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Adalberto Hugo Klahn Oliva

Full Professor

PUCV

Valparaiso, Chile

Quimica Inorganica; Quimica Organometalica; Quimica Bioorganometalica; Catalysis.

Chemistry, SIMON FRASER UNIVERSITY. Canada, 1987

Full Professor Full Time

PONTIFICIA UNIVERSIDAD CATOLICA DE VALPARAISO

Science

Valparaiso, Chile

1978 - A la fecha

Full Professor Full Time

Pontificia Universidad Catolica de Valparaiso

Chile

1978 - A la fecha

Tesis Doctorales dirigidas:
1. Coordinación y Activación de Enlaces C-F y C-H en Bencenos Fluorados por Complejos Organometálicos de Renio.
Alumna: Beatriz Oelckers P.
Universidad Católica de Valparaíso, 1999.

2. Reacciones del Ligando Tetrametilfulveno Coordinado a Complejos de Renio. Alumno: Fernando Godoy G.
Universidad Católica de Valparaíso, 2003.

3. Compuestos organometálicos de cyretreno y ferroceno con potencial actividad antiparasitaria.
Alumno: Rodrigo Arancibia G.
Universidad Católica de Valparaíso, 2011.

4. Complejos Heterobinucleares derivados de ligandos ciretrenos.
Alumno: Diego Sierra.
Universidad Católica de Valparaíso, 2011.

5. Ligandos Organometálicos Piridínicos y Polipiridínicos Cyretrénicos y sus Complejos de
Coordinación.
Alumno: Teresa Cautivo S.
Universidad Católica de Valparaíso, 2012.

6.- Tesis de Pregrado: 25 tesis dirigidas de alumnos de Licenciatura en Química y Química
Industrial de las cuales 4 han sido ejecutadas durante 2004-2014.


Synthesis and characterization of thin molybdenum oxide films prepared from molybdenum dioxo tropolonate precursors by photochemical metal-organic deposition (PMOD) and its evaluation as ammonia gas sensors Buono-Core G.E.; Klahn A.H.; Castillo C.; Muñoz E; Manzur, C; Cabello, G; Chornik, B Article ISI JOURNAL OF NON-CRYSTALLINE SOLIDS (2014)
Synthesis, characterization and in vitro anti-Trypanosoma cruzi and anti-Mycobacterium tuberculosis evaluations of cyrhetrenyl and ferrocenyl thiosemicarbazones Arancibia, R.; Klahn, AH; Lapier, M.; Maya, JD; Ibáñez A.; Garland, MT; Carrere-Kremer, S; Kremer, L; Biot, C Article ISI JOURNAL OF ORGANOMETALLIC CHEMISTRY (2014)
METHOXYCARBONYLATION OF STYRENE BY PALLADIUM(II) COMPLEX CONTAINING THE DIPHENYLPHOSPHINOCYRHETRENE LIGAND Zúñiga C.; Sierra D.; Oyarzo J.; Klahn, AH Article ISI SCIELO JOURNAL OF THE CHILEAN CHEMICAL SOCIETY (2012)
Pt/WO3 thin films prepared by photochemical metal-organic deposition (PMOD) and its evaluation as carbon monoxide sensor Buono-Core G.E.; Klahn A.H.; Muñoz E; Bustamante M.J.; Castillo C.; Cabello, G; Chornik, B Article ISI SCOPUS POLYHEDRON (2012)
? 2-coordination of chlorobenzenes to rhenium fragment CpRe(CO) 2: Chemical and photochemical syntheses of CpRe(CO) 2(? 2-C 6H 6-nCl n) Klahn A.H.; Morales, V; Oelckers, B; Buono-Core G.E.; Gómez J.; Godoy, F Article SCOPUS Journal of the Chilean Chemical Society (2011)
Suzuki cross-coupling of aryl bromides catalyzed by cyrhetrenylphosphine complexes of palladium (II) Sierra D.; Zúñiga C.; Buono-Core, GE; Godoy, F; Klahn, AH Article ISI SCOPUS INORGANIC CHEMISTRY COMMUNICATIONS (2011)
Synthesis and evaluation of bis-?-diketonate dioxotungsten(VI) complexes as precursors for the photodeposition of WO 3 films Buono-Core G.E.; Klahn A.H.; Castillo C.; Bustamante M.J.; Muñoz E; Cabello, G; Chornik, B Article POLYHEDRON (2011)
Synthesis and evaluation of bis-beta-diketonate dioxotungsten(VI) complexes as precursors for the photodeposition of WO3 films Buono-Core, GE; Klahn, AH; Castillo C.; Bustamante, MJ; Muñoz E; Cabello, G; Chornik, B Article ISI SCOPUS POLYHEDRON (2011)
Synthesis, characterization and anti-Trypanosoma cruzi evaluation of ferrocenyl and cyrhetrenyl imines derived from 5-nitrofurane Arancibia, R.; Klahn, AH; Buono-Core, GE; Gutierrez-Puebla E.; Monge, A; Medina, ME; Olea Azar C.; Maya, JD; Godoy, F Article ISI SCOPUS JOURNAL OF ORGANOMETALLIC CHEMISTRY (2011)
(Z)-3-(4-Bromoanilino)-1-ferrocenylbut-2-en-1-one Valdebenito, C.; Garland, MT; Fuentealba, M; Klahn, AH; Manzur, C Article ISI SCOPUS Acta Crystallographica Section E: Structure Reports Online (2010)
Growth and characterization of molybdenum oxide thin films prepared by photochemical metal-organic deposition (PMOD) Buono-Core, GE; Cabello, G; Klahn, AH; Lucero A.; Nunez, MV; Torrejon, B; Castillo C. Article ISI SCOPUS POLYHEDRON (2010)
Heterobimetallic Re=Pd complexes bridged by eta(1):eta(5)-Ph2PC5H4 ligand. Synthesis, electronic and crystal structure of (CO)(2)(PR3)(eta(5)-C5H4(PPh2)Re-P)over bardCl(2), R = Me and OMe Sierra D.; Klahn, AH; Ramirez-Tagle, R; Arratia-Perez, R; Godoy, F; Garland, MT; Fuentealba, M Article ISI SCOPUS DALTON TRANSACTIONS (2010)
Synthesis and antimalarial activities of rhenium bioorganometallics based on the 4-aminoquinoline structure Arancibia, R.; Dubar, F; Pradines, B; Forfar, I; Dive, D; Klahn, AH; Biot, C Article ISI SCOPUS Bioorganic and Medicinal Chemistry (2010)
Synthesis and reactivity of eta(5)-tetramethylcyclopentadienyl-propenyl rhenium complexes: Molecular structure of [(eta(5):eta(2)-C(5)Me(4)CH(2)CH=CH(2))Re(CO)(2)] Godoy, F; Gomez A.; Cardenas-Jiron, G; Klahn, AH; Lahoz, FJ Article ISI SCOPUS JOURNAL OF ORGANOMETALLIC CHEMISTRY (2010)
Heterobimetallic Re-Pd, Re-Au and Re-Cu complexes derived from diphenylphosphino cyrhetrene: Synthesis and X-ray structure Sierra D.; MuÑoz A.; Godoy, F; Klahn, AH; Ibáñez A.; Garland, MT; Fuentealba, M Article ISI SCOPUS POLYHEDRON (2009)
Reactions of cationic complex [(?5-C5Me5)Re(CO)3I]+ with primary amines leading to cyclic carbamoyl complexes Aballay, A.; Buono-Core G.E.; Klahn A.H.; Godoy, F; Ibáñez A.; Garland M.T. Article JOURNAL OF ORGANOMETALLIC CHEMISTRY (2009)
Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta(5):eta(1)-C5Me4CH2PPh2)Re(CO)(2) Godoy, F; Klahn, AH; Oelckers, B; Garland, MT; Ibáñez A.; Perutz, RN Article ISI SCOPUS DALTON TRANSACTIONS (2009)
Cyrhetrenylimines and cyrhetrenylamines: Synthesis, characterization and X-ray crystal structure Arancibia, R.; Godoy, F; Buono-Core, GE; Klahn, AH; Gutierrez-Pueblo, E; Monge, A Article ISI SCOPUS POLYHEDRON (2008)
?-Diketones derived from cyclopentadienyl rhenium tricarbonyl Cautivo, T; Godoy, F; Klahn A.H.; Buono-Core G.E.; Sierra D.; Fuentealba, M; Garland M.T. Article INORGANIC CHEMISTRY COMMUNICATIONS (2007)
SOLID STATE PHOTOCHEMISTRY OF Cu(II) ALKYLTROPOLONATE COMPLEXES IN THIN FILMS: THE PHOTOCHEMICAL FORMATION OF HIGH QUALITY FILMS OF COPPER(I) OXIDE Buono-Core, GE; Tejos M.; Klahn, AH; Cabello, G; Lucero A.; Hill, RH Article ISI SCIELO JOURNAL OF THE CHILEAN CHEMICAL SOCIETY (2007)
Characterization of pure ZnO thin films prepared by a direct photochemical method Buono-Core, GE; Cabello, G; Klahn, AH; Del Rio R.; Hill, RH Article ISI SCOPUS JOURNAL OF NON-CRYSTALLINE SOLIDS (2006)
Reductive elimination reaction of rhenium complexes trans-(?5-C5Me5)Re(CO)2(chloroaryl)Cl Aballay, A.; Arancibia, R.; Buono-Core G.E.; Cautivo, T; Godoy, F; Klahn A.H.; Oelckers, B Article JOURNAL OF ORGANOMETALLIC CHEMISTRY (2006)
Selectivity in C-Cl bond activation of dichloroarenes by photogenerated Cp*Re(CO)(2): combined experimental and DFT studies Aballay, A.; Clot, E; Eisenstein, O; Garland, MT; Godoy, F; Klahn, AH; Muñoz JC; Oelckers, B Article ISI SCOPUS NEW JOURNAL OF CHEMISTRY (2005)
NICKEL TROPOLONATE COMPLEXES AS PRECURSORS FOR THE DIRECT PHOTODEPOSITION OF NiO THIN FILMS Buono-Core, GE; Tejos M.; Schrebler, R; Klahn, AH; Hill, RH Article ISI SCIELO SCOPUS JOURNAL OF THE CHILEAN CHEMICAL SOCIETY (2004)
Reaction of tetramethylfulvene rhenium complexes (?6-C 5Me4CH2Re(CO)2R (R = I, C6F5) with alkyl phosphines and trimethylphosphite. X-ray structure of [(?5-C5Me4CH2-(PMe3))Re(CO)2(PMe3)]+I- Godoy, F; Klahn A.H.; Oelckers, B; Lahoz, F; Oro L.A. Article SCOPUS JOURNAL OF THE CHILEAN CHEMICAL SOCIETY (2004)
Cis-trans isomerisation of CpRe(CO)2(H)(ArF) (ArF = C6FnH5-n; n = 0-5) is the rate determining step in C-H activation of fluoroarenes: A DFT study Clot, E; Eisenstein, O; Oelckers, B; Klahn A.H.; Perutz R.N. Article SCOPUS DALTON TRANSACTIONS (2003)
Photochemical C-Cl bond activation of trichloroarenes by the rhenium complex (eta(5)-C5Me5)Re(CO)(3). X-ray structure of trans-(eta(5)-C5Me5)Re(CO)(2)(2-methoxy-4,5-dichlorophenyl)chloride Aballay, A.; Godoy, F; Buono-Core, GE; Klahn, AH; Oelckers, B; Garland, MT; Muñoz JC Article ISI SCOPUS JOURNAL OF ORGANOMETALLIC CHEMISTRY (2003)
Syntheses and reactivity of functionalized (eta(5)-tetramethylcyclopentadienyl) rhenium complexes: Molecular structures of (eta(5):eta(2)-C5Me4CH2CH2CH=CH2)Re(CO)(2) and (eta(5)-C5Me4CH2-2-C4H3S)Re(CO)(2)(PMe3) Godoy, F; Klahn, AH; Lahoz, FJ; Balana, AI; Oelckers, B; Oro, LA Article ISI SCOPUS ORGANOMETALLICS (2003)
Syntheses and reactions of the complexes (?5-C5Me5)Re(CO)2 (C6Cl5-nHn)Cl (n = 2,3): Compounds derived from initial C-Cl activation Klahn A.H.; Carreño, M; Godoy, F; Oelckers, B; Pizarro A.; Toro, A.; Reyes A. Article SCOPUS JOURNAL OF COORDINATION CHEMISTRY (2001)
SYNTHESES AND REACTIONS OF THE COMPLEXES (N5-C5ME5)RE(CO)2(C6CL5-NHN)CL(N=2,3): COMPOUNDS DERIVED FROM INITIAL C-CL ACTIVATION Toro, Adriana; Reyes, Arturo; Pizarro, Alejandra; Oelckers, Beatriz; Klahn, Adalberto; Godoy, Fernando; Carreno, Monica Article JOURNAL OF COORDINATION CHEMISTRY (2001)
Photochemical reactions of [Re(?5-C5R5)(CO)3] (R = H or Me) with partially fluorinated benzenes: C-H and C-F activation Godoy, F; Klahn A.H.; Oelckers, B; Higgitt C.L.; Perutz R.N.; Parsons, S Article Journal of the Chemical Society - Dalton Transactions (1999)
Synthesis and X-ray structure of the rhenium methyl complex trans-CpRe(CO)2(Me)I and a study of the products of photolysis of the rhenium alkyl methyl and dimethyl complexes CpRe(CO)2(Me)R (R = Ph, p-Tolyl, Me) under CO Leiva, C.; Sutton D.; Klahn A.H.; Godoy, F; Toro, A.; Manriquez, V.; Wittke, O Article ORGANOMETALLICS (1999)
SYNTHESIS AND CHARACTERIZATION OF BIS(ALKYLTROPOLONATE) URANYL COMPLEXES: NEW PRECURSORS FOR THE PHOTODEPOSITION OF THIN FILMS OF UO3 Buono-Core, Gonzalo; Klahn, Adalberto; tejos, marisol; Hill, Ross Article BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA (1998)
Synthesis and reactions of the rhenium fulvene complexes [Re(?6-C5Me4CH2)(CO) 2(C6F4R)] (R = F or CF3): Products derived from initial C-F activation Klahn A.H.; Oelckers, B; Godoy, F; Garland M.T.; Vega A.; Perutz R.N.; Higgitt C.L. Article Journal of the Chemical Society - Dalton Transactions (1998)
Direct and high yield syntheses of Re2(CO)10 and Re(CO)5 Cl by sodium reduction of K2ReCl6 under CO Klahn A.H.; Oelckers, B; Toro, A.; Godoy, F Article JOURNAL OF ORGANOMETALLIC CHEMISTRY (1997)
Sensitized photolysis of dihydrobis(1-pyrazolyl)borate copper(II); general reaction pattern Buono-Core G.E.; Klahn A.H.; Bahamondes C.; Aros, F.; Tejos M.; Astorga V. Article INORGANICA CHIMICA ACTA (1997)
Stepwise substitution reactions of the (?5-C5Me5) Re(CO) 2I2 complex: Aryl-iodo and aryl-methyl derivatives trans-(?5-C5Me5) Re(CO) 2(Ar) X, X = I and Me. X-ray structure of trans-(?5-C5Me5) Re(CO) 2(Ph) I Klahn A.H.; Toro, A.; Arenas, M; Manriquez, V.; Wittke, O Article JOURNAL OF ORGANOMETALLIC CHEMISTRY (1997)
Structure and dynamics of the ?2-hexafluorobenzene complexes [Re(?5-C5H4R)(CO)2(? 2-C6F6)] (R = H or Me) and [Rh(?5-C5Me5)(PMe3)(? 2-C6F6)] Higgitt C.L.; Moore M.H.; Partridge M.G.; Perutz R.N.; Klahn A.H.; Oelckers, B Article Journal of the Chemical Society - Dalton Transactions (1997)
Benzophenone sensitized photochemistry of a copper(ii) polypyrazolylborate complex Buono-Core G.E.; Klahn A.H.; Aros, F.; Astorga V. Article POLYHEDRON (1996)
The mechanism of the photoreaction of cis-(?5-C5Me5)Re(CO)2I 2 with P(OMe)3 Xia W.; Hill R.H.; Klahn A.H.; Leiva, C.; Buono-Core G.E. Article POLYHEDRON (1996)
SYNTHESES AND REACTIONS OF THE COMPLEXES (ETA(5)-C5ME5)RE(CO)(2)(C6CL5-NHN)CL (N=2,3): COMPOUNDS DERIVED FROM INITIAL C-CL ACTIVATION Carreno, Monica; Godoy, Fernando; Klahn, Adalberto; Oelckers, Beatriz; Pizarro, Alejandra; Reyes, Arturo Article JOURNAL OF COORDINATION CHEMISTRY