Man

Fernando Javier Mendizabal Emaldia

Full Professor

UNIVERSIDAD DE CHILE - FACULTAD DE CIENCIAS

Santiago, Chile

Líneas de Investigación


Relativistic effects in heavy-element chemistry and Metallomacrocycles: Ab initio level the strong closed-shell metal-metal interactions in inorganic chemistry with quasi-relativistic effects. Supramolecular chemistry and molecular elestronics.

Educación

  •  Chemistry, UNIVERSIDAD DE CHILE. Chile, 1996

Experiencia Académica

  •   Full Profesor (Titular) Full Time

    UNIVERSIDAD DE CHILE

    Science

    Santiago, Chile

    1996 - A la fecha

Formación de Capital Humano


Dirección de las tesis de pre- y postgrado:

i) Unidades de investigación a nivel de la Licenciatura en Química y Química Ambiental.

Federico Eisner. “Estudio Teórico en Polímeros Inorgánicos Semiconductores del Tipo [MacM(L) ]n”. Unidad de Investigación carrera de Química (2000).

María Luisa Cerón. “Estudio Teórico en Interacciones de van der Waals M-CO en Complejos Carbonilicos M(CO)n (M = Cu, Ag, Th, U; n = 1,2)”. Unidad de Investigación carrera de Licenciatura C/M Química (2002).

Antonio Reyes L. “Estudio Teórico en Interacción de van der Waals Sobre Complejos M(C2H2)n (M = Au, Cu, Ag; n =1,2)”. Unidad de Investigación carrera de Química Ambiental (2003).

Dana Reyes M. “Estudio de Interacciones Débiles: Combinación entre Atracción Aurofílica y Puente de Hidrógeno”. Unidad de Investigación carrera de Química Ambiental (2003).

Felipe Herrera. “Propiedades Electrónicas en Polímeros de Oro(I) y Platino(II)“. Unidad de Investigación carrera de Química (2004).

Daniela Donoso. “Estudio Teórico en Complejos Hipotéticos del Tipo [Tl(C2Hn)m]+ (n = 2,4; m = 2-4)“. Unidad de Investigación Programa de Doctorado en Química (2007).

Raúl Mera. “Estudio Teórico en Complejos Hipotéticos del Tipo [AuCl(PH3)2-Tl]+“. Unidad de Investigación Programa de Doctorado en Química (2007).

Darwin Burgos. “Estudio Teórico de la Interacción de [M(PH3)+] Con Sistemas orgánicos ? ”. Unidad de Investigación Programa de Doctorado en Química (2008).

Richard Salazar Molina “Estudio Teórico en Propiedades Electrónicas y Espectro de Absorción en Complejos del tipo [Pt3(u-L)3(X)3]-MPH3+ y [Pt3(u-L)3(X)3]-M” para optar al titulo profesional de Profesor en Química, Universidad Metropolitana de Ciencias de la Educación. Finalizada Enero 2012.

ii) Tesis de Doctorado en Química Dirigidas

Darwin Burgos C. “Estudio Teórico de la Catálisis de Oro en Sustratos con Sistemas Orgánicos ?”. Finalizada en Julio 2014.

Sebastián Miranda “Estudio teórico de la Influencia del Sustrato y Producto de la Glutamato Mutasa en la Ruptura y Formación del Enlace Cobalto-Carbono”. Finalizada en Marzo 2012.

Raúl Mera A. “Estudio Teórico del Sitio de Coordinación de Zinc en Variedades Silvestre y Mutante de la Enzima Superóxido de Cobre y Zinc ”. Finalizada 2011.

Germán Barriga G. “Estudio de Resonancia de Espín Electrónico y Estudio Teórico de Nuevas Nitronas Como Atrapadores de Radicales Libres”. Finalizada 2011.

Jorge Rodriguez B. “Estudio Electroquímico, Espectroscópico y Teórico de una Nueva Familia de 5-nitroindazoles con Potenciales Actividades Biológicas”. Finalizada 2009.

Carolina Jullian M. “Estudio de Resonancia Magnética en Complejos de Inclusión de Ciclodextrinas con Flaconas y Flavonoles”. Finalizada 2007.

Rodolfo Briones J. “Estudio Teórico de Selectividad Aniónica y Mecanismo de Apertura y Cierre (Gating) en Canales de Cloruro de la Familia ClC”. Finalizada 2006.

Carolina Rigor O. “Evaluación experimental y teórica de la reactividad de derivados de N-óxidos y Nitrofuranos en sus formas neutras y radicalarias como potenciales agentes farmacológicos”. Finalizada 2006.

Tesis en Etapa de Desarrollo Bajo mi Dirección:

Daniela Donoso “Estudio Teórico de la Interacción entre Pt(0) y L en complejos del tipo Pt3L y Pt3L2 (L=MPH3+ (M = Cu, Au, Ag), Hg, Tl(+); CO, SO2, SNC, PH3)”. Finalizara segundo semestre del 2014.

Recurso Humano a Nivel Post-doctorado Bajo mi Dirección:

Dr. Cristián Linares. He works in theoretical model of TiO2 solar cells with MPc-CO2H (M= Fe, Co y Zn) dyes (2013-1015). Proyecto INTERNATIONAL COOPERATION PROGRAM FOR JOINT RESEARCH IN NON CONVENTIONAL RENEWABLE ENERGY AKA-FINLAND-CONICYT-CHILE 2012 (2013-2015): “Computational Studies of Light-Absorption Processes in Dye-Sensitized Solar Cells”.

Dra. Natalia Inostroza. She works in theoretical model organic dye-sensitized solar cells (2014-2015). Proyecto INTERNATIONAL COOPERATION PROGRAM FOR JOINT RESEARCH IN NON CONVENTIONAL RENEWABLE ENERGY AKA-FINLAND-CONICYT-CHILE 2012 (2013-2015): “Computational Studies of Light-Absorption Processes in Dye-Sensitized Solar Cells”.


Premios y Distinciones

  •   Concurso Beca Doctorado

    FUNDACION ANDES

    Chile, 1991

    Obtención de la beca para realizar estudios de Doctorado en Química otorgada por Fundación Andes (1991- 1994).


 

Article (85)

Theoretical insights into the adsorption of neutral, radical and anionic thiophenols on gold(111)
THEORETICAL STUDY OF COMPLEXES OF THE TYPE [Pt3(M-L)3(L')3J-X (L=CO,SO2,CNH; L'=PH3,CNH; X=Tl+, Hg0, MPH3+ (M = Cu, Au, Ag))
Theoretical study on electronic spectra and interaction in [Au-3]-L-[Au-3] (L = C6F6,Ag+) complexes
Computational Studies of the Metal-Binding Site of the Wild-Type and the H46R Mutant of the Copper, Zinc Superoxide Dismutase
Electrochemical, ESR and Theoretical Insights into the Free Radical Generation by 1,1 '-Hydrocarbylenebisindazoles and Its Evaluation as Potential Bio-Active Compounds
Enhancement of the Catalytic Activity of Fe Phthalocyanine for the Reduction of O-2 Anchored to Au(111) via Conjugated Self-Assembled Mono layers of Aromatic Thiols As Compared to Cu Phthalocyanine
Theoretical study of the local reactivity of electrophiles of the type MPR (3) (+) (M = Cu, Ag, Au ;R = -H, -Me, -Ph)
A Computationally Efficient and Reliable Bond Order Measure
Basicity of bisperhalophenyl aurates toward closed-shell metal ions: metallophilicity and additional interactions
ESR, electrochemical, molecular modeling and biological evaluation of 4-substituted and 1,4-disubstituted 7-nitroquinoxalin-2-ones as potential anti-Trypanosoma cruzi agents
Theoretical and Experimental Study of Bonding and Optical Properties of Self-Assembly Metallophthalocyanines Complexes on a Gold Surface. A Survey of the Substrate-Surface Interaction
Theoretical study of the closed-shell d(10)-d(10) Au(I)-Cu(I) attraction in complexes in extended unsupported chains
Theoretical study of the closed-shell d10-d10 Au(I)-Cu(I) attraction in complexes in extended unsupported chains
Theoretical study of the interaction between Pt(0) and MPH3 (+) fragments in complexes of the [Pt-3 (mu-CO)(3)(PH3)(3)]-MPH3 (+) (M = Cu+, Au+, Ag+) type
Theoretical study of the protonation of [Pt-3(mu-L)(3)(L ')(3)] (L = CO, SO2, CNH; L ' = PH3, CNH)
Theoretical study of the protonation of [Pt3(?-L) 3(L?)3] (L = CO, SO2, CNH; L? = PH3, CNH)
Theoretical EPR study of Nitroindazoles: 3-Alkoxy, 3-Hydroxy and 3-Oxo Derivatives
Theoretical study of the interaction between Au(I) and I on the [AuI2](-)-I-2 complexes
Theoretical study of the interaction between Au(I) and I on the [AuI2]--I2 complexes
THEORETICAL STUDY OF THE S-2-P INTERACTION BETWEEN TL(I) AND OLEFINIC SYSTEMS ON HYPOTHETICAL [TL(C2H4)(2)](+) AND [TL(C2H2)(N)](+) (N=2,3) COMPLEXES
Theoretical study of the s2-p interaction between tl(i) and olefinic systems on hypothetical [tl(c2h4) 2]+ and [tl(c2h2)n] + (n= 2,3) complexes
THEORETICAL STUDY OF THE S²-P INTERACTION BETWEEN TL(I) AND OLEFINIC SYSTEMS ON HYPOTHETICAL [TL(c2H4)2]+ And [TL(c2H2)n]+ (N = 2,3) COMPLEXES
Theoretical Study of {Au-3(CH3N=COCH3)(3)}(n)center dot{2,4,7-Trinitro-9-fluorenone} (n=1,2) Complexes
Theoretical study of {au3(ch3nacoch3) 3}n.{2,4,7-trinitro-9-?uorenone} (n = 1,2) complexes
Theoretical study of electronic spectra of [Pt 3(?-CO) 3(CO) 3] n -2 (n = 3-5) complexes
Theoretical Study of Electronic Spectra of [Pt-3(mu-CO)(3)(CO)(3)](n)(-2) (n=3-5) Complexes
Theoretical study of the d(10)-s(2) interaction between Au(I) and Tl(I) in the [AuCl(PH3)(2)]Tl+ hypothetical complex
Complexation of morin with three kinds of cyclodextrin - A thermodynamic and reactivity study
Theoretical study of [Hg 3(o-C 6F 4) 3] n · {benzene} (n = 1, 2) complexes
Theoretical study of [Hg(3)(o-C(6)F(4))(3)](n) center dot {benzene} (n=1, 2) complexes
Theoretical study of the aggregation of d(10)-s(2) Au(I)-Tl(I) complexes in extended unsupported chains
Theoretical study of the electronic spectra of bi- and tri-heteronuclear platinum complexes
Studies of inclusion complexes of natural and modified cyclodextrin with (+)catechin by NMR and molecular modeling
Theoretical study in [C 2H 4-Tl] + and [C 2H 2-Tl] + complexes
Theoretical study in [C2H4-Tl](+) and [C2H2-Tl](+) complexes
Theoretical study of the interaction d 10-d 8 between Pt(0) and M(I) on the [Pt(PH 3) 3-MPH 3] + complexes (M = Cu, Ag, Au)
Theoretical study of the interaction d 10-s 2 between Pt(0) and metals on the [Pt(PH 3) 3M] complexes (M = Hg(0), Au(-I))
Theoretical study of the interaction d(10)-d(8) between Pt(0) and M(I) on the [Pt(PH3)-MPH3](+) complexes (M = Cu, Ag, Au)
Theoretical study of the interaction d(10)-s(2) between Pt(0) and metals on the [Pt(PH3)(3)M] complexes (M = Hg(0), Au(-I))
Theoretical study on electronic spectra and aurophilic attraction in [Au 3 (MeN {double bond, long} COMe) 3] n (n = 1 s(-) 4) complexes
Theoretical study on electronic spectra and aurophilic attraction in [Au-3(MeN=COMe)(3)](n) (n-1-4) complexes
Complexes self-associate by hydrogen bonding and metallophilic attraction: Theoretical study
Electronic structure and molecular properties of the heptacyanorhenate [Re(CN)(7)](3-) and [Re(CN)(7)](4-) complexes
Electronic structure and molecular properties of the octacyanorhenate [Re(CN)(8)](3-) and [Re(CN)(8)](2-) complexes
Theoretical study on 5-nitrofuryl thiosemicarbazone radicals electronic properties
Theoretical study on the electronic spectrum of [M(CN)(2)](n)(-n) (M = Au(I), Ag(I); n=1-3) complexes
Electrochemical and ESR study of 5-nitrofuryl-containing thiosemicarbazones antiprotozoal drugs
Novel benzo[1,2-c]1,2,5-oxadiazole N-oxide derivatives as antichagasic agents: Chemical and biological studies
Theoretical study of the electronic spectrum of binuclear gold(I) complexes
Theoretical study of the interaction d(10)-s(2) between Pt(0) and Tl(I) on the [Pt(PH3)(3)Tl](+) complex
Theoretical study of the interaction d10-s2 between Pt(0) and Tl(I) on the [Pt(PH3)3Tl]+ complex
A detailed study of the vapochromic behavior of {TI[Au(C 6Cl 5) 2]} n
A detailed study of the vapochromic behavior of {Tl[Au(C6Cl5)(2)]}n
Aurophilic attraction in binuclear complexes with Au(I) and Au(III). A theoretical study
Aurophilic attraction: the additivity and the combination with hydrogen bonds
Electrochemical and microsomal production of free radicals from 1,2,5-oxadiazole N-oxide as potential antiprotozoal drugs
ESR spin trapping studies of free radicals generated from nitrofuran derivative analogues of nifurtimox by electrochemical and Trypanosoma cruzi reduction
QUANTUM CHEMICAL MODEL FOR LITHIUM ELECTROCHEMICAL INTERCALATION INTO MOLYBDENUM DISULFIDE
Theoretical and photoluminescence studies on the d(10)-s(2) Au-I-Tl-I interaction in extended unsupported chains
THEORETICAL STUDY OF COPPER-CARBONYLS INTERACTION IN CU(CO)N (N=1-2) COMPLEXES
Theoretical study of the d 10-d 8 interaction between Au(I) and Au(III) on the cis/trans-[PH 3Au(I)C(L)=C(L)Au(III)(R) 2PH 3] (R=-H, -CH 3; L=-H, -CH 3) systems
Theoretical study of the d(10)-d(8) interaction between Au(I) and Au(III) on the cis/trans-[PH3Au(I)C(L)=C(L)Au(III)(R)(2)PH3] (R = -H -CH3; L = -H, -CH3) systems
Vibrational study of sub-2,3-boronnaphthalocyanine chlorine adsorbed on metal surfaces
Basis set effects on B3LYP geometries and energies: Case study of interstellar reaction HN=CH 2 + •C?N ? H 2N-C( •)H-C?N
METALLOMACROCYCLE (MacM) COMPLEX WITH CYANIDE AS BRIDGED LIGAND: ELECTRONIC STRUCTURE OF [MacMCN]n
Metallomacrocycle (MacM) complex with cyanide as bridged ligand: Electronic structures of [MacMCN](n)
NEW ENTRY TO PIANO -STOOL ELECTRON RICH (PENTAMETHYL CYCLOPENTADIENYL) IRON COMPLEXES
Phthalocyanoruthenium complexes and polymers with bridged ligands
Electron spin resonance studies and theoretical quantum calculations of free radicals generated from anthracenetrione by electrochemical and microsomal reduction
EXPONENTIAL DECAY OF A CHARGE TRANSFER INDUCED BY COORDINATION IN ORGANOMETALLIC COMPLEXES
EXPONENTIAL DECAY OF A CHARGE TRANSFER INDUCED BY CORRDINATION IN ORGANOMETTALIC COMPLEXES
Metallomacrocycle complex bridged polymers: electronic structures of -[MacM(L)](n)
Mixed gold(I)-gold(III) complexes with bridging selenido ligands. Theoretical studies of the gold(I)-gold(III) interactions
Phthalocyanoiron complex with bridged ligands. Electronic structure of monomers and polymers
Surface-enhanced vibrational study of azabipiridyl and its Co(II), Ni(II) and Cu(II) complexes
Theoretical study of gold-carbonyls interaction in Au(CO)(n) (n=1-3) complexes
Polynuclear gold complexes with bridging selenido ligands. Theoretical studies of gold-gold interactions
Iron and ruthenium organometallic derivatives of spiro-substituted cyclotriphosphazenes bearing nitrile spacer: Synthesis and electronic structure
Theoretical study of the Au-ethylene interaction
Cyclic voltammetry and electron paramagnetic resonance studies of some analogues of nifurtimox
Infrared and theoretical interpretation of the structure of naphthalocyanine and its copper(II) complex deposited onto a smooth copper surface
Theory of d 10 - d 10 Closed-Shell Attraction. III. Rings
Molecular modelling of lithium intercalation in 1T-TiS 2
Vibrational study and semiempirical calculation for the hexaazacyclophane copper(II) complex
Infrared spectrum of the bis-(1,10-phenanthroline) Cu(I) and Cu(II) perchlorate complexes

Abstract (1)

ESR and spin trapping studies of nitrofuran derivatives as potential antitrypanosoma drugs

Review (2)

Applications of electron spin, resonance and spin trapping in tropical parasitic diseases
Intercalation chemistry of molybdenum disulfide
105
Fernando Mendizabal

Full Professor

Chemistry

UNIVERSIDAD DE CHILE - FACULTAD DE CIENCIAS

Santiago, Chile

34
claudio olea

Full Professor

Inorganica y Analitica

UNIVERSIDAD DE CHILE

Santiago, Chile

7
Sebastián Miranda

Profesor Asistente

Departamento de Ciencias Químicas

UNIVERSIDAD NACIONAL ANDRES BELLO

Santiago, Chile

5
Gerald Zapata

DEPARTAMENTO DE QUÍMICA INORGÁNICA Y ANALÍTICA FACULTAD DE CIENCIAS QUÍMICAS Y FARMACÉUTICAS UNIVERSIDAD DE CHILE

Santiago, Chile

5
Ramiro Arratia

DIRECTOR DOCTORADO

CIENCIAS QUIMICAS

UNIVERSIDAD ANDRES BELLO

Santiago, Chile

5
Carlos Diaz

Profesor Titular

Quimica

Universidad de Chile

Santiago, Chile

5
Juan Maya

Full Professor

Biomedical Sciences Institute

UNIVERSIDAD DE CHILE

Santiago, Chile

4
Juan Silva

Academic

Química de los Materiales

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

3
Alvaro Muñoz

UNIVERSIDAD ANDRES BELLO

Santiago, Chile

3
Alvaro Muñoz

Full time professor

Dirección de Investigación y Postgrado

Universidad Autónoma de Chile

Santiago, Chile

2
Ingrid Ponce

Assistant Professor

Departmento Ciencias del Ambiente

Univerisidad de Santiago de Chile

Santiago, Chile

2
EGLANTINA BENAVENTE

ACADEMICO

QUIMICA

UNIVERSIDAD TECNOLOGICA METROPOLITANA

SANTIAGO, Chile

2
Ulrike Kemmerling

Full Professor

ICBM

Facultad de Medicina, Universidad de Chile

Santiago, Chile

2
Guillermo González

FACULTAD DE CIENCIAS UIVERSIDAD DE CHILE

Santiago, Chile

2
MARITZA PAEZ

Full professor

Química de los Materiales

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

2
CAROLINA JULLIAN

Profesor Asociado

Quimica Organica y Fisicoquimica

UNIVERSIDAD DE CHILE

SANTIAGO, Chile

2
José Zagal

Distinguished Professor

Chemistry of Materials

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

1
Renato Contreras

professor

Quimica

Universidad de Chile

Santiago, Chile

1
Rodrigo Lopez

Profesor Asociado

Facultad de Ciencias Veterinarias

UNIVERSIDAD AUSTRAL DE CHILE

Valdivia, Chile

1
patricio fuentealba

Profesor Titular

Física

U. DE CHILE, FAC. CIENCIAS, DPTO. FISICA

Santiago, Chile

1
Hernan Speisky

PROFESOR TITULAR

UNIVERSITY OF CHILE

SANTIAGO, Chile

1
Michel Lapier

Investigador Postdoctoral

ICBM

Universidad de Chile

Santiago, Chile

1
Mauricio Gonzalez

Profesor Titular

INTA

UNIVERSIDAD DE CHILE - INSTITUTO DE NUTRICION Y TECNOLOGIA DE ALIMENTOS

Santiago, Chile

1
Ramiro Araya

UNIVERSIDAD DE CHILE, FAC. CIENCIAS QUÍMICAS Y FARMACÉUTICAS, DPTO. QUÍMICA ORGÁNICA Y FISICOQUÍMICA

Santiago, Chile

1
JORGE PAVEZ

Professor

Materials Chemistry

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

1
Fernanda Perez

Investigadora senior principal

Síntesis orgánica

Ientropia SPA

Santiago, Chile