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Carolina del Pilar Aliaga Vidal

Profesora Titular

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

Líneas de Investigación


Effect of the microheterogeneous media in the interaction of spin probes with organic and nanoclusters fluorophores. These studies are performed by static and dynamic fluorescence, confocal microscopy and Electron Spin Resonance techniques.

Educación

  •  Profesor de Química y Ciencias Naturales, UNIVERSIDAD METROPOLITANA DE CIENCIAS DE LA EDUCACION. Chile, 1991
  •  Chemistry, UNIVERSIDAD DE CHILE. Chile, 1995
  •  Chemistry, UNIVERSIDAD DE CHILE. Chile, 2000

Experiencia Académica

  •   Profesor Asociado Full Time

    UNIVERSIDAD DE SANTIAGO DE CHILE

    Química y Biología

    Santiago, Chile

    2008 - A la fecha

  •   Associate Researcher Full Time

    UNIVERSITY OF OTTAWA

    Science

    Ottawa, Canada

    2004 - 2005

  •   Posdoctoral Fellow Full Time

    UNIVERSITY OF OTTAWA

    Science

    Ottawa, Chile

    2001 - 2003

Experiencia Profesional

  •   Profesor Asociado Full Time

    Universidad de Santiago de Chile

    Santiago, Chile

    2008 - A la fecha

  •   Investigador Part Time

    Centro para el Desarrollo de la Nanociencia y Nanotecnología

    Santiago, Chile

    2009 - A la fecha

Formación de Capital Humano


Graduate thesis.

2007-2011 Sr. Cristián Tirapegui, USACH co-tutora de tesis de Doctorado en Química “Estudio de derivados del 1,4-difenilpiridinio”.
2011-2014 Sr. Freddy Celis, USACH, tutora tesis de Doctorado en Química “Diseño, síntesis y evaluación de un nanosensor prefluorescente”.

Undergraduate thesis

2007 Srta. Andrea Arenas, USACH Licenciatura en Química “Estudio de hidrofobicidad en la reactividad de antioxidantes con nitróxidos por técnicas EPR”

2011 Srta. Paulina Torres, USACH Licenciatura en Química “Síntesis, reparto y cinéticas de sondas derivadas de tempo en medio micelar”

2011 Srta. Fabiola Berríos, USACH TUAQF ““Estabilidad del colorante natural annato en formulaciones para productos lácteos (aromcolor damasco)”



 

Article (56)

Influence of the Ni-II/Mn-II ratio on the physical properties of heterometallic Ni2xMn(2-2x)P2S6 phases and potassium intercalates K0.8Ni2xMn(1.6-2x)P2S6 center dot 2H(2)O
A comparison of multiparametric methods for the interpretation of solvent-dependent chemical processes
Influence of cyano substituents on the electron density and catalytic activity towards the oxygen reduction reaction for iron phthalocyanine. The case for Fe(II) 2,3,9,10,16,17,23,24-octa(cyano)phthalocyanine
Oxygen Reduction Reaction at Penta-Coordinated Co Phthalocyanines
Synthesis and evaluation of new heteroaryl nitrones with spin trap properties
In search of the most active MN4 catalyst for the oxygen reduction reaction. The case of perfluorinated Fe phthalocyanine
Interaction of Nitroxide Radicals with an Au-8 Nanostructure: Theoretical and Calorimetric Studies
Solvatofluorochromism of conjugated 4-methoxyphenyl-Pyridinium electron donor-acceptor pairs
The location of amphiphobic antioxidants in micellar systems: The diving-swan analogy
Antioxidant-spotting in micelles and emulsions
On the interactions of TEMPO radicals with gold nanostructures
Solvatochromism of conjugated 4-N,N-dimethylaminophenyl-pyridinium donor-acceptor pairs
The Solvatofluorochromism of 2,4,6-Triarylpyrimidine Derivatives
Visualization of Phase-Transfer Catalysis through Charge-Transfer Complexes
Cut-off effect of radical TEMPO derivatives in olive oil-in-water emulsions
Influence of the lanthanide(III) ion in {[Cu(3)Ln(2)(oda)(6)(H2O)(6)]center dot nH(2)O}(n) (Ln(III): La, Gd, Yb) catalysts on the heterogeneous oxidation of olefins
Nitrones: A Potential New Alternative as Therapeutic Agents
Hydroxyl Radical Generation and DNA Nuclease Activity: A Mechanistic Study Based on a Surface-Immobilized Copper Thioether Clip-Phen Derivative
Hydroxyl Radical Generation and DNA Nuclease Activity=> A Mechanistic Study Based on a Surface Immobilized Cu Thioether Clip-Phen Derivative
Location of TEMPO derivatives in micelles: subtle effect of the probe orientation
The effect of micellization on the EPR spectra and reactivity of 2,2,4,4-tetramethylpiperidinoxyl (TEMPO) radicals
“Cut-off” effect of antioxidants and/or probes of variable lipophilicity in microheterogeneous media
A single theoretical descriptor for the bond-dissociation energy of substituted phenols
RAMAN AND SURFACE ENHANCED RAMAN SIGNALS OF THE SENSOR 1-(4-MERCAPTOPHENYL)-2,4,6-TRIPHENYLPYRIDINIUM PERCHLORATE
TEMPO-Attached Pre-fluorescent Probes Based on Pyridinium Fluorophores
Angular dependence of hysteresis shift in oblique deposited ferromagnetic/antiferromagnetic coupled bilayers
Change of mechanism with a change of substituents for a Zincke reaction
EPR spectrum of a radical from a nontypical antioxidant
Ferromagnetic resonance investigation in permalloy magnetic antidot arrays on alumina nanoporous membranes
Mechanism of fluorophore quenching in a pre-fluorescent nitroxide probe: A theoretical illustration
Special Issue Dedicated to the Memory of Elsa Beatriz Abuin Saccomano (1942-2012) Introduction
A simple method for the determination of the partitioning of nitroxide probes in microheterogeneous media
Distribution and reactivity of gallates toward galvinoxyl radicals in SDS micellar solutions - Effect of the alkyl chain length
Exchange Interactions Through pi-pi Stacking in the Lamellar Compound [{Cu(bipy)(en)}{Cu(bipy)(H2O)}{VO3}(4)](n)
Sensing different micellar microenvironments with solvatochromic dyes of variable lipophilicity
MAGNETIC AND CATALYTIC PROPERTIES OF THE 2D COPPER(II) FUNCTIONALIZED VPO HYBRID SYSTEM [{CU(BPY)}(2)(VO)(3)(PO(4))(2)(HPO(4))(2)]CENTER DOT 2H(2)O
Magnetic and catalytic properties of the 2D copper(II) functionalized VPO hybrid system [{Cu(bpy)}(2)(VO)(3)(PO4)(2)(HPO4)(2)]center dot 2H(2)O
Magnetic and catalytic properties of the 2D copper(II) functionalized VPO hybrid system [{Cu(bpy)}(2)(VO)(3)(PO4)(2)(HPO4)(2)]center dot 2H(2)O
The thermochromism of the E-T(30) betaine in a micro-heterogeneous medium: A spectral and dynamics simulation study
A new dual probe for hydrogen abstraction
How meaningful is the assessment of antioxidant activities in microheterogeneous media?
Hydrogen-transfer reactions from phenols to TEMPO prefluorescent probes in micellar systems
Generation, spectroscopic characterization by EPR, and decay of a pyranine-derived radical
Transient enol isomers of dibenzoylmethane and avobenzone as efficient hydrogen donors toward a nitroxide pre-fluorescent probe
Solvent effects on hydrogen abstraction reactions from lactones with antioxidant properties
Comparison of the free radical scavenger activities of quercetin and rutin - An experimental and theoretical study
KINETICS PROFILES IN THE REACTION OF ABTS DERIVED RADICALS WITH SIMPLE PHENOLS AND POLYPHENOLS
Kinetics and mechanism of the reaction of a nitroxide radical (Tempol) with a phenolic antioxidant
Formation and decay of the ABTS derived radical cation: A comparison of different preparation procedures
Formation and decay of the ABTS derived radical cation: A comparison of different preparation procedures
A comparison of methods employed to evaluate antioxidant capabilities
Reactions of the radical cation derived from 2,2 '-azinobis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS(.+)) with amino acids. Kinetics and mechanism
REACTION OF 2,2-AZINOBIS (3-ETHYLBENZOTHIAZOLINE-6-SULFONIC ACID) (ABTS) DERIVED RADICALS WITH HYDROPEROXIDES. KINETICS AND MECHANISM
On the solvatochromic reversal of merocyanine dyes. Part 2.1 An experimental and semi-empirical study of the solvatochromism of ?- and ?-vinylogous pyridones
Angular dependence of hysteresis shift in oblique deposited ferromagnetic/antiferromagnetic coupled bilayers
EPR spectrum of a radical from a non typical antioxidant

Comentario (1)

Obituary Dra. Elsa Beatriz Abuin Saccomano

EditorialMaterial (1)

Special Issue Dedicated to the Memory of Elsa Beatriz Abuin Saccomano (1942-2012) Introduction

Letter (1)

EPR spectrum of a radical from a nontypical antioxidant

Proyecto (11)

NITROXIDE-BASED PROBES IN MICRO-HETEROGENEOUS MEDIA=> MICELLES AND NANOPARTICLES
Materiales Inorgánicos Polifuncionales en base a metales chilenos estratégicos -IPMaG
Study of Persistent Radicals in micro-heterogeneous media
PERICHROMIC DYES IN HOMOGENEOUS AND ADSORBED ON NANOPARTICLES
Determinación de dosis de radiación aplicada a alimentos por Resonancia de Spin Electrónica (ESR )
DESIGN AND PROPERTIES OF NEW PREFLUORESCENT PROBES IN HOMO AND MICROHETERO-GENEOUS MEDIA
Centro para el Desarrollo de la Nanociencia y la Nanotecnología
USE OF PREFLUORESCENT AND RADICAL PROBES FOR THE STUDY OF MEDIUM EFFECTS ON HYDROGEN TRANSFER REACTIONS.
Detección de especies radicalarias por técnicas de resonancia de espín electrónico (ESR) en sistemas de interés biológico
CINETICA Y MECANISMOS DE REACCION DE RADICALES ESTABLES CON SUSTRATOS DE INTERES BIOLOGICO
REACTIVIDAD Y MECANISMOS DE REACCION DE RADICALES LIBRES ESTABLES CON SUSTRATOS DE INTERES BIOLOGICO
74
Carolina Aliaga

Profesora Titular

Ciencias de Ambiente

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

8
ALEXIS ASPEE

Profesor Titular

Ciencias del Ambiente

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

4
Evgenia Spodine

Full Professor

Química Inorgánica y Analítica

UNIVERSIDAD DE CHILE

Santiago, Chile

3
Raquel Bridi

Profesor Asistente

Departamento de Farmacia

PONTIFICIA UNIVERSIDAD CATÓLICA DE CHILE

Santiago, Chile

3
Moisés Domínguez

Assistant professor

Department of Environmental sciences

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

2
Sebastian Michea

Profesor Asistente

Instituto de Ciencias Químicas Aplicadas

Universidad Autónoma de Chile

Santiago, Chile

2
Verónica Paredes

Academic

Ciencias Químicas

UNIVERSIDAD ANDRES BELLO

Santiago, Chile

2
Cristian Tirapegui

Académico

Universidad Autonoma de Chile

Santiago, Chile

2
Federico Tasca

PROFESOR ASOCIADO

QUIMICA DE LOS MATERIALES

Universidad de Santiago de Chile

Santiago, Chile

2
Iriux Almodóvar

Académico

Ciencias del Ambiente

Universidad de Santiago de Chile

Santiago, Chile

2
Andres Vega

Director

Departamento de Química

UNIVERSIDAD ANDRES BELLO

Santiago, Chile

2
Susan Lühr

Profesor Asistente

Química

Universidad de Chile

Santiago, Chile

2
Pedro Aguirre

Profesor asociado

Inorgánica y Analítica

Universidad de Chile, Facultad de Ciencias Químicas y Farmacéuticas

Santiago, Chile

2
patricio fuentealba

Profesor Titular

Física

U. DE CHILE, FAC. CIENCIAS, DPTO. FISICA

Santiago, Chile

2
Roberto Rodríguez

Profesor Asociado

Física

PONTIFICIA UNIVERSIDAD CATOLICA DE CHILE

Santiago, Chile

2
Gabriel Abarca

Profesor Asistente

Departamento de Ciencias Químicas y Biológicas

Universidad Bernardo O'Higgins

Santiago, Chile

2
FREDDY CELIS

Profesor Asociado

Química

Universidad de Playa Ancha

Valparaiso, Chile

2
Carlos Cardenas

Associate professor

Physics

UNIVERSIDAD DE CHILE

Santiago, Chile

2
Diego Venegas

Full Professor

Quimica de los Materiales

UNIVERSIDAD DE SANTIAGO DE CHILE, FACULTAD DE QUÍMICA Y BIOLOGÍA, DEPARTAMENTO DE QUÍMICA DE LOS MATERIALES

Santiago, Chile

1
Fernando Gonzalez

Titular Professor

Facultad de Ciencias de la Vida

Universidad Andres Bello

Santiago, Chile

1
Juan Escrig

Associate Professor

Department of Physics

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

1
Ingrid Ponce

Assistant Professor

Departmento Ciencias del Ambiente

Univerisidad de Santiago de Chile

Santiago, Chile

1
José Carcamo

Profesional Asociado a Investigacion

Instituto de Alta Investigación

Universidad de Tarapacá

Arica, Chile

1
Juliano Casagrande

Profesor Titular

Fisica

UNIVERSIDAD DE SANTIAGO DE CHILE

Santiago, Chile

1
Juan Palma

Profesor / Investigador Académico Asociado

Departamento de Ciencias Básicas

Universidad Central de Chile

Santiago, Chile

1
Carolina Mascayano

Académico

Ciencias del Ambiente

UNIVERSIDAD DE SANTIAGO DE CHILE, FACULTAD DE QUÍMICA Y BIOLOGIA

santiago, Chile

1
Camilo López

prof. Asociado

Química Física

PONTIFICIA UNIVERSIDAD CATÓLICA DE CHILE

Santiago, Chile

1
Patricio Cancino

Posdoc

Departamento de Ciencias Químicas y Farmacéuticas

Universidad de Chile

Santiago , Chile

1
Germán Barriga

Asociado

Quimica

Universidad Metropolitana de Ciencias de la Educación

Ñuñoa, Chile

1
Erick Burgos

Postdoctoral researcher

CNRS

Palaiseau, Francia

1
SEBASTIÁN MÁRQUEZ

Investigador

Fundación Biociencia

Santiago, Chile