Man

José Heráclito Zagal Moya

Distinguished Professor

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

Líneas de Investigación


Physical-Chemistry of Interfaces; Electrochemistry; Electrocatalysis, Nanostructures; Electrode Kinetics;Molecular Electrochemistry; Electrochemical Energy Conversion;

Educación

  •  Chemistry, CASE WESTERN RESERVE UNIVERSITY. Estados Unidos, 1978

Experiencia Académica

  •   Ayudante Part Time

    UNIVERSIDAD DE CHILE

    Ciencias Físicas y Matematicas

    Santiago, Chile

    1971 - 1973

  •   Full Professor Full Time

    UNIVERSIDAD DE SANTIAGO DE CHILE

    Química y Biologia

    Santiago, Chile

    1973 - A la fecha

  •   Posdoctoral Fellow Full Time

    Brookhaven National Laboratory

    Upton, New York, Estados Unidos

    1982 - Sin Información

Experiencia Profesional

  •   Lecturer Full Time

    State Technical University

    Santiago, Chile

    1973 - 1975

  •   Associate Professor Full Time

    University of Santiago de Chile

    Santiago, Chile

    1978 - 1982

  •   Vice-chairman of Research Full Time

    University of Santiago de Chile

    Santiago, Chile

    1980 - 1982

  •   Chairman Department of Chemistry Full Time

    University of Santiago de Chile

    Santiago, Chile

    1982 - 1985

  •   Director, Graduate Program in Chemistry Full Time

    University of Santiago de Chile

    Santiago, Chile

    1999 - 2004

  •   Full Professor Full Time

    University of Santiago de Chile

    Santiago, Chile

    1989 - A la fecha

  •   Member of the Superior Council of Research Part Time

    Conicyt

    Santiago, Chile

    2011 - 2013

Formación de Capital Humano


Ph.D. (TUTOR) (LAST 5 YEARS)

1. Rodrigo del Río Quero. “Electrocompositos de Polianilina y Negro de Carbón, Síntesis, Caracterización y Propiedades” (1999) (Doctorado en Química).

2. Jorge Pavez Irrazabal. “Estudio de la electropolimerización y propiedades electrocatalíticas de tetraaminoftalocianinas de metales de transición” (2000) (Doctorado en Química).

3. Claudia Andrea Caro Diaz. “Modelo Cinético-Cuántico de Transferencia de carga para ftalocianinas de metales de Transisión” (2003) (Doctorado en Química).

4. Miguel Gulppi Cabra. “Estudio del carácter predictivo de los potenciales redox de ftalocianinas de cobalto adsorbidos sobre grafito para la oxidación de tioles y reducción de disulfuros” (2003)

5. Danica Mimica Viladrich. “Electrodos Modificados como sensores en Sustancias de interés Biológico” (2005) (Doctorado en Ingeniería y Ciencias de los Materiales)

6. Mamie Sancy Velásquez. “Complejos Macrocíclicos como inhibidores de la corrosión de cobre” (2005) (Doctorado en Ingeniería y Ciencias de los Materiales) en co-tutela con la Université Pierre et Marie Curie, Paris, Francia.

7. Daniela Andrea Geraldo Durán. “Correlaciones de Tipo Volcán entre la reactividad de una familia de ftalocianianas de cobalto y el potencial redox Co(II)/(I) del complejo para la oxidación de hidracina”. (2006) (Doctorado en Química).

8. Juan Francisco Silva Rojas. “Propiedades Estructurales y Electrocatalíticas de Monocapas Autoensambladas Funcionalizadas con Ftalocianinas de Hierro” (2008) (Doctorado en Química).

9. Carlos Silva “Preparación de Materiales de Electrodos Hibridos que Conteniendo Polímeros altamente ordenados” Universidad de Santiago de Chile (2014) (Doctorado en Química).

10. Ingrid Ponce “Estudio Electrocatalíticos de Electrodos conteniendo películas autoensambaladas de tioles y Ftalocianinas (2013) Universidad de Santiago de Chile (Doctorado en Química).

11. Alejandra Aurora gomez San Martín “Complejos Organometálicos de Renio Sustituidos con Éteres Corona y Azamacrociclos: Síntesis, caracterización, estudios 1H-RMN y Electroquímicos (2013). Universidad de Santiago de Chile (Doctorado en Química).

12. Cristian Gutierrez “Diseño de electrodos molecularmente ensamblados para sensores de tioles” (2014) Universidad de Santiago de Chile (Doctorado en Química).

13. Ruben Oñate “Síntesis y Caracterización de Tioles Orgánicos y su autoensamble en electrodos de oro” (2014) (Doctorado en Química).

14. Andrea Carolina Ramos Hernández. “Efecto de la Unidad de partida y de las condiciones de electro-polimerización sobre las propiedades de nano-depósitos obtenidos desde tiofenos” (2014) (Doctorado en Química)

15. Ricardo Venegas “Electrocatalisis de la reduccion de O2 mediada por complejos de Cu(I)” (en desarrollo) (Doctorado en Química).

16. Mireya Santander-Nelly “Estudios teórico y Experimental de Electrodos modificados con nanotubos de carbono para la reduccion de O2” (en desarrollo) (Doctorado en Química).

17. Javier Espinoza Vergara “Electrocatálisis de la reducción de O2 en electrodos híbridos conteniendo nanotubos de carbono y grafeno. (en desarrollo) (Doctorado en Química).

18. María Paz Oyarzun Medina “Funcionalizaciòn de nanoestructuras para la detecciòn de neurotransmisores y reducciòn de oxìgeno molecular” (Doctorado en Química) (Doctorado en Química) (2017)

Undergraduate.

1. Ingrid Ponce Hormazabal, “Estudio comparativo de la reducción de oxigeno molecular catalizada por complejos macrocíclicos de Co y de Fe confinados sobre superficies de oro modificados con monocapas autoensambladas de tioles” Licenciatura en Química, Universidad de Santiago de Chile, 2009.

2. Cristian Gutierrez Cerón,“Oxidación de l-cisteina sobre electrodos de carbon vitreo modificados con ftalocianians de hierro” Licenciatura en Química, Universidad de Santiago de Chile, 2009.

3. Dafne Pino Riffo “Desarrollo de un Sensor Electroquímico para la detección amperométrica de tiocinato”.Ingenieria de Ejecución en Química Universidad de Santiago de Chile (2011)

4. Giselle Francis Adam Pino “Nanotubos de Carbono Modificados con Ftalocianinas de Cobalto, estabilidad y detección frente a sulfito y glutatión” Ingeniero Quimico y Licenciado en Ciencias de la Ingenieria, Universidad Tecnológica Metropolitana (2012)

5. Alexander José Sandoval Gerardino. “Respuesta electroquímica de electrodos modificados con FePc, Frente a la reducción del oxígeno molecular” Ingenieía en Química y al grado de Licenciado en Ciencias de la Ingeniería, Universidad Tecnológica Metropolitana (2013).

6. Manuel Felipe Becerra Cofré. “Caracterización y estudio de la durablidad de Ftlocianina de Hierro (FePc) para la reducción de Oxígeno a pH 13 y 7. Ingeniería en Química y al grado de Licenciado en Ciencias de la Ingeniería, Universidad Tecnológica Metropolitana (2014)

Postdocs (and country of origin and present position)

1. Luis Basaez (Chile), 1998. Profesor Asociado, Universidad de Concepción.
2. Maria Jesus Aguirre, 1997-1998, Profesor Titular, Universidad de Santiago de Chile
3. Gloria Cárdenas-Jirón, 1998 , Profesor Titular, Universidad de Santiago de Chile
4. Igor Zhukov (Federación Rusa), 2006.
5. Jan Clau?en (Alemania) 2005. Investigador, Procter & Gamble
6. Francisco Silva (Chile), 2009. Profesor Asistente, USACH:
7. Sophie Griveau (Francia).Profesor Asociado, Ecole National Superieure de Chimie
8. Mamie Sancy (Chile), 2009. Profesor Adjunto, Pontificia Universidad Católica de Chile.
9. Luis Lemus (Chile) 2010-2012) Profesor Adjunto, Universidad de Santiago de Chile
10. Nazareth Pereira Rodrigues (France) Scientist, Synchrotron SOLEIL
11. Hanna Ayoub (Francia 2010). Scientist , Impeto Biomedicals, France
12. Javier Recio (España, 2012-2015) Profesor Adjunto, Pontificia Universidad Católica de Chile.
13. Federico Tasca (Italia, 2012) Profesor Adjunto, Universidad de Santiago de Chile
14. Evelyn Gonzalez (Chile 2012-2015) Investigador Asociado, Universidad de Santiago de Chile
15. Paulina Cañete (Chile 2012) Investigador Asociado, Universidad de Chile
16. Amandine Calmet (Francia 2016)
17. Nataly Silva (Chile 2014-2017) Posdoctorando, Universidad de Santiago de Chile
18. Ricardo Matute (2017. Profesor Asociado, U. Bernardo OHiggins


Premios y Distinciones

  •   Cátedra Presidencial en Ciencias

    MINISTERIO DE EDUCACION

    Chile, 1996

    This award was given only during the Presidencial period of Eduardo Frei Ruiz-Tagle adn given by a International Commitee

  •   Fellow

    International Society of Electrochemistry

    Suiza, 2014

    "ISE Fellow'" is a category of membership conferred upon an individual in recognition of her/his continuing outstanding scientific and/or technical achievement within the field of electrochemistry. ISE Fellow candidates must be fully active in research and must have made significant contributions to electrochemistry in the last few years. This recognition should be limited to a small fraction of the active membership (approx. 5%). Fellowship should not be granted for political or administrative service; Honorary Membership provides the means of recognizing such contributions to the Society.

  •   "Dr Alberto Zanlungo"

    UNIVERSIDAD DE SANTIAGO DE CHILE

    Chile, 2014

    La Fundación Dr. Alberto Zanlungo C. llama a concurso a los estudiantes de las carreras de Licenciatura en Bioquímica, Licenciatura en Educación en Química y Biología, Licenciatura en Química y Química y Farmacia de la Facultad de Química y Biología de la Universidad de Santiago de Chile para la postulación a la beca de ayuda económica para el año 2014. La beca se otorgará en base a antecedentes académicos. Sin embargo, se hace un llamado a los estudiantes para que postulen aquellos que tengan reales necesidades económicas.

  •   Fellow, Electrochemical Society

    The Electrochemical Society, USA

    Chile, 2014

    The Fellow of The Electrochemical Society was established in 1989 for advanced individual technological contributions in the field of electrochemical and solid state science and technology; and active membership and involvement in the affairs of The Electrochemical Society. Recipient qualifications The fellow selection will be made both on the basis of technical contributions and involvement in the activities of the Society. Technical contributions will be emphasized. It is understood that an individual may be selected as a fellow only on the basis of technical contributions, but may not be selected only on the basis of contributions to Society activities. The applicant MUST be a member of The Electrochemical Society. Nominations, once made, are considered in effect for two award cycles and no candidate may be considered for more than two successive years. Award The award consists of an appropriately worded scroll and lapel pin.

  •   Fellow of The Royal Society of Chemistry

    Royal Society of Chemistry

    Reino Unido, 2018

    You are eligible to become a Fellow of the Royal Society of Chemistry if you’ve been more than five years in a senior position, and your efforts have made an impact in any field of the chemical sciences. As a Fellow, yours is a position of influence in this community. Your experience, expertise and commitment to promoting the value of chemistry are assets that we are here to help you showcase and develop, with a wide range of support tailored to your goals.

  •   Emeritus Member, The Electrochemical Society

    The Electrochemical Society, USA

    Estados Unidos, 2018

    Category after 40 years of Full Membership

  •   Diploma Fondecyt 30 años

    Conicyt

    Chile, 2012

    El año 2012 se distinguió a 27 investigadores de Chile por la adjudicación de 10 Proyectos de Fondecyt Regular sin rechazos.


 

Article (143)

Mapping Transition Metal-MN4 Macrocyclic Complex Catalysts Performance for the Critical Reactivity Descriptors
Mapping Transition Metal-Nitrogen-Carbon Catalysts Performance on the Critical Descriptors Diagram
Transition metal phthalocyanine-modified shungite-based cathode catalysts for alkaline membrane fuel cell
Experimental reactivity descriptors of M-N-C catalysts for the oxygen reduction reaction
Oxygen Reduction Reaction at Penta Coordinated Co Phthalocyanines
Reactivity descriptors for Cu bis-phenanthroline catalysts for the hydrogen peroxide reduction reaction
“Penta-coordinated transition metal macrocycles as electrocatalysts for the oxygen reduction reaction”
Electrochemical dynamic sensing of hydrogen peroxide in the presence of microorganisms
Electroreduction of oxygen in alkaline solution on iron phthalocyanine modified carbide-derived carbons
Elucidating the mechanism of the oxygen reduction reaction for pyrolyzed Fe-N-C catalysts in basic media
Modulation of the electrocatalytic activity of Fe phthalocyanine to carbon nanotubes: Electrochemistry of L-cysteine and L-cystine
Biomimicking vitamin B12. A Co phthalocyanine pyridine axial ligand coordinated catalyst for the oxygen reduction reaction
Building Pyridinium Molecular Wires as Axial Ligands for Tuning the Electrocatalytic Activity of Iron Phthalocyanines for the Oxygen Reduction Reaction
Climbing over the activity volcano correlation by biomimicking Vitamin B12: A co phthalocyanine pyridine axial ligand coordinated catalyst for the reduction of molecular oxygen
Electrocatalytic Activity of Nanohybrids Based on Carbon Nanomaterials and MFe2O4 (M=Co, Mn) towards the Reduction of Hydrogen Peroxide
Electrochemical Behavior of Stainless Steels for Sudomotor Dysfunction Applications
Probing the Fen +/Fe(n-1)+ redox potential of Fe phthalocyanines and Fe porphyrins as a reactivity descriptor in the electrochemical oxidation of cysteamine
Surface Functionalization of an Aluminum Alloy to Generate an Antibiofilm Coating Based on Poly(Methyl Methacrylate) and Silver Nanoparticles
Biomimetic reduction of O-2 in an acid medium on iron phthalocyanines axially coordinated to pyridine anchored on carbon nanotubes
Comparison of the catalytic activity for O-2 reduction of Fe and Co MN4 adsorbed on graphite electrodes and on carbon nanotubes
Oxygen Electroreduction on Zinc and Dilithium Phthalocyanine Modified Multiwalled Carbon Nanotubes in Alkaline Media
Tailoring electroactive surfaces by non-template molecular assembly. Towards electrooxidation of L-cysteine
Catalytic aspects of metallophthalocyanines adsorbed on gold-electrode. Theoretical exploration of the binding nature role
Multiscale approach to the study of the electronic properties of two thiophene curcuminoid molecules
O-2 reduction on electrodes modified with nitrogen doped carbon nanotubes synthesized with different metal catalysts
Polyaniline nanostructure electrode: morphological control by a hybrid template
Reactivity descriptors for iron porphyrins and iron phthalocyanines as catalysts for the electrooxidation of reduced glutathione
Reactivity descriptors for the activity of MN4 molecular catalysts for the oxygen reduction reaction
Reactivity indexes for the electrocatalytic oxidation of hydrogen peroxide promoted by several ligand-substituted and unsubstituted Co phthalocyanines adsorbed on graphite
Surface on Surface. Survey of the Monolayer Gold-Graphene Interaction from Au-12 and PAH via Relativistic DFT Calculations
Building Nanoscale Molecular Wires Exploiting Electrocatalytic Interactions
Stripping voltammetry microprobe (SPV)=> substantial improvements of the protocol
Synthesis, reactivity, electrochemical behaviour, and molecular structure of crown ether cyrhetrene complexes
Linear versus volcano correlations for the electrocatalytic oxidation of hydrazine on graphite electrodes modified with MN4 macrocyclic complexes
Optimizing the reactivity of surface confined cobalt N-4-macrocyclics for the electrocatalytic oxidation of L-cysteine by tuning the Co(II)/(I) formal potential of the catalyst
Towards a unified way of comparing the electrocatalytic activity MN4 macrocyclic metal catalysts for O-2 reduction on the basis of the reversible potential of the reaction
Antibiofouling Properties of Sol-Gel Type Polymers for Aluminium Alloys: Biocorrosion Protection Against Pseudomonas Aeruginosa.
Electrocatalytic actvity of modified gold electrodes based on self-assembled monolayers of 4-mercaptopyridine and 4-aminothiophenol on Au(111) surfaces chemically functionalized with substituted and unsubstituted iron phthalocyanines
Matching the Catalyst Co (II)/(I) Formal Potential of a Macrocyclic complex to the Reversible Potential of Hydrazine Oxidation for the Highest Activity
New evidence on the role of catalase in Escherichia coli-mediated biocorrosion
SIMULTANEOUS ELECTROCHEMICAL DETECTION OF DOPAMINE, ASCORBIC ACID AND URIC ACID USING COPPER-PHTHALOCYANINE FUNCTIONALIZED MWCNTS
Synthesis and Spectroscopic and Electrochemical Studies of Chitosan Schiff Base Derivatives
Tuning the Fe(II)/(I) formal potential of FeN4 catalysts adsorbed on graphite electrodes to the reversible potential of the reaction for maximum activity: Hydrazine oxidation.
Unusual behaviour of perflurorinated cobalt phthalocyanine compared to unsubstituted cobalt phthalocyanine for the electrocatalytic oxidation of hydrazine. Effect of the surface concentration of the catalyst on the graphite surface.
A Possible Interpretation for the High Catalytic Activity of Heat-Treated Non-Precious Metal Nx/C Catalysts for O-2 Reduction in Terms of Their Formal Potentials
Carbon nanotubes and metalloporphyrins and metallophthalocyanines-based materials for electroanalysis
CATALYTIC ACTIVITY OF ELECTRODE MATERIALS BASED ON POLYPYRROLE, MULTI-WALL CARBON NANOTUBES AND COBALT PHTHALOCYANINE FOR THE ELECTROOXIDATION OF GLUTATHIONE AND L-CYSTEINE
Electrochemical Kinetics of Anodic Ni Dissolution in Aqueous Media as a Function of Chloride Ion Concentration at pH Values Close to Physiological Conditions
Enhancement of the Catalytic Activity of Fe Phthalocyanine for the Reduction of O-2 Anchored to Au(111) via Conjugated Self-Assembled Mono layers of Aromatic Thiols As Compared to Cu Phthalocyanine
Inverted Linear Correlation Between the Catalytic Activity of Iron Phthalocyanines and the Formal Potential of the Catalyst in the Electrooxidation of L-Cysteine
Oxygen reduction reaction using N-4-metallomacrocyclic catalysts: fundamentals on rational catalyst design
Preparation and antibacterial properties of hybrid-zirconia films with silver nanoparticles
Reinterpreting the Role of the Catalyst Formal Potential. The case of Thiocyanate Electrooxidation Catalyzed by CoN4-Macrocyclic Complexes
Structure, electronic, and CV properties of hydroxy-naphthaldehyde Schiff-base copper(II) complexes derived from alkyl amines: X-ray structure of bis(n-i-propyl-3-hydroxy-2-naphthaldiminato)copper(II)
Surface Electrochemistry: Structured Electrode, Synthesis, and Characterization
A silanol-based nanocomposite coating for protection of AA-2024 aluminium alloy
Enhanced catalytic activity of Fe phthalocyanines linked to Au(111) via conjugated self-assembled monolayers of aromatic thiols for O-2 reduction
Optimizing the Electrocatalytic Activity of Surface Confined Co Macrocyclics for the Electrooxidation of Thiocyanate at pH 4
SCREEN-PRINTED ELECTRODE MODIFIED WITH SILVER HEXACY ANOFERRATE-NAFION® FOR ASCORBIC ACID DETERMINATION
Screen-printed electrode modified with silver hexacyanoferrate-Nafion® for ascorbic acid determination
Theoretical and Experimental Study of Bonding and Optical Properties of Self-Assembly Metallophthalocyanines Complexes on a Gold Surface. A Survey of the Substrate-Surface Interaction
Does CO poison Fe-based catalysts for ORR?
Electrochemical Transducer Based on Nanostructured Polyaniline Films Obtained on Functionalized Self Assembled Monolayers of 4-Aminothiophenol
Influence of 8-aminoquinoline on the corrosion behaviour of copper in 0.1 M NaCl
Reactivity trends of surface-confined Co-tetraphenyl porphyrins and vitamin B-12 for the oxidation of 2-aminoethanethiol: Comparison with Co-phthalocyanines and oxidation of other thiols
Substituent Effects on Structural, Electronic, and Redox Properties of Bis(N-alkyl-2-oxy-1-naphthaldiminato)copper(II) Complexes Revisited - Inequivalence in Solid- and Solution-State Structures by Electronic Spectroscopy and X-ray Diffraction Explained by DFT
A zirconia-polyester glycol coating on differently pretreated AISI 316L stainless steel: corrosion behavior in chloride solution
Electrochemical reduction of S(IV) species in aqueous medium by glassy carbon electrodes modified with polymeric copper(II)tetra-aza-annulene complexes
Oligomerization of the Cu(II) and Ni(II) tetraazaannulene complexes: A pulse radiolysis study of the associated reaction mechanism
The (Tetraazaannulene)copper-Catalyzed Reduction of Sulfur(IV) Species. A Pulse-Radiolysis and Theoretical Study of the Associated Reaction Mechanism
TUNING THE FORMAL POTENTIAL OF METALLOMACROCYCLICS FOR MAXIMUM CATALYTIC ACTIVITY FOR THE OXIDATION OF THIOLS AND HYDRAZINE
Electrocatalytic oxidation of hydrazine in alkaline media promoted by iron tetrapyridinoporphyrazine adsorbed on graphite surface
Tuning the redox properties of Co-N4 macrocyclic complexes for the catalytic electrooxidation of glucose
Volcano correlations for the reactivity of surface-confined cobalt N-4-macrocyclics for the electrocatalytic oxidation of 2-mercaptoacetate
Copper modified chitosan for protection of AA-2024
Electrocatalytic activity of cobalt phthalocyanine CoPc adsorbed on a graphite electrode for the oxidation of reduced (L)-glutathione (GSH) and the reduction of its disulfide (GSSG) at physiological pH
Glassy carbon electrodes modified with single walled carbon nanotubes and cobalt phthalocyanine and nickel tetrasulfonated phthalocyanine: Highly stable new hybrids with enhanced electrocatalytic performances
SOL-GEL COATINGS FOR PITTING CORROSION RESISTANCE OF AA 2024-T3 ALUMINIUM ALLOY
Bridging the gap between the topological and orbital description of hydrogen bonding: The case of the formic acid dimer and its sulfur derivatives
Electrocatalysis of oxidation of 2-mercaptoethanol, L-cysteine and reduced glutathione by adsorbed and electrodeposited cobalt tetra phenoxypyrrole and tetra ethoxythiophene substituted phthalocyanines
Electrocatalytic reduction of carbon dioxide induced by bis(N-R-2-hydroxy-1-naphthaldiminato)-copper(II) (R = n-octyl, n-dodecyl): Magnetic and theoretical studies and the X-ray structure of bis(N-n-octyl-2-hydroxy-1-naphthaldiminato)-copper(II)
Influence of 5-chloro and 5-methyl benzotriazole on the corrosion of copper in acid solution: an experimental and a theoretical approach
Influence of surface treatments in the initial stages of anodizing Al-Ag alloys in neutral electrolytes
Nickel(II) complexes with tetraaza macrocycles in the electrocatalytic oxidation of sulfite
The Core-Valence Bifurcation Topological Index for Doubly Hydrogen Bonded Complexes:The Case of Formic Acid Dimer and its Sulphur Derivatives
Theoretical modeling of the oxidation of hydrazine by iron(II) phthalocyanine in the gas phase. Influence of the metal character
Trends in reactivity of unsubstituted and substituted cobalt-phthalocyanines for the electrocatalysis of glucose oxidation
UV-visible and electrochemical monitoring of carbon monoxide release by donor complexes to myoglobin solutions and to electrodes modified with films containing Hemin
Effect of film thickness on the electro-reduction of molecular oxygen on electropolymerized cobalt tetra-aminophthalocyanine films
Electropreparation and characterization of polyNiTSPc films. An EQCM study
Inverted correlations between rate constants and redox potential of the catalyst for the electrooxidation of 2-aminoethanethiol mediated by surface confined substituted cobalt-phthalocyanines
Optical determination of differential coverage-potential relations of redox-active species immobilized on electrode surfaces
Synthetic-Substituted Metal Aza Macrocyclic Complexes. Properties and Applications
The influence of aniline and its derivatives on the corrosion behaviour of copper in acid solution: a theoretical approach
The influence of Aniline and its Derivatives on the Corrosion Behaviour of Copper in Acid Solutions
Through-space and through-bond mixed charge transfer mechanisms on the hydrazine oxidation by cobalt(II) phthalocyanine in the gas phase
Biomimetic electroreduction of O-2 by hemoglobin in a surfactant film: Preliminary electrochemical impedance spectroscopy insight
Effect of ligand substituents on the electrocatalytic activity of metallophthalocyanines for the oxidation of hydrazine
Electrochemical reduction of carbon dioxide in the presence of [Ni II-5,7,12,14-tetramethyldinaphtho [b,i] [1,4,8,11] tetra aza [14]annulene]++ cation
Experimental and theoretical study of the activity of substituted metallophthalocyanines for nitrite electro-oxidation
Reactivity Trends for Surface-confined Metallophthalocyanine and Porphyrin Complexes in Electrocatalysis
Solvent effect on density functional reactivity indexes applied to substituted nickel phthalocyanines
Cobalt phthalocyanine-based molecular materials for the electrocatalysis and electroanalysis of 2-mercaptoethanol, 2-mercaptoethanesulfonic acid, reduced glutathione and L-cysteine
Electrocatalytic activity of substituted metallophthalocyanines adsorbed on vitreous carbon electrode for nitric oxide oxidation
Electrooxidation of 2-chlorophenol on polyNiTSPc-modified glassy carbon electrodes
ELECTROPOLYMERIZED COBALT MACRO COMPLEX-BASED FILMS FOR THIOLS ELECTRO-OXIDATION: EFFECT OF THE FILM FORMATION CONDITIONS AND THE NATURE OF THE MACROCYCLIC LIGAND
Environment effects on the oxidation of thiols: cobalt phthalocyanine as a test case
Non-linear correlations between formal potential and Hammett parameters of substituted iron phthalocyanines and catalytic activity for the electro-oxidation of hydrazine
On understanding the effect of benzotriazole during barrier-film growth on Al-Cu alloys
Theoretical study of the electron transfer reaction of hydrazine with cobalt(II) phthalocyanine and substituted cobalt(II) phthalocyanines
Effect of the substituents on the ligand of iron phthalocyanines adsorbed on graphite electrodes on their activity for the electrooxidation of 2-mercaptoethanol
Electrocatalytic oxidation of nitrite on a vitreous carbon electrode modified with cobalt phthalocyanine
Electroreduction of molecular oxygen on poly-iron-tetraaminophthalocyanine modified electrodes
Reversibility of the L-cysteine/L-cystine redox process at physiological pH on graphite electrodes modified with coenzyme B-12 and vitamin B-12
Theoretical study of the interaction energy profile of cobalt phthalocyanine and 2-mercaptoethanol. Effect of the graphite on the global reactivity
Volcano correlations between formal potential and Hammett parameters of substituted cobalt phthalocyanines and their activity for hydrazine electro-oxidation
Anodizing of AI 2024-T3 in mixtures of sulphuric-boric acids
CHANGES IN THE EQCM RESPONSE OF PLATINUM DEPOSITS IN THE HYDROGEN REGION INDUCED BY REPETITIVE CYCLING OF THE ELECTRODE
Changes in the eqcm response of platinum deposits in the hydrogen region induced by repetitive cycling ofthe electrode
Donor-acceptor intermolecular hardness on charge transfer reactions of substituted cobalt phthalocyanines
ELECTRO-OXIDATION OF 2-MERCAPTOETHANOL ON ADSORBED MONOMERIC AND ELECTROPOLYMERIZED COBALT TETRA-AMINOPHTHALOCYANINE FILMS. EFFECT OF FILM THINCKNESS
Electrocatalysis of 2-mercaptoethanesulfonic acid oxidation on cobalt phthalocyanine modified electrodes. Effect of surface concentration of the catalyst
Electrocatalysis of nitric oxide reduction by hemoglobin entrapped in surfactant films
METHANOL ELECTRO-OXIDATION ON Pt-Rh ALLOYS IN ACID MEDIUM
REACTIVITY OF ELECTRODES MODIFIED WITH SUBSTITUTED METALLOPHTHALOCYANINES. CORRELATIONS WITH REDOX POTENTIALS, HAMMETT PARAMETERS AND DONOR-ACCEPTOR INTERMOLECULAR HARDNES
Silver as a powerful electrocatalyst for organic halide reduction: The critical role of molecular structure
Metal-centered redox chemistry of substituted cobalt phthalocyanines adsorbed on graphite and correlations with MO calculations and Hammett parameters. Electrocatalytic reduction of a disulfide
POTENTIOMETRIC RESPONSE OF A GRAPHITE ELECTRODE MODIFIED WITH COBALT PHTHALOCYANINE FOR THIOLS AND DISULFIDES
Reactivity of immobilized cobalt phthalocyanines for the electroreduction of molecular oxygen in terms of molecular hardness
Electrocatalytic response of poly(2-chloroaniline)/cobalt phthalocyanine modified electrodes
Paradoxical effect of the redox potential of adsorbed metallophthalocyanines on their activity for the oxidation of 2-mercaptoethanol. Inner versus outer sphere electrocatalysis
SYNTHESIS AND CHARACTERIZATION OF A COMPOSITE OF POLYANILINE AND CARBON BLACK
Synthesis and Electrocatalytic Properties of Octaalkoxycobalt Phthalocyanine for the Oxidation of 2-Mercaptoethanol
Catalytic Electrooxidation of 2-Mercaptoethanol on Perchlorinated Iron Phthalocyanine Adsorbed on a Graphite Electrode
Comparative study of the electrocatalytic activity of cobalt phthalocyanine and cobalt naphthalocyanine for the reduction of oxygen and the oxidation of hydrazine
Linear versus volcano correlations between electrocatalytic activity and redox and electronic properties of metallophthalocyanines
Spectroelectrochemical studies of tetrasulfonated metallophthalocyanines adsorbed on the basal plane of graphite in the presence of cysteine
Catalytic electro-oxidation of 2-mercaptoethanol using cobalt phthalocyanine + poly(2-chloroaniline) modified electrodes
Effect of benzotriazole on the efficiency of anodizing of Al-Cu alloys
Electro-oxidation of hydrazine on electrodes modified with vitamin B12
O2 reduction kinetics on a graphite electrode modified with adsorbed vitamin B12
Stability and electrical properties of polyaniline films formed with EDTA and FeEDTA in the electrolyte
Catalytic Electroreduction of Thionyl Chloride on Graphite in the presence of Cobalt Phthalocyanine

BookSection (1)

Fundamental Studies on the Electrocatalytic Properties of metal macrocyclics and other complexes for the electroreduction of O2

BookWhole (3)

Electrochemistry of N4 Macrocyclic Metal Complexes. Volume 1 Energy
Electrochemistry of N4 Macrocyclic Metal Complexes. Volume 2 Biomimesis, electroanalysis and electrosynthesis of MN4 metal complexes
Electroquímica: voltametrías sobre electrodo sólido” Sello Editorial Usach, (2009) 336 pages.

ConferencePaper (3)

Preparation and characterization of modified electrodes based on carbon nanotubes/pyrrole/cobalt phthalocyanine for the development of hybrid materials for the electrochemical activation of 2-mercaptoethanol
Electropolymerized cobalt macrocomplex-based films for thiols electro-oxidation: Effect of the film formation conditions and the nature of the macrocyclic ligand
A theoretical procedure to determine interaction energies in complex systems: Application to the oxygen-iron tetraazaporphyrin interaction

Editorial (1)

Preface

EditorialMaterial (1)

Editorial Overview: Tuning chemistry for better electrocatalysis

Errata (2)

Linear versus volcano correlations for the electrocatalytic oxidation of hydrazine on graphite electrodes modified with MN4 macrocyclic complexes (vol 140, pg 314, 2014)
Enhanced catalytic activity of Fe phthalocyanines linked to Au(111) via conjugated self-assembled monolayers of aromatic thiols for O-2 reduction (vol 13, pg 1182, 2011)

Monograph (1)

“Oxygen reduction on carbon-supported metallophthalocyanines and metalloporphyrins” (2017) 1-8.

Proyecto (42)

REACTIVITY DESCRIPTORS FOR MNX NON-PRECIOUS METAL COMPLEXES AS MOLECULAR CATALYSTS FOR ELECTROCHEMICAL REACTIONS
DESIGN AND SYNTHESIS OF NON-PRECIOUS METALLIC NANOCATALYSTS (M-N-C) AS ALTERNATIVE TO PT FOR ENERGY CONVERSION
REACTIVIDAD DE COMPLEJOS MACROCÍCLICOS Y NANOPARTÍCULAS DE HIERRO INMOVILIZADOS EN ELECTRODOS HÍBRIDOS CON NANOTUBOS DE CARBONO EN LA OXIDACIÓN DE TIOLES Y REDUCCIÓN DE DISULFUROS DE INTERÉS BIOLÓGICO.
TUNING THE REDOX AND ELECTRONIC PROPERTIES OF METAL COMPLEXES FOR METAL COMPLEXES FOR THE HIGHEST ELECTROCATALYTIC ACTIVITY
MOLECULARLY ASSEMBLED ELECTRODES
DISEÑO, SINTESIS Y ESTUDIO DEL PODER CATALITICO DE NUEVOS ELECTRODOS TRIDIMENSIONALES DE MATRIZ POLIMERICA CON NANOESTRUCTURAS MAGNETICAS FUNCIONALIZADAS CON FTALOCIANINAS.
NANOTUBOS DE CARBONO DOPADOS CON NITROGENO, SINTETIZADOS CON DIFERENTES CATALIZADORES ORGANOMETALICOS=> EFECTO EN SU ACTIVIDAD ELECTROCATALITICA HACIA LA REACCION DE REDUCCION DE OXIGENO EN CELDAS DE COMBUSTIBLE H2/O2.
UNDERSTANDING GALVANIC CORROSION OF ALUMINUM ALLOYS FOR AEROSPACE APPLICATIONS
SYNTHESES AND REACTIVITY OF CROWN ETHER ANDMIXED-AZA-MACROCYLES CYCLOPENTADIENYL RHENIUM COMPLEXES AS APOTENCTIAL ELECTROCHEMICAL AND OPTICAL SENSORS.
HYBRID MOLECULAR ELECTRODE MATERIALS CONTAINING METALLOMACROCYCLICS, CARBON NANOTUBES AND SELF ASSEMBLED MONOLAYERS FOR ELECTROCATALYSIS AND ELECTROANALYSIS
NANOPARTICLES MODIFIED INORGANIC-ORGANIC HYBRID POLYMERS FOR CORROSION PROTECTION OF ALUMINIUM ALLOYS
RUPTURA DE ADN ELECTROQUIMICA Y FOTOQUIMICAMENTE ACTIVADO SOBRE ELECTRODOS DE AU(111) MODIFICADOS CON AUTOENSAMBLES DE COMPLEJOS FENANTROLINICOS DE CU(I)
FABRICATION OF LARGE ARRAY OF ORIENTED POLYANILINE NANOWIRES BY HYBRID TEMPLATE.
DOPAMINE SENSOR BASED ON INMOBILIZATION OF PHTHALOCYANINES AND PORPHYRINES IN HYBRID SOL-GEL FILMS
INDICES DE REACTIVIDAD DE COMPLEJOS METALICOS CONFINADOS EN SUPERFICIES ELECTRODICAS EN REACCIONES DE TRANSFERENCIA DE CARGA
INDICES DE REACTIVIDAD DE COMPLEJOS METALICOS CONFINADOS EN SUPERFICIES ELECTRODICAS EN REACCIONES DE TRANSFERENCIA DE CARGA
FORMACION Y ESTABILIDAD DE PELICULAS HIBRIDAS ORGANICAS/INORGANICAS EN LA PROTECCION DE ALEACIONES DE ALUMINIO Y ACERO INOXIDABLE.
INDICES DE REACTIVIDAD DE COMPLEJOS METALICOS CONFINADOS EN SUPERFICIES ELECTRODICAS EN REACCIONES DE TRANSFERENCIA DE CARGA
INDICES DE REACTIVIDAD DE COMPLEJOS METALICOS CONFINADOS EN SUPERFICIES ELECTRODICAS EN REACCIONES DE TRANSFERENCIA DE CARGA
PROCESOS DE TRANSFERENCIA DE CARGA EN ELECTROCATALISIS Y CORROSION ELECTROQUIMICA.
CORRELACIONES ENTRE ENERGIA DE ACTIVACION Y ENERGIA LIBRE EN REACCIONES ELECTRODICAS EN ELECTRODOS MODIFICADOS.
SINTESIS, CARACTERIZACION Y PROPIEDADES ELECTROCATALITICAS DE POLIMEROS CONDUCTORES DE 4, 4',4'',4''' TETRAAMINOFTALOCIANINAS DE CO Y DE FE
ELECTRO-OXIDACION DE TIOLES SOBRE ELECTRODOS MODIFICADOS CON COMPLEJOS METALICOS MACROCICLICOS
ESTUDIO CINETICO DE LA OXIDACION DE TIOLES SOBRE ELECTRODOS DE GRAFITO MODIFICADO. ESTABLECIMIENTO DE CINETICAS TIPO MARCUS.
ELECTRODOS MODIFICADOS CON POLIMEROS Y CON CATALIZADORES DE COMPLEJOS METALICOS. APLICACIONES EN SISTEMAS DE CONVERSION DE ENERGIA Y EN SENSORES.
REDUCCION DEL ANION NITRATO DE OXIDACION DEL ETILEN GLICOL=> ACTIVIDAD ELECTROCATALITICA DE ELECTRODOS DE METALES NOBLES
ELECTRODOS MODIFICADOS CON POLIMEROS CONDUCTORES Y CON COMPLEJOS METALICOS MACROCICLICOS
ELECTRODOS MODIFICADOS CON POLIMEROS CONDUCTORES Y CON COMPLEJOS METALICOS MACROCICLICOS
OXIDACION DE COMPUESTOS ORGANICOS SOBRE ELECTRODOS DE METALES NOBLES MODIFICADOS.
OXIDACION DE COMPUESTOS ORGANICOS SOBRE ELECTRODOS DE METALES NOBLES MODIFICADOS.
ELECTROCATALISIS SOBRE ELECTRODOS MODIFICADOS CON COMPLEJOS METALICOS MACROCICLICOS.
ELECTROCATALISIS SOBRE ELECTRODOS MODIFICADOS CON COMPLEJOS METALICOS MACROCICLICOS.
PROPIEDADES ELECTORCATALITICAS DE ELECTRODOS DE METALES NOBLES MODIFICADOS.
PROPIEDADES ELECTORCATALITICAS DE ELECTRODOS DE METALES NOBLES MODIFICADOS.
PROPIEDADES ELECTROCATALITICAS DE COMPLEJOS METALICOS INMOVILIZADOS SOBRE ELECTRODOS DE GRAFITO.
PROPIEDADES ELECTROCATALITICAS DE COMPLEJOS METALICOS INMOVILIZADOS SOBRE ELECTRODOS DE GRAFITO.
PROPIEDADES ELECTROCATALITICAS DE COMPLEJOS METALICOS INMOVILIZADOS SOBRE ELECTRODOS DE CARBON Y GRAFITO.
PROPIEDADES ELECTROCATALITICAS DE COMPLEJOS METALICOS INMOVILIZADOS SOBRE ELECTRODOS DE CARBON Y GRAFITO.
OXIDACION DE HCOOH SOBRE ELECTRODOS DE RODIO, IRIDIO O PLATINO, MODIFICADOS CON ATOMOS
OXIDACION DE HCOOH SOBRE ELECTRODOS DE RODIO, IRIDIO O PLATINO, MODIFICADOS CON ATOMOS
PROPIEDADES ELECTROCATALITICAS DE COMPLEJOS METALICOS INMOVILIZADOS SOBRE ELECTRODOS DE CARBON Y DE GRAFITO.
PROPIEDADES ELECTROCATALITICAS DE COMPLEJOS METALICOS INMOVILIZADOS SOBRE ELECTRODOS DE CARBON Y DE GRAFITO.

Review (6)

Electrocatalytic oxygen reduction on transition metal macrocyclic complexes for anion exchange membrane fuel cell application
Electrochemical Behavior of Electrode Materials (Nickel and Stainless Steels) for Sudomotor Dysfunction Applications: A Review
Free energy relationships in electrochemistry: a history that started in 1935
Metallophthalocyanine-based molecular materials as catalysts for electrochemical reactions
Carbon Nanotubes, Phthalocyanines and Porphyrins: Attractive Hybrid Materials for Electrocatalysis and Electroanalysis
Tuning the redox properties of metalloporphyrin- and metallophthalocyanine-based molecular electrodes for the highest electrocatalytic activity in the oxidation of thiols
180
José Zagal

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Chemistry of Materials

UNIVERSIDAD DE SANTIAGO DE CHILE

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Química de los Materiales

UNIVERSIDAD DE SANTIAGO DE CHILE

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5
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UNIVERSIDAD DE SANTIAGO DE CHILE

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3
Juan Guerrero

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inorganic chemistry

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santiago, Chile

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Instituto de Química

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Universidad de Talca

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Universidad Nacional de Córdoba

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Universidad de Santiago de Chile

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Edificio de Ciencia y Tecnología

Universidad Tecnológica Metropolitana

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Paulo Molina

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Universidad de Santiago de Chile

Santiago, Chile

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profesor asociado

departamento de física

UChile

santiago, Chile

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Sara Ramirez

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Universidad Bernardo O'Higgins

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Centro Integrativo de Biología y Química Aplicada - CIBQA

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