Man

Sergio Antonio Moya Duran

Profesor Titular

University of Santiago of Chile

Santiago, Chile

Líneas de Investigación


Homogenous Catalysis and Coordination Chemistry

Educación

  •  Chemistry, Santa Barbara, University. Estados Unidos, 1981
  •  Chemistry, Santa Barbara, University. Chile, 1979

Experiencia Académica

  •   professor Full Time

    UNIVERSIDAD DE SANTIAGO DE CHILE

    Química y Biologia

    Santiago, Chile

    1982 - A la fecha

  •   professor Full Time

    UNIVERSIDAD DE CHILE

    Sede Talca

    Talca, Chile

    1968 - 1976

Experiencia Profesional

  •   Profesor Titular Full Time

    Universidad de Santiago de Chile

    Santiago, Chile

    1978 - A la fecha

Formación de Capital Humano


Elizabeth Allende
Síntesis, caracterización de complejos de Rh(I) con ligandos fósforo- nitrógeno. Aplicación catálisis homogénea”.
Licenciada en Ingenieria / UTEM/ 2006

Carolina Cerpa / Sonia Valdebenito
sintesis de compuestos orgánicos de interés comercial utilizado catalizadores de Paladio (II) y Rutenio (II) con ligandos fósforo-nitrógeno (P-N)
Lic Quimica/ UTEM-2007.

Catalina Pérez Zúñiga
Síntesis y caracterización de nuevos compuestos metálicos de Ru(II) y Cu(II) conteniendo ligandos mixtos nitrogenados y fosforados. Aplicación preliminar como catalizadores en la reacción de transferencia de hidrógeno
Químico. Licenciado en Química
Usach, 2007

Cesar Zúñiga Camiroaga
Síntesis, caracterización y estudio comparativo en la conducta catalítica de complejos de Ru y Pd conteniendo ligandos fosforados, polipiridinicos y carbénicos
Doctorado en Química
Usach 2007

Mauricio Yañez
Sintesis, caracterización y estudio químico-cuántico de complejos hidruro de rutenio con ligandos fosforados y polipiridínicos: potenciales aplicaciones como catalizadores en hidroformilación de olefinas
Doctorado en Química
Usach 2007

Gabriel Abarca Anjari Estudio comparativo en la conducta catalítica de complejos de Ru(II) con ligandos polipiridinicos en la reacción de hidroaminación
Químico. Licenciado en Química.
Usach, 2008

Matías Vidal Palomo
Hidrogenación de iminas catalizada por complejos de Ru(II) con ligandos polipiridínicos. Estudios preliminares Químico.
Licenciado en Química.
Usach, 2008

Juana Gajardo Oyarzo
Efecto de ligandos naftiridinicos sustituidos en la actividad catalítica de complejos clorocarbonilos de rutenio(II)en la reacción de transferencia de hidrógeno
Doctorado en Química
/Usach 2011

Juan Araya Vargas
Incorporación de ligantes nitrogenados y su influencia sobre la actividad catalítica de Ru3(CO)12 en la hidrogenación de cetonas por tranasferencia de hidrogéno
Doctorado en Química
Usach,2011

Gabriel Abarca Anjari
“Methoxycarbonylation catalyzed olefin complexes of Pd (II) containing phosphorus-nitrogen ligands in ionic liquids and biphasic media"
Doctorado en Química
Universidad de Chile,2013.

Vania Andrea Artigas Salinas
“Sintesis y caracterización de compuestos bimetálicos hierro-rutenio derivados de ferroceno unidos a través de un puente fósforoy/o nitrógeno. Aplicación preliminar como catalizadores homogéneos en la reacción de hidrogenación de iminas”
Magister en Química Finalizado
Universidad de Santiago de Chile. Octubre 2013

Matías Vidal Palomo
Doctorado en Qu.imica Finalizado
Universidad de Santiago de Chile. Septiembre 2014


Premios y Distinciones

  •   Académico Distinguido e Investigador

    UNIVERSIDAD DE SANTIAGO DE CHILE

    Chile, 2013

    Distinción entregada en reconocimiento a trayectoria académica sobresaliente, a un significativo aporte en la formación de nuevas generaciones e innegable labor como investigador


 

Article (83)

Catalytic activity in transfer hydrogenation using ruthenium (II) carbonyl complexes containing two 1,8-naphthyridine as N-monodentate ligands
Catalytic activity in transfer hydrogenation using ruthenium (II) carbonyl complexes containing two 1,8-naphthyridine as N-monodentate ligands
Catalytic activity of a new Ru(ii) complex for the hydrogen transfer reaction of acetophenone and N-benzylideneaniline: synthesis, characterization and relativistic DFT approaches
Hydrogenation of N-benzylideneaniline by palladium (II) catalysts with phosphorus-nitrogen ligands using formic acid as a renewable hydrogen source
Hydrogenation of N-benzylideneaniline by palladium (II) catalysts with phosphorus-nitrogen ligands using formic acid as a renewable hydrogen source
New palladium (II) complexes containing phosphine-nitrogen ligands and their use as catalysts in aminocarbonylation reaction
New palladium (II) complexes containing phosphine‐ nitrogen ligands and their use as catalysts in aminocarbonylation reaction
Carboxymethylcellulose from bleached organosolv fibers of Eucalyptus nitens: synthesis and physicochemical characterization
Ruthenium(II)–carbonyl complexes containing two N-monodentate 1,8-naphthyridine ligands: active catalysis in transfer hydrogenation reactions
Ruthenium(II)–carbonyl complexes containing two N-monodentate 1,8-naphthyridine ligands: active catalysis in transfer hydrogenation reactions
Transfer hydrogenation of N-benzylideneaniline catalyzed by ruthenium complexes with pincer-type phosphorus nitrogen ligands using propan-2-ol as the hydrogen source
MECHANISTIC STUDY OF A RUTHENIUM HYDRIDE COMPLEX OF TYPE [RuH(CO)(N-N)(PR3)2]+ AS CATALYST PRECURSOR FOR THE HYDROFORMYLATION REACTION OF 1-HEXENE
Luminescent bis-cyclometallated iridium(III) complexes containing phosphine-based ligands: Influence of the P^N bridge
Luminescent bis-cyclometallated iridium(III) complexes containing phosphine-based ligands: Influence of the PN bridge
Methoxycarbonylation of Styrene Using a New Type of Palladium Complexes Bearing P,N-donor Ligands as Catalysts
Methoxycarbonylation of Styrene Using a New Type of Palladium Complexes Bearing P,N-donor Ligands as Catalysts
Synthesis and characterization of ruthenium(II) complexes incorporating 4-phenyl-terpyridine and triphenylphosphine
Synthesis and characterization of ruthenium(II) complexes incorporating 4′-phenyl-terpyridine and triphenylphosphine
New fluorescent bis-dithienylethene (DTE)-based bipyridines as reverse interrupters: single vs. double photochromism
AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS
Ruthenium carbonyl compounds containing polypyridine ligands as catalysts in the reaction of N-benzylideneaniline hydrogenation
Catalytic hydrogenation of N-benzylideneaniline using a new complex of ruthenium (II) derived from 2-ferrocenyl-1,8-naphthyridine
Synthesis, characterization and structure of tribromo(2-phenyl-1,8- naphthyridine)gold(III)
Modulating the luminescence of an iridium(iii) complex incorporating a di(2-picolyl)anilino-appended bipyridine ligand with Zn 2+ cations
SYNTHESIS, CHARACTERIZATION AND PRELIMINARY CATALYTIC PROPERTIES OF NEW COPPER (I) COMPLEXE [Cu (pyrazolyl)(2)]X TYPE
Synthesis, characterization and preliminary catalytic properties of new copper (i) complexe [cu (pyrazolyl)2]x type
Synthesis, structure and catalytic activities for hydrogen transfer reaction of the carbonyl ruthenium(II) complex containing polypyridine and phosphine ligands
Mo(CO) 3(NCMe)(PPh 3) 2: Synthesis, X-ray structure and evaluation of its catalytic activity for the homogeneous hydrogenation of olefins and their mixtures
Synthesis and characterization of new complexes of the type [Ru(CO) 2Cl 2 (2-phenyl-1,8-naphthyridine-kN) (2-phenyl-1,8- naphthyridine-kN?)]. Preliminary applications in homogeneous catalysis
Design and spectroscopic study of new ruthenium(II) complexes containing ligands derived from terpyridine and dipyrido[3,2-a : 2 ',3 '-c]phenazine: {Ru(4 '-Rph-tpy)[dppz(COOH)]Cl}PF6 with R=NO2, Br, Cl
Design and spectroscopic study of new ruthenium(II) complexes containing ligands derived front terpyridine and dipyrido[3,2-a:2?,3?-c] phenazine: Ru(4? -Rph-tpy) [dppz(COOH)]Cl}PF 6 with R = NO 2, Br, Cl
Influence of the 4-substituted pyridine ligand L? on both the conformation and spectroscopic properties of the (2,2?-biquinoline- ?N1,?N1?)
REPPE REACTION CATALYZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES
Catalytic reduction of 4-nitrobenzoic acid by cis-[Rh(CO) 2(amine) 2](PF 6) complexes under water-gas shift reaction conditions: Kinetics study
Intramolecular redox processes induced in biquinoline-centered and metal to ligand charge transfer excited states of Ru(II)-(4,4 '-bipyridine)-Re(I)- and Ru(II)-(pyrazine)-Re(I)-containing dyads
Erratum: Homoegeneous catálisis of the water gas shift reaction: IR, 1H-and 13C-NMR in situ estudies on catalytic iridium systems (Journal of the Chilean Chemical Society)
Erratum: Hydroformylation and isomerization of alkenes catalyzed by [Rh(COD)(Amine)2]PF6 complexes immobilized on poly(4-vinylpyridine) under CO/H2O conditions (Journal of the Chilean Chemical Society (2003) 48: 2)
Homogeneous catalysis of the water gas shift reaction: IR, 1H- and 13C-NMR in situ studies on catalytic iridium systems
Synthesis of ruthenium complexes with carbonyl and polypyridyl ligands derived from dipyrido[3,2-a:2?,3?-c]phenazine: Application to the water gas shift reaction
Síntesis and characterization of monometallic and bimetallic complexes of rhenium(I) and ruthenium(II) uit 4,4?-bipyridine as ligand-bridge Sintesis y caracterizacion de complejos mono y bimetalico de renio(I) y rutenio (II) con 4,4?-bipiridina como ligando puente
Water gas shift reaction and nitrobenzene reduction catalysis by tetracarbonyldi-?-chlorodirhodium(I) complex immobilized on poly(4-vinylpyridine)
Catalytic oxidation of 1-hexene with molecular oxygen by the cu(ch3cn)2(no2)2/pd(ch 3cn)2cl2 bimetallic system
Hydroformylation of 1-hexene catalyzed by [Rh(COD)(2-picoline) 2]PF 6 immobilized on poly(4-vinylpyridine) under water gas shift reaction conditions
Influence of the reaction conditions on the reduction of nitrobenzene catalyzed by poly(4-vinylpyridine) anchored [Rl}(COD)(2-P\C)2](PF 6) complex
Crystal structure of bis(3,3?-trimethylene-2,2?-biquinolinium)(1+) dibromoaurate(I)(1-) tetrabromoaurate(III)(1-), (C21H16N2H)2[AuBr 2][AuBr4], a mixed valence Au(I)/Au(III) salt
Crystal structure of tribromo(3,3?-dimethyl-2,2?-biquinoline)gold(III) hemiglycolate, (C9H5CH3N)2AuBr3 · 0.5(CH2OH)2
Synthesis, structure, and antitumor activity of a novel tetranuclear titanium complex
The reduction of nitrobenzene as catalyzed by poly(4-vinylpyridine)-immobilized [Rh(COD)(amine) 2](PF 6) complexes under WGSR conditions
Water as hydride source in the reduction of nitrobenzene to aniline catalyzed by cis-[Rh(CO) 2(2-picoline) 2](PF 6) in aqueous 2-picoline under CO atmosphere: Kinetics study
Bromotricarbonyl(3,3?-dimethylene-2,2?-biquinoline)rhenium(I)
ELECTROCHEMICAL PROPERTIES OF RHENIUM CARBONYL COMPLEXES CONTAINING TERPYRIDINE LIGAND DERIVATIVES
Rhodium amino complexes [Rh(COD)(amine) 2]pf 6 immobilized on poly(4-vinylpyridine) as catalysts in the water gas shift reaction
[Re(Co)3(3,3?-trimethylene-2,2?-biquinoline) (p-substituted-py)]+ complexes. Preparation and characterization
Bromotricarbonyl(3,3?-dimethyl-2,2?-biquinoline-N,N?) rhenium(I)
Homogeneous catalysis of the water-gas shift reaction by copper complexes in aqueous substituted pyridine solutions
Homogeneous reduction of nitrobenzene to aniline by CO/H 2O, catalyzed by C/S-[lr(CO) 2(amine) 2]PF 6
Homogeneous reduction of nitrobenzene to aniline under CO/H2O, catalyzed by cis-[Rh(CO)2(amine)2]PF6.the role of the a mine effect
Polymer heterogenized iridium amino complexes. Catalyzed reduction of nitrobenzene under WGSR conditions
ReBr(CO) 3(3,3?-disubstituted-2,2?-biquinoline) modified complexes as initiating systems for styrene polymerization
Reduction of nitrobenzene to aniline by CO/H 2O catalyzed by cis-[Rh(CO) 2(amine) 2]PF 6 immobilized on poly(4-vinylpyridine)
SOME STUDIES ON STYRENE POLYMERIZACION USING NEW SYSTEMS PREPARED FROM COORDINATION METAL COMPOUNDS REBR(CO)3(3,3-DIMETHYL-2,2-BIQUINOLINE)-DIPHENYLZINC WITH AND WITHOUT MAO SYSTEMS
Some studies on styrene polymerization using new systems prepared from coordination metal compounds: ReBr(CO) 3(3,3?-dimethyl-2,2?-biquinoline)-diphenylzinc with and without MAO systems
WGSR catalyzed by cis-[Rh(CO)2(amine)2]PF6 heterogenised on poly(4-vinylpyridine)
Catalytic oxidation of 1-hexene with molecular oxygen by iridium nitro complexes
Complexes with heterocyclic nitrogen ligands - IV : Complexes of ruthenium(II) and applications in catalysis
Spectroscopic and electroreductive characterization of new ?-oxo-diiron(III) compounds with acyclic tetradentate ligands
Complexes with heterocyclic nitrogen ligands - III. Cationic rhodium(I) derivatives and applications in catalysis
Crystal structure and spectroscopic data of fac-tricarbonylbromo(3,3?-trimethylene-2,2?-bi-1,8-naphthyridine) rhenium(I), Re(CO) 3Br(C 19H 14N 4)
Metallic carbonyl complexes containing heterocyclic nitrogen ligands. Part IV 1. Compounds of the type [BrRe(CO)3(4?-R-2,2?:6?,2?-terpyridine)]
Reaccion de bromuro de oro(III) con tetra-fer-butil-ciclotetrafosfina
Soluble ruthenium carbonyl complexes containing new sterically hindered bipyridine ligands
The novel use of Rh(I) complexes with naphthyridine ligands and poly(oxyethylene) as antitumorals
Catalytic reduction of nitrobenzene by hydrogen transfer from 2-propanol
CATALITIC OXIDATION OF 1-HEXENE WITH MOLECULAR OXYGEN BY THE Cu(CH3CN)2(NO2)2/Pd(CH3CN)2Cl2 BIMETALLIC SYSTEM
Crystal structure of tribromo(3,3’-dimethyl-2,2’-biquinoline)gold(III) hemi glycolate, (C9H5CH3N)2AuBr3*0.5(CH2OH2
HOMOGENEOUS CATALYSIS OF THE WATER GAS SHIFT REACTION: IR, ¹H- AND 13C-NMR IN SITU STUDIES ON CATALYTIC IRIDIUM SYSTEMS
HOMOGENEOUS CATALYSIS REACTION OF FORMALDEHYDE WITH SYNTHESIS GAS USING RHODIUM COMPLEXES
Hydroformylation and Isomerization of Alkenes Catalyzed by [Rh(COD)(Amine)2]PF6 Complexes Immobilized on poly(4-vinylpyridine) Under CO/H2O Conditions
INFLUENCE OF THE REACTION CONDITIONS ON THE REDUCTION OF NITROBENZENE CATALIZED BY POLY (4-VINYLPYRIDINE) ANCHORED [RH(COD)(2-PIC)2](PF6) COMPLEX
Kinetics of the Water Gas Shift Reaction Catalyzed by [Rh(COD)(4-Picoline)2]PF6 Immobilized On Poly(4-vinylpyridine)
NEW POLYNUCLEAR CARBONYL RUTHENIUM(II) COMPLEXES DERIVED FROM 1,8-NAPHTHYRIDINE
REDUCTION OF 5-NITROFURAN COMPOUNDS CATALYZED BY A RHODIUM COMPLEX IMMOBILIZED ON POLY(4-VINYLPYRIDINE): A RELATIONSHIP WITH ANTIBACTERIAL ACTIVITY
SINTESIS Y CARACTERIZACION DE COMPLEJOS MONO Y BIMETALICO DE RENIO(I) Y RUTENIO (II) CON 4,4´-BIPIRIDINA COMO LIGANDO PUENTE

ConferencePaper (1)

Iron oxides from volcanic soils as potential catalysts in the water gas shift reaction

Proyecto (13)

New catalysts for renewable chemicals and biofuels
Luminescent bis-cyclometallated iridium (III) complexes containing phosphine-based ligands: influence of the PN bridge
Materiales Inorgánicos Funcionales
New catalysts for renewable chemicals and biofuels
Carbonylation reactions catalyzed by palladium complexes containing phosphorus-nitrogen ligands. Potential application for synthesis of pharmaceutical compounds
Hydrogenation of imines catalyzed by ruthenium complexes containing phosphine and polypyridine ligands
Carbonylation reactions catalyzed by palladium complexes containing phosphorus-nitrogen ligands. Potential application for synthesis of pharmaceutical compounds
HYDROGENATION OF IMINES CATALYZED BY RUTHENIUM COMPLEXES CONTAINING PHOSPHINE AND POLYPYRIDINE LIGANDS
New imine hydrogenations and hydroamination using homogeneous catalysis based on Ruthenium complexes containing polypyridine ligands
Inorganic Functional Materials
Nuevas sondas organometálicas luminiscentes para la detección de cationes
Nuevas sondas organometálicas luminiscentes para la detección de cationes”. RESUMEN: Este proyecto tiene como objetivo fomentar la colaboración con la Universidad de Rennes-Francia, buscando nuevas aplicaciones en la utilización de compuestos organometálicos en luminiscencia
Una nueva generación de catalizadores homogéneos conteniendo ligandos polipiridínicos fosfinados y hemilabiles P-N para reacciones de hidrogenación e hidroformilación de olefinas
88
Sergio Moya

Profesor Titular

Chemistry of the Materials

University of Santiago of Chile

Santiago, Chile

22
Pedro Aguirre

Profesor asociado

Inorgánica y Analítica

Universidad de Chile, Facultad de Ciencias Químicas y Farmacéuticas

Santiago, Chile

7
Juan Guerrero

ACADEMICO

QUÍMICA DE LOS MATERILAES

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

6
Diego Villagra

Academico-Investigador

Ingeniería Industrial

UNIVERSIDAD DE TARAPACA

Arica, Chile

3
Braulio Aranda

Académico

Ciencias Químicas y Recursos Naturales

Universidad de La Frontera

Temuco, Chile

2
Andres Vega

Director

Departamento de Química

UNIVERSIDAD ANDRES BELLO

Santiago, Chile

2
Claudio Terraza

Titular Professor

Organic Chemistry

PONTIFICIA UNIVERSIDAD CATÓLICA DE CHILE

Santiago, Chile

2
Manuel Azocar

Assistant Professor

Química de los Materiales

Universidad de Santiago de Chile

Santiago, Chile

2
Gonzalo Valdebenito

Investigador Postdoctoral

Centro Integrativo de Biología y Química Aplicada (CIBQA))

Universidad Bernardo O'Higgins

Santiago, Chile

2
César Zúñiga

Profesor Investigador

Instituto de Ciencias Naturales

Universidad de Las Américas

Santiago, Chile

1
Juan Quijada

FULL PROFESSOR

INGENIERIA QUIMICA Y BIOTECNOLOGIA

UNIVERSIDAD DE CHILE

Santiago, Chile

1
Carmen Pizarro

Associate Professor

Química de los Materiales

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

1
Mauricio Fuentealba

Profesor Adjunto

Pontificia Universidad Católica de Valparaíso

Valparaíso, Chile

1
Mauricio Yañez

UNIVERSIDAD DE SANTIAGO DE CHILE

SANTIAGO, Chile

1
Rodrigo Torres

Postdoc

Departamento de farmacología

Universidad de Chile

Santiago, Chile

1
Plinio Cantero

Profesor Adjunto

Química

Universidad Andrés Bello

Santiago de Chile, Chile