC AND ELECTROCHEMICAL STUDY OF CATIONIC CICLOPENTADIENYLIRON(DIPHOSPHINE) COMPLEXES SUPPORTED ON A HIGH MOLECULAR WEIGHT PHOSPHAZENE POLYMER THROUGH NITRILE LIGANDS
THE REACTION OF THE BIS-SPIROCYCLIC PHOSPHAZENE [N3P3(O2C12H8)(2)CL-2](O2C12H8=2,2 -DIOXYBIPHENYL) WITH THIOPHENOLS, IN THE PRESENCE OF ALKALI CARBONATES
Cymantrene derivatives of oligomers and polyphosphazenes containing benzylcyanide spacer
Iron-iron interaction through an ethanedithiolate ligand: a magnetic and theoretical study
NEW ENTRY TO PIANO -STOOL ELECTRON RICH (PENTAMETHYL CYCLOPENTADIENYL) IRON COMPLEXES
Transition metal containing dendrimers based on cyclophosphazene units
EXPONENTIAL DECAY OF A CHARGE TRANSFER INDUCED BY COORDINATION IN ORGANOMETALLIC COMPLEXES
EXPONENTIAL DECAY OF A CHARGE TRANSFER INDUCED BY CORRDINATION IN ORGANOMETTALIC COMPLEXES
Incorporation of chromium-carbonyl fragments to bis-spirocyclophosphazene and spiro polyphosphazene containing a benzylcyanide spacer
New ruthenium(II) complexes containing organodisulfide ligands
Dendrimers based on cyclophosphazene unit and containing iron (III)
FE (II) - FE (III) ELECTRONIC AND MAGNETIC INTERACTION THROUGH A THIOPYRIDINE BRIDGE
Intervalence electron transfer through a thiolate bridge ligand: a Fe-III-S-R-Fe-II mixed valence complex
Intervalence electron transfer through a thiolate bridge ligand: A FeIIIS-R-FeII mixed valence complex
Metal-metal interaction through CH2-CN bridge: synthesis and characterization of [CpM(L-2) NCCH(2)Fc]PF6 complexes (Fc = ferrocenyl; L=1/2 dppe, PPh3; M = Fe,Ru)
S-H bond cleavage in molecules of biological interest with CpFe(dppe)I
TCNE and TCNQ ligands as efficient bridges in mixed-valence complexes containing iron-cyclopentadienyl and other organometallic systems
Iron and ruthenium organometallic derivatives of spiro-substituted cyclotriphosphazenes bearing nitrile spacer: Synthesis and electronic structure
OBSERVATION OF STABLE 17 e IRON(III) CYCLOPENTADIENYL RADICAL COMPLEXES
THE CRYSTAL STRUCTURE OF A NOVEL SULFENAMIDE: (N,N-DIBENZYL)BENCENESULFENAMIDE
An evidence of mixed-valence electron transfer in the inverted Marcus region
Molecular encapsulation of half-sandwich complexes of iron with cyclodextrins: New laminar materials
Monodentate and bridging behavior of dinitriles ligands toward the fragment Cp(dppe)Fe+
Redox properties of 17-electron thiolate complexes of cyclopentadienyl iron (III)
The cyanide ligand as an efficient bridge in mixed-valence complexes
Donor-acceptor properties of the methyl cyanide and methyl isocyanide ligands towards the fragment CpFe(dppe)
Monodentated, bridged and chelated behaviour of diphosphines towards the fragment CpFe (dppe)+
Solvent effect on the oxidative addition of HS-C6H4Br to CpFe(dppe)+; a reaction involving an Fe-S intramolecular electron transfer
Sulfur-hydrogen bond activation of thiols by the fragment CpFe(dppe)+: Cyclopentadienyl iron(III) thiolate complexes
Coordinating properties of some solvents towards the fragment CpFe(dppe)+
Inclusion compounds of half-sandwich complexes of iron with cyclodextrins: Unprecedented laminar structures
Oxidative addition of disulfides to the fragment CpFe(dppe) +: Steric and dielectric medium control on the reaction
S-S cleavage in disulphides by the fragment CpFe(dppe)+
Thermal behaviour of benzenesulfenamides and of their chromium carbonyl complexes
A characteristic redox reaction for N,N' thiobisamines and some other S(II) compounds”
A Reversible Oxidative Addition of HSCH2CH2SH to The Fragment CpFe(dppe); Medium Control of the Reaction
Alkoxythioamines
Bimetallic Au//Ag Alloys Inside SiO2 Using a Solid-State Method
C5H5-diphenylphosphinoethane iron (II) derivatives from (n-C5H5)Fe(CO)2I.Synthesis and Mössbauer spectra
Cis-trans isomeric influence on the reactivity of BrMn(CO)2dppmP(OPh)3 towards dialkylthioethers
Cis-Trans Isomerism in the complex BrMn(CO)2dppm P(OPh)3. An Electronic spectroscopy study
Comparison of the oxidation of dinuclear cyclopentadienyl iron diphosphine complexes with the bridging ligands-CN and-C=C (CH2)2CN
Coordination of (N,-N'-Dibenzyl)-benzene sulfenamide, via sulfur atom. Crystal and Molecular Structure of (C6H5CH2)2NS(C6H5)Cr(CO)5
Coordination properties of some solvents in Cr(CO)5L complexes
Crystal structure of Methylsulfenamide Pentacarbonyl Chromium (0). A complex with a short Cr-S Bond
Dioxybiphenyl and chiral dioxybinaphthyl Polyphosphazene random copolymers carrying carboxylic acids and their reactions with ε- caprolactam to form nylon-6-branched phosphazene materials
Donor-acceptor molecular complexes of the thiobisphaltalimide with diphenylamine and potassium thiocyanate
Electrochemical oxidation of monosubstituted chromium carbonyl complexes. Ligand and solvent effect
ESCA studies of N,N'-thiobisamines and of their chromium, carbonyl complexes
Espectros Infrarrojos de la N,N'-tiobisdimetilamina y sus derivados
Generation of thionitroso compounds from N,N'-thiodiamines. A molecular orbital study
Identification of lowest excited state in the complex Cr(CO)5PBu3
Identification of Lowest excited States in the Organometallic iron-Nitrile Complexes”.
Infrared and Raman study of thiobisamines
Interation of thiourea with sulfur divalent compounds: Desulfurization of thiourea by N,N'-Thiobismorpholine
Ionization of the Fe-X bond in polar solvents: a spectroscopic study of CpFe(dppe)X complexes
IR and 'H-NMR characterization of Sulfenamides
Iron (II) and manganese (I) complexes containing diphosphine ligands. An infrared study of BrMn(CO)2 (dpmm)P(OPh)3 and CpFe(dppe)R(R=I, CN)
Iron and Ruthenium Derivatives of Cyclophosphazenes Coordinated Through Nitrile Spacer Ligands
Luminescent Gold and Silver Complexes with the Monophosphane 1‐(PPh2)‐2-Me‐C2B10H10 and Their Conversion to Gold Micro- and Superstructured Materials. Inorganic Chemistry
N,N-Thiodianilines. Detection of thionitrosobenzene derivatives
New Complexes [CpFe(dppe)thiophenes]PF6
NEW ENTRY TO PIANO - STOOL ELECTRON RICH (PENTAMETHYL CYCLOPENTADIENYL) IRON COMPLEXES
Novel Solid-State Route to nanostructured Tin, Zinc and Cerium Oxides as Potencial Materials for Sensors
Preparation of new cationic complexes [(n5-C5H5)Fe(dppe)L]PF6 with sulphur and other donor ligands
Properties of dioxybiphenyl- and chiral dioxybinaphthyl phosphazene copolymers with propyl-carboxylate-phenoxy units and the randomization of the substitution reactions of poly(dichlorophosphazene)
Reactivity of Sulfur(II) compounds. Chemical properties and frontier molecular orbital analysis
Reaktionen von Diaminosulfanen mit Kupfer (II) - Salzen
Redox and coordinated properties of N,N'-Dithiobisamines: Oxidative Desulphuration by Cu (II) ions and Cr(CO)5 S2(NR2) 2 complexes
Role of the linking of metallic centers to macromolecular and oligomeric systems in the pyrolytic products
Solid State Pathways to Complex Shape Evolution and Tunable Porosity During Metallic Crystal Growth.
Solid state synthesis of micro and nanostructured metal oxides using organometallic-polymers precursors
Solution and surfactant-free growth of supported high index facet SERS active nano particles of rhenium by phase demixing
Solution and surfactant-free growth of supported high index facet SERS actu
Solvent and stabilizer free growth of Ag and Pd nanoparticles using Metallic salts/cyclotriphosphazenes mixtures
Solvent effect on the infrared and 1H-NMR spectra of N,N'- thodianilines
Spectroscopic properties of N,N'-dithiobisamines and their cyclic analogues N,N'- dialkylcyclotetrasulfur-1,4-diimides
Structure of (N,N'-dicyclohexyl) benzenesulfenamide and its pentacarbonyl chromium (O) complex via sulfur atom
Structure of Pentacarbonyl-(morpholin) Chromium (O)
Sulfenamides as ligands in transition metal chemistry. Pentacarbonyl (Sulfenamide) Chromium (0) complexes
Sulphur (II) - metal coordination compounds. Group VI metal carbonyl complexes with N,N' - thiobisamine ligands
Sulphur(II) compounds as ligands. Chromium pentacarbonyl complexes with alkoxythioamines as ligands
Sulphurating and coordinating properties of N,N'-Thiobismorpholine towards iron Carbonyls
Synthesis and oxidation of cationic heterobinuclear Cyanide-Bridged Complexes of Manganese and iron
Synthesis and Pyrolysis of Silicon and Tin containing Poly-2,2’-dioxy-1,1’ biphenoxyphosphazene
Synthesis and thermal decarbonylation of W(CO)5 complexes supported by nitrile, pyridine and phosphine ligands to polyspirophosphazene random copolymers carryng OC6H4CO2Pr group
Synthesis of disubstituted ammonium trichlorodicuprate (I) from the reaction of CuCl2.2H2O with N,N'thiobisamines
Synthesis of new carbonyl complexes of manganese (I) containing monodentate Ph2PCH2PPh2(dppm)
The 1A1 → 1E transition as a measure of the π-acceptor ability in M(CO)5L complexes"
The crystal structure of the Hydrogen Bonded Molecular adduct Thiobisphtalimide. Diphenylamine
the first spectroscopic evidence for the existence of substituted thionitrosobenzene, X-C6H4N=S, as an intermediate in the thermal decomposition of N,N-thiodianilines
The mass spectral fragmentation of N,N'-Dithiobisamines and their Cyclic Analogues 3,6-Dialkyl-1,2,4,5,3,6-Tetrathiadiazines
The S-S Bond in N,N'-Dithiobisamines. A Raman study
Unexpected reaction of sulphur dichloride with Cr(CO)5THF: A Cr(III)product without carbon monoxide as ligand

BookSection (7)

A General Solid-State approach to metallic, metal oxides and Phosphates Nanoparticles
Coordination of Organometallic Fragments to Polyphospahzenes Containing Side Groups with Donor Atoms
Metallic Nanostructures using Oligo and Polyphosphazenes as Template /stabilizer in solid state
Nanostructured Materials from Solid-State Pyrolysis of Organometallic Derivatives of Phospahzenes
Organometallic-Metallic-Cyclotriphosphazene Mixtures : Solid-State Method for Metallic Nanoparticle Growth
Solution and Solid State Methods to prepare Au Nanoparticles : A comparison
Synthesis and Characterization of Organometallic Polyphospazenes and their Applications in Nanoscience

Proyecto (5)

Chemical Study of Metal Nanodecoration onto Select Guests partially Included in Cyclodextrins
Metal and metal oxides nanostructured materials inside solid matrix by a new method=> Matrix effect on nanostructured metal and metal oxides
NEW MATERIALS BASED IN POLYSPIROPHOSPHAZENE FUNCTIONALIZED
FABRICATION OF METALLIC AND METAL OXIDES NANOPARTICLES BY A NEW SOLID-STATE METHOD USING MACROMOLECULAR METAL COMPLEXES
“Preparation of metallic nanostructured materials from organometallic derivatives of cyclotriphosphazenes and its inclusion inside solid matrix”
182
Carlos Diaz

Profesor Titular

Quimica

Universidad de Chile

Santiago, Chile

31
Maria Valenzuela

Director and Researcher

Institute of Applied Sciences

Universidad Autonoma de Chile

Temuco, Chile

7
Evgenia Spodine

Full Professor

Química Inorgánica y Analítica

UNIVERSIDAD DE CHILE

Santiago, Chile

5
Fernando Mendizabal

Full Professor

Chemistry

UNIVERSIDAD DE CHILE - FACULTAD DE CIENCIAS

Santiago, Chile

3
Patricio Allende

docente

Química

Universidad Católica del Norte

antofagasta, Chile

2
Daniel Carrillo

Servicios Profesionales

Particular

Santiago, Chile

2
Svetlana Ushak

academico

Dpto de Ingeniería Química y Procesos de Minerales

UNIVERSIDAD DE ANTOFAGASTA

Antofagasta, Chile

1
Pedro Aguirre

Profesor asociado

Inorgánica y Analítica

Universidad de Chile, Facultad de Ciencias Químicas y Farmacéuticas

Santiago, Chile

1
Guillermo González

FACULTAD DE CIENCIAS UIVERSIDAD DE CHILE

Santiago, Chile

1
Ivan Brito

Full Professor

Chemsitry

UNIVERSIDAD DE ANTOFAGASTA

Antofagasta, Chile

1
Maria Toral

Profesor Titular

UNIVERSIDD DE CHILE, FACULTAD DE CIENCIAS, DEPARTAMENTO DE QUÍMICA

Santiago, Chile

1
Andres Vega

Director

Departamento de Química

UNIVERSIDAD ANDRES BELLO

Santiago, Chile

1
Ivan Brito

Profesor Titular

Quimica

Universidad de Antofagasta

Antofagasta, Chile

1
Valeria Villalobos

Profesor asistente

Universidad Autónoma de Chile

Santiago, Chile